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Succinoyl Peroxide

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Name

Succinoyl Peroxide

EINECS 204-611-5
CAS No. 123-23-9 Density 1.493 g/cm3
PSA 127.20000 LogP -0.28260
Solubility very soluble in water Melting Point 133°C (rough estimate)
Formula C8H10 O8 Boiling Point 453.3 °C at 760 mmHg
Molecular Weight 234.163 Flash Point 183.3 °C
Transport Information UN 2135 Appearance Fine white odorless powder.
Safety An irritant. Explodes on contact with flame. When heated to decomposition it emits acrid smoke and irritating fumes. See also PEROXIDES, ORGANIC. Risk Codes N/A
Molecular Structure Molecular Structure of 123-23-9 (SUCCINIC ACID PEROXIDE) Hazard Symbols Fire risk in contact with combustible materials, oxidizing agent. Toxic by ingestion and inhalation, irritant to skin.
Synonyms

Peroxide,bis(3-carboxypropionyl) (6CI,7CI,8CI);Alfozono;Alphozone;Disuccinic acidperoxide;Disuccinoyl peroxide;NSC 676;Peroxydisuccinic acid;Peroyl SA;Succinic acid peroxide;Succinic monoperoxyanhydride;Succinoyl peroxide;Succinyl peroxide;

Article Data 10

Succinoyl Peroxide Synthetic route

108-30-5

succinic acid anhydride

123-23-9

peroxydicuccinic acid

Conditions
ConditionsYield
With dihydrogen peroxide
With dihydrogen peroxide
With dihydrogen peroxide
123-23-9

peroxydicuccinic acid

81-64-1

1,4-dihydroxy-9,10-anthracenedione

2-(2-carboxyethyl)-1,4-dihydroxy-9,10-anthraquinone

Conditions
ConditionsYield
With boric acid; acetic anhydride at 95 - 98℃; for 5h;79%
123-23-9

peroxydicuccinic acid

158526-26-2

2,5,8-trihydroxy-6,7-dichloro-1,4-naphthoquinone

187149-28-6

3-(6,7-dichloro-3,5,8-trihydroxy-1,4-dioxo-1,4-dihydro-naphthalen-2-yl)-propionic acid

Conditions
ConditionsYield
In tert-butyl alcohol Heating;38%
123-23-9

peroxydicuccinic acid

129-43-1

1-hydroxyanthraquinone

2-(2-carboxyethyl)-1-hydroxy-9,10-anthraquinone

Conditions
ConditionsYield
With boric acid; acetic anhydride at 80℃; for 10h;33%
605-94-7

2,3-Dimethoxy-5-methyl-1,4-benzoquinone

123-23-9

peroxydicuccinic acid

58186-10-0

3-(2,3-Dimethoxy-5-methyl-1,4-benzoquinon-6-yl)propionic acid

Conditions
ConditionsYield
In acetic acid at 90℃; for 4h;32%
56-23-5

tetrachloromethane

123-23-9

peroxydicuccinic acid

A

108-30-5

succinic acid anhydride

B

124-04-9

Adipic acid

83-72-7

2-Hydroxy-1,4-naphthoquinone

123-23-9

peroxydicuccinic acid

3,4-dihydro-benzo[g]chromene-2,5,10-trione

Conditions
ConditionsYield
With methanol; acetic acid
123-23-9

peroxydicuccinic acid

58-27-5

menadione

84978-48-3

3-(3-methyl-1,4-naphthoquinon-2-yl)-propionic acid

Conditions
ConditionsYield
With acetic acid
123-23-9

peroxydicuccinic acid

A

124-04-9

Adipic acid

B

15719-64-9, 15719-76-3, 97762-63-5

methylammonium carbonate

Conditions
ConditionsYield
at 280℃;
123-23-9

peroxydicuccinic acid

54305-79-2

Peroxydisuccinyldichlorid

Conditions
ConditionsYield
With thionyl chloride

Succinoyl Peroxide Consensus Reports

Reported in EPA TSCA Inventory.

Succinoyl Peroxide Specification

Succinoyl Peroxide is also a chemical of molecular forumula C8-H10-O8. Its CAS Registry number is 123-23-9 and it is also called 4,4'-Dioxybis(4-oxobutanoic acid); Alfozono; Alphozone; Bis(3-carboxypropionyl) peroxide; Butanoic acid, 4,4'-dioxybis(4-oxo-; Disuccinic acid peroxide; Disuccinoyl peroxide; Peroxide, bis(3-carboxypropionyl); Peroxydisuccinic acid; Peroyl SA; Succinic acid peroxide; Succinic monoperoxyanhydride; Succinic peroxide. Succinoyl Peroxide is white odorless solid, used as polymerization catalyst, antiseptic, and disinfectant.

Physical properties about Succinoyl Peroxide are: (1)ACD/LogP: -1.001; (2)ACD/LogD (pH 5.5): -3.96; (3)ACD/LogD (pH 7.4): -5.74; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 8 ; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 9; (11)Index of Refraction: 1.496; (12)Molar Refractivity: 45.791 cm3; (13)Molar Volume: 156.805 cm3; (14)Polarizability: 18.153 10-24cm3; (15)Surface Tension: 63.984001159668 dyne/cm; (16)Density: 1.493 g/cm3; (17)Flash Point: 183.27 °C; (18)Enthalpy of Vaporization: 78.109 kJ/mol; (19)Boiling Point: 453.287 °C at 760 mmHg

You can still convert the following datas into molecular structure:
(1)InChI=1S/C8H10O8/c9-5(10)1-3-7(13)15-16-8(14)4-2-6(11)12/h1-4H2,(H,9,10)(H,11,12);
(2)InChIKey=MKTOIPPVFPJEQO-UHFFFAOYSA-N;
(3)SmilesC(OOC(CCC(O)=O)=O)(CCC(O)=O)=O;

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD intraperitoneal > 15600ug/kg (15.6mg/kg)   "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 2, Pg. 302, 1950.

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