Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Tributylamine

Related Products

Hot Products

Name

Tributylamine

EINECS 203-058-7
CAS No. 102-82-9 Density 0.792 g/cm3
PSA 3.24000 LogP 3.68870
Solubility 0.386 g/L (25 °C) in water Melting Point -70 °C(lit.)
Formula C12H27N Boiling Point 215.3 °C at 760 mmHg
Molecular Weight 185.353 Flash Point 63.3 °C
Transport Information UN 2542 6.1/PG 2 Appearance pale yellow liquid with an amine odour
Safety 26-36/37-45-61-36/37/39-28A Risk Codes 22-23/24-38-51/53-23/24/25
Molecular Structure Molecular Structure of 102-82-9 (Tributylamine) Hazard Symbols ToxicT,DangerousN
Synonyms

Tributylamine(7CI,8CI);N,N-Dibutyl-1-butanamine;Tri-n-butylamine;Tris-n-butylamine;Tributylamine;

Article Data 141

Tributylamine Synthetic route

111-92-2

dibutylamine

123-72-8

butyraldehyde

102-82-9

tributyl-amine

Conditions
ConditionsYield
With polymethylhydrosiloxane; bis(1,5-cyclooctadiene)diiridium(I) dichloride In tetrahydrofuran at 50℃; for 5h;99%
With NiO doped titania In butan-1-ol Reagent/catalyst; Irradiation;93%
With hydrogen; nickel at 120 - 140℃;
71-36-3

butan-1-ol

102-82-9

tributyl-amine

Conditions
ConditionsYield
With C42H44ClN4P2Ru(1+)*Cl(1-); potassium tert-butylate; ammonium formate at 100℃; for 72h;95%
With 1-hydroxytetraphenylcyclopentadienyl(tetraphenyl-2,4-cyclopentadien-1-one)-μ-hydrotetracarbonyldiruthenium(II); ammonium chloride; potassium hydroxide at 140℃; for 39h; Sealed tube; Inert atmosphere;99 %Chromat.
7529-21-7

tributylamine N-oxide

102-82-9

tributyl-amine

Conditions
ConditionsYield
With BER-CuSO4 In methanol for 3h; Ambient temperature;93%
With Dimethylphenylsilane In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;88%
With bis(tri-n-butyltin) In tetrahydrofuran at 50℃; for 1h;84%
With BER-CuSO4 In methanol for 3h; Ambient temperature; other tertiary amine N-oxides and aromatic N-oxides, var. temp. and time;
109-74-0

propyl cyanide

111-87-5

octanol

71-36-3

butan-1-ol

A

102-82-9

tributyl-amine

B

41145-51-1

octyldibutylamine

Conditions
ConditionsYield
With hydrogen; copper at 240℃; under 7600 Torr;A n/a
B 92%
109-65-9

1-bromo-butane

102-82-9

tributyl-amine

Conditions
ConditionsYield
With 5-methyl-1,3,4-thiadiazol-2-amine; potassium hydroxide In ethanol; water at 25℃; for 1h;85%
With sodium hydroxide; urea at 120℃; under 3102.97 Torr; for 40h;76.5%
With ammonia
110-68-9

N-n-butyl-N-methylamine

A

102-82-9

tributyl-amine

B

927-62-8

N,N-dimethylbutylamine

Conditions
ConditionsYield
palladium at 160℃; for 5h;A 8%
B 85%
109-74-0

propyl cyanide

71-36-3

butan-1-ol

143-08-8

nonyl alcohol

A

102-82-9

tributyl-amine

B

93658-58-3

1-Dibutylamino-nonan

Conditions
ConditionsYield
With hydrogen; copper at 240℃; under 7600 Torr;A n/a
B 85%
109-74-0

propyl cyanide

A

102-82-9

tributyl-amine

B

butyl-1-idene-di-n-butylamine

C

111-92-2

dibutylamine

Conditions
ConditionsYield
With hydrogen at 200℃;A 13%
B 2%
C 85%
109-74-0

propyl cyanide

112-30-1

1-Decanol

71-36-3

butan-1-ol

A

102-82-9

tributyl-amine

B

N,N-dibutyldecan-1-amine

Conditions
ConditionsYield
With hydrogen; copper at 240℃; under 7600 Torr;A n/a
B 84%
111-92-2

dibutylamine

102-82-9

tributyl-amine

Conditions
ConditionsYield
With chlorohydridocarbonylbis(tricyclohexylphosphine)ruthenium(II) In toluene at 120℃; for 24h; Catalytic behavior; Reagent/catalyst; Schlenk technique; Inert atmosphere;82%
With aluminium trichloride
With palladium/alumina at 199.84℃; under 760.051 Torr; Kinetics;

