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Name |
Tellurium hexafluoride |
EINECS | 232-027-0 |
CAS No. | 7783-80-4 | Density | (solid; -191°) 4.006; d (liq; -10°) 2.499 |
PSA | 0.00000 | LogP | 2.14040 |
Solubility | slowly mixes with H2O, hydrolyzing to telluric acid [MER06] | Melting Point |
-37 |
Formula | TeF6 | Boiling Point | -38,9°C |
Molecular Weight | 241.59 | Flash Point | N/A |
Transport Information | N/A | Appearance | N/A |
Safety | 3/7-9-36/37/39-45 | Risk Codes | 20-31-34 |
Molecular Structure | Hazard Symbols | T | |
Synonyms |
Telluriumfluoride (TeF6) (6CI,7CI,8CI);Hexafluorotellurium;Tellurium hexafluoride;hexafluoro-λ6-tellane; |
Article Data | 30 |
Conditions | Yield |
---|---|
In neat (no solvent) KTeF5O was treated with F2 (molar ratio 1:3.11) for 6 wk at -45°C; | A 0% B 80% |
In neat (no solvent) KTeF5O was treated with F2 (molar ratio 1:3.11) for 8 d at -45°C; | A 0% B 26% |
Conditions | Yield |
---|---|
In neat (no solvent) a mixture of TeO2:Te=1:1 was treated with F2 (4 l/h) dild. with N2 (10 l/h) at a furnace temp. of 50-60°C;; | A 25% B 2% C 73% |
In neat (no solvent) a mixture of TeO2:Te=1:1 was treated with F2 (4 l/h) dild. with O2 (10 l/h) at a furnace temp. of 50-60°C; the yield of Te2F10 is almost 50%;; |
fluorosulfuryl hypofluorite
A
teflic acid
B
TeF5OF
C
tellurium hexafluoride
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: CsSO3F; CsTeF5O was evacuated and cooled to -196°C, FOSO2F (molar ratio 1.22:1) was added from vac. line, closed, warmed slowly to -78°C in liq. N2-CO2 slush bath, kept at -45°C for 9 d, cooled to -196°C; pumped off, sepd. by fractional condensation in traps (-78, -126 and -196°C); | A n/a B 68% C n/a |
titanium(IV) tetrakis(pentafluoroorthotellurate)
A
titanium oxyfluoride
B
F5TeOTeF5
C
F5Te(OTeF4)OTeF5
D
tellurium hexafluoride
Conditions | Yield |
---|---|
heated at 250°C for 15 h in autoclave; | A 19% B 26% C 51% D 3.9% |
Conditions | Yield |
---|---|
In neat (no solvent) CsTeF5O was treated with F2 (molar ratio 1:3.11) for 2 wk at -10°C; | A 0% B 48% |
In neat (no solvent) CsTeF5O was treated with F2 (molar ratio 1:3.11) for 8 d at -45°C; | A 0% B 26% |
tellurium(IV) oxide
boron trifluoride
C
tellurium hexafluoride
D
tellurium(IV) fluoride
Conditions | Yield |
---|---|
In neat (no solvent) TeO2 was treated with a continous stream of BF3 with He as carrier gas at 100-450°C;; | |
In neat (no solvent) TeO2 was treated with a continous stream of BF3 with He as carrier gas at 100-450°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) TeO2 was treated with F2 (0.5-10 l/h) dild. with N2 (0-5 l/h) at a furnace temp. of 100-200°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) distd. Te; with inflammation;; |
Conditions | Yield |
---|---|
In neat (no solvent) product mixture of TeF6 and lower tellurium fluorides;; | |
In neat (no solvent) from F2 and Te in very dry glass apparatus; 10-15 hours; on cooling since begin of reaction no inflammation;; | |
In neat (no solvent) passing pure F2 (purified from HF by waterfree NaF in copper tube) over Te in copper tube (1.5l F2 / hour; no explosion);; condensation on cooling with carbon dioxide-alc.-freezing mixture in Pyrex glass vessel; fractionated sublimation in vac.;; |
fluorine
A
tellurium hexafluoride
B
tungsten(VI) fluoride
C
tellurium(IV) fluoride
Conditions | Yield |
---|---|
In neat (no solvent) WTe2 placed in a tungsten saucer, addn. of a small amt. of sulfur as fuse, react. with fluorine in a prefluorinated perforated nickel crucible; |
EPA Extremely Hazardous Substances List. Reported in EPA TSCA Inventory.
OSHA PEL: TWA 0.02 ppm (Te)
ACGIH TLV: TWA 0.02 ppm (Te)
DOT Classification: 2.3; Label: Poison Gas
The Tellurium hexafluoride, with the CAS registry number 7783-80-4 and EINECS registry number 232-027-0, has the systematic name of hexafluoro-λ6-tellane. And the molecular formula of this chemical is TeF6. It is a colorless, highly toxic gas with an extremely unpleasant smell. And it is often used as chemical medicine.
The physical properties of Tellurium hexafluoride are as following: (1)ACD/LogP: -1.94; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): -1.94; (4)ACD/LogD (pH 7.4): -1.94; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 2.1; (8)ACD/KOC (pH 7.4): 2.1; (9)#H bond acceptors: 9; (10)#H bond donors: 5; (11)#Freely Rotating Bonds: 12; (12)Polar Surface Area: 83.07 Å2; (13)Index of Refraction: 1.622; (14)Molar Refractivity: 92.74 cm3; (15)Molar Volume: 263 cm3; (16)Polarizability: 36.76×10-24cm3; (17)Surface Tension: 59.4 dyne/cm; (18)Density: 1.415 g/cm3; (19)Flash Point: 342.4 °C; (20)Enthalpy of Vaporization: 99.67 kJ/mol; (21)Boiling Point: 642.6 °C at 760 mmHg; (22)Vapour Pressure: 2.17E-17 mmHg at 25°C.
Properties of Tellurium hexafluoride: It is a highly symmetric octahedral molecule, and its physical properties resemble the sulfur and selenium analogs. Due to the increase in molecular weight, it is less volatile. At temperatures below -38 °C, this chemical condenses to a volatile white solid.
Preparation of Tellurium hexafluoride: It can be prepared by passing fluorine gas over tellurium metal at 150 °C. It can also be prepared by passing fluorine gas over TeO3 or indirectly by reacting TeO2 with SeF4 to produce TeF4 and then heating TeF4 in excess of 200 °C to make TeF6 and Te.
You should be cautious while dealing with this chemical. It is harmful by inhalation, and it may also cause burns. Besides, if contact with acids, it will liberate toxic gas. Therefore, you had better take the following instructions: Keep container tightly closed in a cool place; Keep container in a well-ventilated place; Wear suitable protective clothing, gloves and eye/face protection; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: F[Te](F)(F)(F)(F)F
(2)InChI: InChI=1/F6Te/c1-7(2,3,4,5)6
(3)InChIKey: NNCGPRGCYAWTAF-UHFFFAOYAP
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
guinea pig | LCLo | inhalation | 5ppm/4H (5ppm) | LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA | Archiv fuer Toxikologie. Vol. 18, Pg. 140, 1960. |
mouse | LCLo | inhalation | 5ppm/1H (5ppm) | LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA | Archiv fuer Toxikologie. Vol. 18, Pg. 140, 1960. |
rabbit | LCLo | inhalation | 5ppm/4H (5ppm) | LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA | Archiv fuer Toxikologie. Vol. 18, Pg. 140, 1960. |
rat | LCLo | inhalation | 5ppm/4H (5ppm) | LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA | Archiv fuer Toxikologie. Vol. 18, Pg. 140, 1960. |