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Basic information

  • Name:
  • Sodium hypophosphite monohydrate

  • CAS No.:
  • 10039-56-2

  • Molecular Structure:
  • Formula:
  • NaH2PO2.H2O
  • Molecular Weight:
  • 105.99
  • Synonyms:
  • Phosphinicacid, sodium salt, monohydrate (8CI,9CI);Phosphonous acid, monosodium salt,monohydrate;Phosphinic acid, sodiumsalt, hydrate (1:1:1);Sodium phosphinate hydrate;Sodium hypophosphite;
  • EINECS:
  • 231-669-9
  • Melting Point:
  • 90 °C
  • Solubility:
  • 1000 g/L (20 °C) in water
  • Appearance:
  • white crystals
  • Safety Description:
  • 22-24/25 Details

Famous Chemical Enterprises

  • Livzon
  • Total
  • Shell
  • Dupont
  • Exxonmobil
  • Akzonobel
  • Basf
  • Bayer
  • BP

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Chemistry

Molecule structure of Sodium hypophosphite monohydrate (CAS NO.10039-56-2):

Molecular Weight: 105.9935  g/mol
Molecular Formula: NaH2PO2.H2O
Melting Point: 90 °C
Water Solubility: 1000 g/L (20 °C)
Sensitive: hygroscopic
H-Bond Donor: 1
H-Bond Acceptor: 3
Exact Mass: 103.963925
MonoIsotopic Mass: 103.963925
Topological Polar Surface Area: 41.1
Heavy Atom Count: 5 
Canonical SMILES: O.[O-]P=O.[Na+]
InChI: InChI=1S/Na.HO2P.H2O/c;1-3-2;/h;(H,1,2);1H2/q+1;;/p-1
InChIKey: ACUGTEHQOFWBES-UHFFFAOYSA-M
EINECS: 231-669-9
Product Categories: Inorganic Salts;Synthetic Reagents;Analytical Reagents for General Use;Puriss p.a.;Q-S, Puriss p.a.

Uses

 Sodium hypophosphite monohydrate (CAS NO.10039-56-2) is mainly used for electroless nickel plating. A durable nickel-phosphorus film can coat objects with irregular surfaces with this method, and can widely be used ionics, aviation and the petroleum field. It is also used as a food additive.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
rat LD50 oral 7640mg/kg (7640mg/kg)   "Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku," Marhold, J.V., Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha, Czechoslovakia, 1972Vol. -, Pg. 16, 1972.

Safety Profile

Safety Statements: 22-24/25 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3
RTECS: SZ5640000
F: 3

Specification

 Sodium hypophosphite monohydrate (CAS NO.10039-56-2) is also named as Fosfornan sodny ; Fosfornan sodny [Czech] ; Sodium phosphinate hydrate ; Phosphinic acid, sodium salt, monohydrate . Sodium hypophosphite monohydrate (CAS NO.10039-56-2) is odorless white crystals at room temperature. It is soluble in water, and easily absorbs moisture from the air. Sodium hypophosphite should be kept in a cool, dry place, isolated from oxidizing materials. It produces toxic phosphine gas when heated, causing irritation to the respiratory tract.

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