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Cas Database |
| Name |
Sulfur bromide fluoride(SBrF5), (OC-6-22)- |
EINECS | N/A |
| CAS No. | 15607-89-3 | Density | 2.098 g/cm3(Temp: 20.1 °C) |
| PSA | 25.30000 | LogP | 3.59480 |
| Solubility | N/A | Melting Point |
-79°C |
| Formula | BrF5 S | Boiling Point | 3.1°C |
| Molecular Weight | 206.962 | Flash Point | N/A |
| Transport Information | N/A | Appearance | N/A |
| Safety | Risk Codes | N/A | |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Sulfurbromide fluoride (SBrF5) (7CI,8CI); Bromopentafluorosulfur; Pentafluorosulfurbromide; Sulfur bromide pentafluoride |
Article Data | 3 |
Sulfur bromide fluoride(SBrF5), (OC-6-22)- Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| byproducts: SF6, SF4; 150°C, 16 h, procedure described by T. A. Kovacina, A. D. Berry,and W. B. Fox, J. Fluorine Chem., 7,430, (1976); trap-to-trap fractionation (-63°C, -116°C, -196°C), addn. of Hg to the trap at 0°C; | 85% |
| In neat (no solvent) reaction; distn.; |
- 112043-76-2
SF5N(Br)CF3
- 15607-89-3
pentafluorosulfanyl bromide
Conditions
| Conditions | Yield |
|---|---|
| With CO In neat (no solvent) byproducts: CF3N=C=O, Br2; excess CO, room temp., 4 d; fractional distn., mixt. of SF5Br/CF3N=C=O not separated; |
- 15607-89-3
pentafluorosulfanyl bromide
- 79410-50-7
Perfluoro-n-butanesulfonyl hypochlorite
- 79410-59-6
pentafluoro(nonafluorobutanesulfonato)sulfur(VI)
Conditions
| Conditions | Yield |
|---|---|
| -111 to 0°C; | 80% |
| -111 to 0°C; | 80% |
Conditions
| Conditions | Yield |
|---|---|
| With CsF In neat (no solvent) byproducts: Br2, SOF4, SF4; Irradiation (UV/VIS); mixt. irradiated for 12 h; condensed at -196°C; warmed to -78°C; volatiles transferred into cylinder cooled to -196°C cntg.CsF; distilled through -78, -130, -196°C traps; recovered from -130°C trap; | 3% |
- 15607-89-3
pentafluorosulfanyl bromide
- 612-17-9
1,4-dihydronaphthalene
- 880871-79-4
3-bromo-2-pentafluorosulfanyl-1,2,3,4-tetrahydro-naphthalene
Conditions
| Conditions | Yield |
|---|---|
| With potassium fluoride; triethyl borane In hexanes; pentane at -50℃; for 2h; |
- 15607-89-3
pentafluorosulfanyl bromide
A
- 10546-01-7
sulfurpentafluoride
B
- 10035-10-6, 12258-64-9
hydrogen bromide
Conditions
| Conditions | Yield |
|---|---|
| In gaseous matrix Kinetics; reaction of H (produced on microwave discharge) and SF5Br in Ar; not isolated; |
- 15607-89-3
pentafluorosulfanyl bromide
- 40779-99-5
Lithium; 2,3,4,5,6-pentafluoro-benzenethiolate
A
- 1494-06-0
bis(pentafluorophenyl) disulfide
B
- 52082-75-4
bis(pentafluorophenyl)trisulfane
Conditions
| Conditions | Yield |
|---|---|
| In gaseous matrix Kinetics; byproducts: SF5; Xe/Ar mixt. flowing through inner tube and SF5Br/Ar mixt. through outertube of flowing afterglow reactor (coaxial mixing type), combined gas flows passing through rolled tantalum electrodes (ca. 0.7 cm diam., sepd.by ca. 1 cm, 200-250 V); |
- 15607-89-3
pentafluorosulfanyl bromide
- 1076-44-4
pentafluorophenyl lithium
- 26346-84-9
bis(pentafluorophenyl) sulfoxide
Conditions
| Conditions | Yield |
|---|---|
| In diethyl ether -78°C, 5 h; | 50-60 |
- 15607-89-3
pentafluorosulfanyl bromide
- 13997-93-8
bromine(I) fluorosulfate
- 81439-35-2
pentafluorosulfur fluorosulfonate
Conditions
| Conditions | Yield |
|---|---|
| In not given BrSO3F was reacted with SF5Br according to Johri, K. K.; Katsuhara, Y.; DesMarteau, D. D.; J. Fluorine Chem. 1982, 19, 227; |
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