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Tridodecylamine
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Name

Tridodecylamine

 EINECS 203-063-4
CAS No. 102-87-4 Density 0.828 g/cm3
PSA 3.24000 LogP 13.05110
Solubility Not miscible or difficult to mix with water. Melting Point 16 °C
Formula C36H75N Boiling Point 544.6 °C at 760 mmHg
Molecular Weight 521.998 Flash Point 256.6 °C
Transport Information N/A Appearance clear slightly yellow liquid
Safety 26-36 Risk Codes 36/37/38
Molecular Structure Molecular Structure of 102-87-4 (TRIDODECYLAMINE) Hazard Symbols IrritantXi
Synonyms

Tridodecylamine(6CI,8CI);Adogen 360;Alamine 304;Alamine 304-1;Armeen 312;N,N-Didodecyl-1-dodecanamine;NSC 35134;Tri-n-dodecylamine;Trilaurylamine;Tris(dodecyl)amine;

Article Data 13

Tridodecylamine Synthetic route

124-22-1

n-Dodecylamine

A

3007-31-6

N,N-didodecylamine

B

102-87-4

tridodecylamine

Conditions
ConditionsYield
With Co2Rh2/C In toluene at 180℃; under 760.051 Torr; for 6h; Temperature; Time; Solvent; Autoclave; Inert atmosphere;A 86%
B 5%
With ruthenium trichloride; triphenylphosphine In tetrahydrofuran at 235℃; for 8h;A 26 % Chromat.
B 52%
With ruthenium trichloride; triphenylphosphine In tetrahydrofuran at 235℃; for 8h; Title compound not separated from byproducts;A 67 % Chromat.
B 30 % Chromat.
With tris(triphenylphosphine)ruthenium(II) chloride In methanol at 180℃; for 7h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
2437-25-4

undecyl cyanide

A

3007-31-6

N,N-didodecylamine

B

102-87-4

tridodecylamine

Conditions
ConditionsYield
With hydrogen; silica gel; copper at 160℃; under 33002.6 Torr; for 2.69444h; Product distribution; Rate constant; other temperatures, other catalysts;A 84%
B n/a
With methanol; hydrogen at 249.9℃; under 37503 Torr; for 25h;A 15%
B 60 % Chromat.
With methanol; hydrogen; aluminum oxide; copper-chromium powder at 249.9℃; under 37503 Torr; for 25h;A 48 % Chromat.
B 5 % Chromat.
124-22-1

n-Dodecylamine

143-15-7

1-dodecylbromide

102-87-4

tridodecylamine

Conditions
ConditionsYield
With sodium carbonate In ethanol for 144h; Heating;22.6%
4292-19-7

1-Iodododecane

3007-31-6

N,N-didodecylamine

102-87-4

tridodecylamine

Conditions
ConditionsYield
at 160 - 170℃;
4292-19-7

1-Iodododecane

A

3007-31-6

N,N-didodecylamine

B

102-87-4

tridodecylamine

Conditions
ConditionsYield
With ammonia; water
3007-31-6

N,N-didodecylamine

112-52-7

1-chlorododecane

102-87-4

tridodecylamine

Conditions
ConditionsYield
at 160 - 170℃;
67-56-1

methanol

111-82-0

methyl n-dodecanoate

A

124-22-1

n-Dodecylamine

B

112-18-5

N,N-dimethylaminododecane

C

7311-30-0

N-methyldodecylamine

D

3007-31-6

N,N-didodecylamine

E

2915-90-4

N-methyldidodecylamine

F

102-87-4

tridodecylamine

Conditions
ConditionsYield
With ammonia; hydrogen; copper-chromium powder; titanium(IV) oxide at 250℃; under 37503 Torr; Product distribution; other catalyst; var. temp., pressure, and reagents ratio;A 31.9 % Chromat.
B 20.0 % Chromat.
C 30.7 % Chromat.
D 2.5 % Chromat.
E 2.0 % Chromat.
F 2.0 % Chromat.
...Expand
111-82-0

methyl n-dodecanoate

A

124-22-1

n-Dodecylamine

B

3007-31-6

N,N-didodecylamine

C

102-87-4

tridodecylamine

Conditions
ConditionsYield
With methanol; ammonia; hydrogen; copper-chromium powder; titanium(IV) oxide at 250℃; under 37503 Torr;A 31.9 % Chromat.
B 2.5 % Chromat.
C 2.0 % Chromat.
112-53-8

1-dodecyl alcohol

A

102-87-4

tridodecylamine

B

didodecylamine; dodecylamine

didodecylamine; dodecylamine

Conditions
ConditionsYield
With aluminium silicate; ammonia at 350℃;

tridodecyl-amine; compound with 2,4,6-trichloro-phenol

A

102-87-4

tridodecylamine

B

88-06-2

2,4,6-Trichlorophenol

Conditions
ConditionsYield
In tetrachloromethane at 25℃; Equilibrium constant;

Tridodecylamine Specification

The 1-Dodecanamine,N,N-didodecyl-, with the CAS registry number 102-87-4, is also known as Tri-n-dodecylamine. Its EINECS registry number is 203-063-4. This chemical's molecular formula is C36H75N and molecular weight is 521.9874. Its IUPAC name is called N,N-didodecyldodecan-1-amine. This chemical is clear slightly yellow liquid.

Physical properties of 1-Dodecanamine,N,N-didodecyl-: (1)ACD/LogP: 17.60; (2)# of Rule of 5 Violations: 2; (3)ACD/LogD (pH 5.5): 14.52; (4)ACD/LogD (pH 7.4): 15.24; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 10000000; (8)ACD/KOC (pH 7.4): 10000000; (9)#H bond acceptors: 1; (10)#Freely Rotating Bonds: 33; (11)Index of Refraction: 1.459; (12)Molar Refractivity: 172.55 cm3; (13)Molar Volume: 630 cm3; (14)Surface Tension: 31.2 dyne/cm; (15)Density: 0.828 g/cm3; (16)Flash Point: 256.6 °C; (17)Enthalpy of Vaporization: 82.33 kJ/mol; (18)Boiling Point: 544.6 °C at 760 mmHg; (19)Vapour Pressure: 6.41E-12 mmHg at 25°C.

Uses of 1-Dodecanamine,N,N-didodecyl-: it can be used to produce tridodecylamine oxide. This reaction will need reagent H2O2 and solvent H2O, methanol. The yield is about 85%.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC
(2)InChI: InChI=1S/C36H75N/c1-4-7-10-13-16-19-22-25-28-31-34-37(35-32-29-26-23-20-17-14-11-8-5-2)36-33-30-27-24-21-18-15-12-9-6-3/h4-36H2,1-3H3
(3)InChIKey: SWZDQOUHBYYPJD-UHFFFAOYSA-N

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