Tributylamine Chemical Properties

:

Tributylamine Specification

The Tributylamine is an organic compound with the formula C12H27N. The IUPAC name of this chemical is N,N-dibutylbutan-1-amine. With the CAS registry number 102-82-9, it is also named as 1-butanamine, N,N-dibutyl-. The product's categories are Amines; C11 to C38; Nitrogen Compounds; Analytical Reagents for General Use; Puriss p.a. ACS; T-Z, Puriss p.a. ACS. Besides, it is pale yellow liquid with an amine odour, which should be stored in a cool and well-ventilated place. It is used as oil additives, solvents, pharmaceutical intermediates, pesticides, emulsifier, plasticizer, mineral flotation agent and surface active agent.

Physical properties about Tributylamine are:
(1)ACD/LogP: 4.85; (2)ACD/LogD (pH 5.5): 1.76; (3)ACD/LogD (pH 7.4): 2.37; (4)ACD/BCF (pH 5.5): 2.34; (5)ACD/BCF (pH 7.4): 9.55; (6)ACD/KOC (pH 5.5): 8.51; (7)ACD/KOC (pH 7.4): 34.7; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 9; (10)Polar Surface Area: 3.24 Å2; (11)Index of Refraction: 1.437; (12)Molar Refractivity: 61.36 cm3; (13)Molar Volume: 233.8 cm3; (14)Polarizability: 24.32×10-24cm3; (15)Surface Tension: 27.4 dyne/cm; (16)Density: 0.792 g/cm3; (17)Flash Point: 63.3 °C; (18)Enthalpy of Vaporization: 45.16 kJ/mol; (19)Boiling Point: 215.3 °C at 760 mmHg; (20)Vapour Pressure: 0.149 mmHg at 25°C.

Preparation of Tributylamine:
This chemical can be prepared by butyl-methyl-amine. This reaction will need catalyst palladium black. The reaction time is 5 hours with reaction temperature of 160 °C. The yield is about 85%.
Preparation of Tributylamine

Uses of Tributylamine:
 It can be used to produce methyl methyltributylammonium sulfate. The reaction time is 3 hours with reaction temperature of 80 °C. The yield is about 84.6%.
Uses of Tributylamine

When you are using Tributylamine, please be cautious about it as the following:
It is harmful if swallowed and toxic by inhalation, in contact with skin and if swallowed. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical is irritating skin and toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable gloves and eye/face protection and avoid release to the environment. Refer to special instructions/safety data sheet. After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer). In case of accident or if you feel unwell seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: N(CCCC)(CCCC)CCCC
(2)InChI: InChI=1/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
(3)InChIKey: IMFACGCPASFAPR-UHFFFAOYAY
(4)Std. InChI: InChI=1S/C12H27N/c1-4-7-10-13(11-8-5-2)12-9-6-3/h4-12H2,1-3H3
(5)Std. InChIKey: IMFACGCPASFAPR-UHFFFAOYSA-N

The toxicity data of Tributylamine is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LD50 oral 350mg/kg (350mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(12), Pg. 36, 1977.
mammal (species unspecified) LD50 intraperitoneal 107mg/kg (107mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: EXCITEMENT
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(11), Pg. 50, 1984.
mammal (species unspecified) LD50 oral 888mg/kg (888mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: EXCITEMENT
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 28(11), Pg. 50, 1984.
mouse LD50 oral 114mg/kg (114mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(12), Pg. 36, 1977.
rabbit LD50 oral 615mg/kg (615mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 42(12), Pg. 36, 1977.
rabbit LD50 skin 250uL/kg (0.25mL/kg)   Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat LCLo inhalation 75ppm/4H (75ppm)   Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974.
rat LD50 oral 114mg/kg (114mg/kg)   Trudy Leningradskogo Sanitarno-Gigienicheskogo Meditsinskogo Instituta. Vol. 115, Pg. 57, 1977.
rat LDLo subcutaneous 380mg/kg (380mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: COMA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
Journal of Pharmacology and Experimental Therapeutics. Vol. 20, Pg. 435, 1923.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 102-82-9