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Tert-butylmagnesium chloride

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Name

Tert-butylmagnesium chloride

EINECS 211-638-6
CAS No. 677-22-5 Density 0.931 g/mL at 25 °C
PSA 0.00000 LogP 2.44360
Solubility Miscible with alcohol and water. Melting Point 46oC to 50oC
Formula C4H9ClMg Boiling Point 34 °F
Molecular Weight 116.873 Flash Point 34 °F
Transport Information UN 3399 4.3/PG 1 Appearance clear faint grey to grey, grey-brown or light
Safety UN 3399 4.3/PG 1 Risk Codes 12-14/15-19-22-34-66-67-15-11-14
Molecular Structure Molecular Structure of 677-22-5 (TERT-BUTYLMAGNESIUM CHLORIDE) Hazard Symbols HighlyF+;CorrosiveC;FlammableF
Synonyms

Magnesium,tert-butylchloro- (7CI,8CI);tert-Butylmagnesium chloride (6CI);(1,1-Dimethylethyl)magnesium chloride;t-Butylmagnesium chloride;tert-Butylchloromagnesium;tert-butylmagnesium chloride;

Article Data 22

Tert-butylmagnesium chloride Chemical Properties

IUPAC Name: Magnesium 2-methylpropane chloride
Synonyms of Magnesium,chloro(1,1-dimethylethyl)- (CAS NO.677-22-5): Magnesium(1+), (1,1-dimethylethyl)-, chloride (1:1) ; tert-Butylmagnesium(1+) chloride
Molecular Structure:
Molecular Formula: C4H9ClMg
Molecular Weight: 116.8723
CAS NO: 677-22-5
EINECS: 211-638-6 
Density: 0.931 g/mL at 25 °C
Flash Point: 34 °F
Storage temp: 2-8°C
Appearance: clear faint grey to grey, grey-brown or light
SMILES: [Cl-].[Mg+]C(C)(C)C
InChI: InChI=1/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1/rC4H9Mg.ClH/c1-4(2,3)5;/h1-3H3;1H/q+1;/p-1 Copy
InChIKey: ZDRJSYVHDMFHSC-DHKKDVNOAZ
Std. InChI: InChI=1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1
Std. InChIKey: ZDRJSYVHDMFHSC-UHFFFAOYSA-M
Product Categories of Magnesium,chloro(1,1-dimethylethyl)- (CAS NO.677-22-5): Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents

Tert-butylmagnesium chloride Safety Profile

Safety Information of Magnesium,chloro(1,1-dimethylethyl)- (CAS NO.677-22-5):
Hazard Codes: HighlyF+F ,CorrosiveC
Risk Statements: 12-14/15-19-22-34-66-67-15-11
R11: Highly flammable. 
R12: Extremely flammable. 
R14/15: Reacts violently with water, liberating extremely flammable gases 
R19: May form explosive peroxides. 
R22: Harmful if swallowed. 
R34: Causes burns. 
R66: Repeated exposure may cause skin dryness or cracking. 
R67: Vapours may cause drowsiness and dizziness.
Safety Statements: 9-16-26-29-33-36/37/39-43-45
RIDADR UN: 3399 4.3/PG 1
WGK Germany: 1
F: 1-3-10

Tert-butylmagnesium chloride Specification

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor. May form explosive peroxides.
Extinguishing Media: Use approved class D extinguishing agents or smother with dry sand, clay, or sodium bicarbonate. DO 
Handling: Do not allow water to get into the container because of violent reaction. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Do not store in direct sunlight. Store in a tightly closed container. Store in a dry area. Flammables-area. Water free area. Store under nitrogen. Store at room temperature.

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