Basic information
- Name:
Sodium percarbonate
- CAS No.:
15630-89-4
- Molecular Structure:

- Formula:
- 2Na2CO3.3(H2O2)
- Molecular Weight:
- 314.02
- Deleted CAS:
- 121525-84-6|205368-25-8|701915-52-8|701915-53-9|81677-18-1|82728-90-3|89140-31-8|90569-69-0
- Synonyms:
- SPC-Q 1;SPC-Q 4;SPC-Q 2;Oxyper;ECOX-C;FB Sodium Percarbonate;Perdox;Carbonic acid disodium salt,compounds,compd. with hydrogen peroxide (2:3);SPC-Q 3;Natriumpercarbonat, nicht gecoated;disodium carbonate, compound with hydrogen peroxide (2:3);
- EINECS:
- 239-707-6
- Boiling Point:
- 333.6 °C at 760 mmHg
- Flash Point:
- 169.8 °C
- Appearance:
- Free flowing white granular powder
- Hazard Symbols:
O,
Xn- Risk Codes:
- 8-22-41-36/38
- Safety Description:
- 17-26-37/39 Details
- Transport Information:
- UN 1479
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Chemistry
IUPAC Name: Tetrasodium hydrogen peroxide dicarbonate
Synonyms of Sodium percarbonate (CAS NO.15630-89-4): Disodium carbonate, hydrogen peroxide (2:3) ; FB Sodium percarbonate ; Oxyper ; Peroxy sodium carbonate ; Carbonic acid disodium salt, compd. with hydrogen peroxide
(H2O2) (2:3)
CAS NO: 15630-89-4
Molecular Formula: C2H6Na4O12
Molecular Weight: 314.0209
Molecular Structure: .png)
EINECS: 200-158-2
H bond acceptors: 3
H bond donors: 2
Freely Rotating Bonds: 0
Polar Surface Area: 57.53 Å2
Flash Point: 169.8 °C
Enthalpy of Vaporization: 63.37 kJ/mol
Boiling Point: 333.6 °C at 760 mmHg
Vapour Pressure: 2.58E-05 mmHg at 25°C
Sensitive: Moisture Sensitive
Appearance: white granular powder
SMILES: [Na+].[Na+].[Na+].[Na+].[O-]C(=O)[O-].[O-]C([O-])=O.OO.OO.OO
InChI: InChI=1/2CH2O3.4Na.3H2O2/c2*2-1(3)4;;;;;3*1-2/h2*(H2,2,3,4);;;;;3*1-2H/q;;4*+1;;;/p-4
InChIKey: MSLRPWGRFCKNIZ-XBHQNQODAD
Std. InChI: InChI=1S/2CH2O3.4Na.3H2O2/c2*2-1(3)4;;;;;3*1-2/h2*(H2,2,3,4);;;;;3*1-2H/q;;4*+1;;;/p-4
Std. InChIKey: MSLRPWGRFCKNIZ-UHFFFAOYSA-J
Product Categories of Sodium percarbonate (CAS NO.15630-89-4): Inorganics
Uses
Sodium percarbonate (CAS NO.15630-89-4) can be used as a convenient source of anhydrous H2O2, particularly in solvents which cannot dissolve the carbonate but can leach the H2O2 out of it.
Production
Sodium percarbonate (CAS NO.15630-89-4) is easily decomposed by water, so it is produced commercially by reacting powdered anhydrous Na2CO3 with H2O2 dissolved in carbon tetrachloride CCl4. It can be obtained in the laboratory by reacting the two substances in aqueous solution with proper control of the pH or concentrations.
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | oral | 2200mg/kg (2200mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994. |
| rat | LD50 | intraperitoneal | 542mg/kg (542mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994. |
| rat | LD50 | oral | 2400mg/kg (2400mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Toksikologicheskii Vestnik. Vol. (3), Pg. 46, 1994 |
Consensus Reports
Moderately toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.
Safety Profile
Hazard Codes:
O,
Xn
Risk Statements: 8-22-41-36/38
R8: Contact with combustible material may cause fire.
R22: Harmful if swallowed.
R36/38: Irritating to eyes and skin.
R41: Risk of serious damage to the eyes.
Safety Statements: 17-26-37/39
S17: Keep away from combustible material.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
RIDADR: UN 1479 5.1/PG 3
WGK Germany: 1
RTECS: FG0750000
F: 21
HazardClass: 5.1
PackingGroup: II
Standards and Recommendations
Reported in EPA TSCA Inventory.
Specification
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions.
Handling: Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid contact with clothing and other combustible materials.
Storage: Keep away from sources of ignition. Do not store near combustible materials. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

