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Tantalum fluoride

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Name

Tantalum fluoride

EINECS 232-022-3
CAS No. 7783-71-3 Density 4.74 g/cm3
PSA 0.00000 LogP 2.10100
Solubility Soluble in water, ether, slightly soluble in hot carbon disulfide, carbon tetrachloride and cold concentrated sulfuric acid Melting Point 96.8 °C
Formula F5Ta Boiling Point 229.5 °C
Molecular Weight 275.94 Flash Point 230 °C
Transport Information UN 3260 8/PG 2 Appearance white crystalline powder
Safety 26-27-28-36/37/39-45 Risk Codes 34
Molecular Structure Molecular Structure of 7783-71-3 (TANTALUM PENTAFLUORIDE) Hazard Symbols CorrosiveC
Synonyms

Tantalumfluoride;Tantalum pentafluoride;Tantalum(V) fluoride;

Article Data 52

Tantalum fluoride Synthetic route

tantalum(V) oxide

353-50-4

Carbonyl fluoride

A

7783-71-3

tantalum pentafluoride

B

124-38-9

carbon dioxide

Conditions
ConditionsYield
In neat (no solvent) slight excess over the stoich. amt. of COF2 required; reaction mixt. heated in a stainless steel or monel cylinder at 210°C for 46 h;A 100%
B n/a

tantalum

7664-39-3

hydrogen fluoride

A

7783-71-3

tantalum pentafluoride

B

13814-17-0

tantalum trifluoride

Conditions
ConditionsYield
300 °C;A 90%
B n/a
300 °C;A 90%
B n/a
300 °C;A 90%
B n/a

3BaF2*2TaF5

7783-71-3

tantalum pentafluoride

Conditions
ConditionsYield
2 h at 1000 °C;70%
2 h at 1000 °C;70%

tantalum

stannous fluoride

B

7783-71-3

tantalum pentafluoride

Conditions
ConditionsYield
In melt placing of mixt. of Ta with SnF2 (molar ratio SnF2:Ta=1.46) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.00 h at 240°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;A 9.2%
B n/a

tantalum

7790-91-2

chlorine trifluoride

7783-71-3

tantalum pentafluoride

Conditions
ConditionsYield
In neat (no solvent) at ambient temp.;;
heating in quartz vessel; excess ClF3 is washed out by liq. HF;
In neat (no solvent) reaction with formation of heat;;
In neat (no solvent) reaction with formation of heat;;
heating in quartz vessel; excess ClF3 is washed out by liq. HF;

tantalum

7664-39-3

hydrogen fluoride

7783-71-3

tantalum pentafluoride

Conditions
ConditionsYield
Kinetics; 473-593 K, 0.1-0.3 atm of HF;
In water byproducts: H2; concd. HF;;

tantalum

7664-39-3

hydrogen fluoride

A

7783-71-3

tantalum pentafluoride

B

1333-74-0

hydrogen

Conditions
ConditionsYield
With dihydrogen hexachloroplatinate In water byproducts: Pt; In presence of H2PtCl6 complete reaction at ambient temp. within a few minutes; H2PtCl6 is reduced to form Pt;;A >99
B n/a

tantalum

7782-41-4

fluorine

7783-71-3

tantalum pentafluoride

Conditions
ConditionsYield
in a quartz system;
in monel or Ni tube at about 300 °C; sepn. of products by cooling, then purifn. by sublimation;
In gaseous matrix Ta was reacted with F2 at 230-1200°C in Ar matrix; monitored by IR;

tantalum(V) oxide

7664-39-3

hydrogen fluoride

7783-71-3

tantalum pentafluoride

tantalum(V) oxide

7664-39-3

hydrogen fluoride

A

7783-71-3

tantalum pentafluoride

B

tantalum(V) dioxide fluoride

Conditions
ConditionsYield
200 to 500°C;

Tantalum fluoride Consensus Reports

Reported in EPA TSCA Inventory.

Tantalum fluoride Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m3
ACGIH TLV: TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: TWA 2.5 mg(F)/m3

Tantalum fluoride Specification

The Tantalum fluoride with CAS registry number of 7783-71-3 is also known as Tantalum(V) fluoride. The IUPAC name is Pentafluorotantalum. It belongs to product categories of Tantalum Salts; Catalysis and Inorganic Chemistry; Chemical Synthesis; Salts; TantalumMetal and Ceramic Science. Its EINECS registry number is 232-022-3. In addition, the formula is F5Ta and the molecular weight is 275.94. This chemical is a white crystalline powder and should be stored in sealed containers in cool and dry place.

Physical properties about Tantalum fluoride are: (1)H-Bond Acceptor: 5; (2)Exact Mass: 275.940012; (3)MonoIsotopic Mass: 275.940012; (4)Heavy Atom Count: 6; (5)Complexity: 37.1; (6)Covalently-Bonded Unit Count: 1.

Preparation of Tantalum fluoride: it is prepared by reaction of tantalum(V) chloride with anhydrous hydrofluoric acid. Solid tantalum pentafluoride is obtained by condensation and filtration separation of the reaction mixture. Then the solid is sublimated in a vacuum to generate product.

TaCl5+5HF→TaF5+5HCl

Uses of Tantalum fluoride: it is used for chemical vapor deposition of tantalum and ion implantation doping. What's more, it is used as organic synthesis catalyst.

When you are using this chemical, please be cautious about it. As a chemical, it may cause burns. During using it, wear suitable protective clothing, gloves and eye/face protection. After contact with skin, take off immediately all contaminated clothing, and wash immediately. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If accident happens or you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
1. Canonical SMILES: F[Ta](F)(F)(F)F
2. InChI: InChI=1S/5FH.Ta/h5*1H;/q;;;;;+5/p-5
3. InChIKey: YRGLXIVYESZPLQ-UHFFFAOYSA-I

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