The Thiophosphoryl chloride, with the CAS registry number 3982-91-0 and EINECS registry number 223-622-6, has the systematic name of phosphorothioic trichloride. It is a kind of is a fuming, colorless liquid with a pungent odor, and belongs to the product category of Inorganic Chemicals. It is soluble in benzene, carbon tetrachloride, chloroform, and carbon disulfide. And the molecular formula of this chemical is Cl₃PS. What's more, it is used to prepare thiophosphorylate organic compounds, such as to produce insecticides.

The physical properties of Thiophosphoryl chloride are as following: (1)ACD/LogP: 0.99; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.994; (4)ACD/LogD (pH 7.4): 0.994; (5)ACD/BCF (pH 5.5): 3.355; (6)ACD/BCF (pH 7.4): 3.355 ; (7)#H bond acceptors: 0; (8)#H bond donors: 0; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 41.9 Å²; (11)Index of Refraction: 1.562; (12)Molar Refractivity: 30.73 cm³; (13)Molar Volume: 94.705 cm³; (14)Polarizability: 12.182×10^-24cm³; (15)Surface Tension: 57.747 dyne/cm; (16)Density: 1.789 g/cm³; (17)Flash Point: °CEnthalpy of ; (18)Vaporization: 34.789 kJ/mol; (19)Boiling Point: 125 °C at 760 mmHg; (20)Vapour Pressure: 15.031 mmHg at 25°C. 

Preparation of Thiophosphoryl chloride: The most common and practical synthesis of the chemcial, which is also used in industrial manufacturing, is directly reacting phosphorus trichloride with excess sulfur at 180 °C.
PCl₃ + S → PSCl₃

Uses of Thiophosphoryl chloride: It can hydrolyze rapidly in basic or hydroxylic solutions, such as alcohols and amines, to produce thiophosphates.
PSCl₃ + 4H₂O → H₃PO₄ + H₂S + 3HCl
PSCl₃ + H₂O → HOP(S)Cl₂ + HCl

You should be cautious while dealing with this chemical. It is harmful if swallowed, and may also cause burns. It is also harmful to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer); In case of accident or if you feel unwell, seek medical advice immediately (show label where possible); Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: P(=S)(Cl)(Cl)Cl
(2)InChI: InChI=1/Cl3PS/c1-4(2,3)5
(3)InChIKey: WQYSXVGEZYESBR-UHFFFAOYAE

The toxicity data is as follows: