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Sodium trifluoromethanesulfonate

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Name

Sodium trifluoromethanesulfonate

EINECS N/A
CAS No. 2926-30-9 Density N/A
PSA 65.58000 LogP 1.13220
Solubility soluble in water Melting Point 253-255 °C(lit.)
Formula CF3HSO3Na Boiling Point 162 °C at 760 mmHg
Molecular Weight 172.06 Flash Point N/A
Transport Information N/A Appearance White to off-white powder
Safety 26-37/39 Risk Codes 36/37/38-20/21/22
Molecular Structure Molecular Structure of 2926-30-9 (Sodium trifluoromethanesulfonate) Hazard Symbols IrritantXi
Synonyms

Methanesulfonicacid, trifluoro-, sodium salt (8CI,9CI);Sodium perfluoromethane sulfonate;Sodium triflate;Sodium trifluoromethanesulfonate;Sodiumtrifluoromethylsulfonate;Trifluoromethanesulfonic acid sodium salt;Methanesulfonic acid, 1,1,1-trifluoro-, sodium salt (1:1);Sodium trifluoromethanesulfonate;

Article Data 16

Sodium trifluoromethanesulfonate Specification

The Methanesulfonic acid,1,1,1-trifluoro-, sodium salt (1:1), with the CAS registry number 2926-30-9, has the systematic name of sodium trifluoromethanesulfonate. It is a kind of white to off-white powder, and it is also hygroscopic. The molecular formula of this chemical is CF3HSO3Na. What's more, it is usually used as organic fluorine substituted agent, intermediate of pesticide and medicine.

The physical properties of Methanesulfonic acid,1,1,1-trifluoro-, sodium salt (1:1) are as following: (1)ACD/LogP: -0.37; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -3.87; (4)ACD/LogD (pH 7.4): -3.87; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 3; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 62.75 Å2; (13)Boiling Point: 162 °C at 760 mmHg; (14)Vapour Pressure: 1.14 mmHg at 25°C.

Uses of Methanesulfonic acid,1,1,1-trifluoro-, sodium salt (1:1): It can react with 2-methyl-pyridine to produce N-Fluoro-2-methylpyridinium triflate. This reaction will need reagent 10 % F2-N2, and the solvent acetonitrile. The reaction time is 3 hours with temperature of -40°C, and the yield is about 60%.   

Methanesulfonic acid,1,1,1-trifluoro-, sodium salt (1:1) can react with 2-methyl-pyridine to produce N-Fluoro-2-methylpyridinium triflate

You should be cautious while dealing with this chemical. It irritates eyes, respiratory system and skin, and it is also harmful by inhalation, in contact with skin and if swallowed. Therefore, you had better take the following instructions: Wear suitable gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].FC(F)(F)S([O-])(=O)=O
(2)InChI: InChI=1/CHF3O3S.Na/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
(3)InChIKey: XGPOMXSYOKFBHS-REWHXWOFAP

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