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Triruthenium dodecacarbonyl
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Name

Triruthenium dodecacarbonyl

 EINECS 239-287-4
CAS No. 15243-33-1 Density N/A
PSA 0.00000 LogP -2.49600
Solubility Insoluble in water Melting Point 150 °C
Formula C12O12Ru3 Boiling Point N/A
Molecular Weight 639.335 Flash Point N/A
Transport Information N/A Appearance Orange crystals
Safety 24/25 Risk Codes 11-20
Molecular Structure Molecular Structure of 15243-33-1 (RUTHENIUM CARBONYL) Hazard Symbols FlammableF, HarmfulXn
Synonyms

Rutheniumcarbonyl (Ru3(CO)12) (6CI,7CI);Dodecacarbonyl-triangulo-triruthenium;Dodecacarbonyltriruthenium;Triangulo-Triruthenium dodecacarbonyl;Trirutheniumdodecacarbonyl;Triruthenium dodecacarbonyl [Ru3(CO)12];cyclo-Tris(tetracarbonylruthenium)(3Ru-Ru);

Article Data 228

Triruthenium dodecacarbonyl Synthetic route

16406-48-7

ruthenium pentacarbonyl

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In further solvent(s) byproducts: CO; exposure to an N2-atmosphere, hydrocarbon soln.;;100%
In pentane storing of soln. for 1 day under Ar at room temp.;
In neat (no solvent) decompn. of (Ru(CO)5) at room temp.;;

Ru2[μ-η(2)-OC(CF3)O]2(CO)6

201230-82-2

carbon monoxide

21907-50-6

cesium trifluoroacetate

A

15243-33-1

dodecacarbonyl-triangulo-triruthenium

184584-51-8

fac-Cs[Ru(CF3COO)3(CO)3]

Conditions
ConditionsYield
In tetrahydrofuran CO-atmosphere; stirring Ru-complex soln. (30°C, 8 h); sepn. of Ru3(CO)12, evapn.;A 95%
B 99%

Ru3{μ-H,μ-O=C(NMe2)}(CO)10

74-85-1

ethene

A

15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru2(OCC2H5)(OCN(CH3)2)(CO)6

Conditions
ConditionsYield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;A n/a
B 98%

K(1+)*RuCl2(CO)2(CO2H)(1-) = K[RuCl2(CO)2(CO2H)]

201230-82-2

carbon monoxide

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In 2-methoxy-ethanol byproducts: CO2, KCl; heating the Ru complex and CO in 2-methoxyethanol to 85°C for 20 min; filtration, washing (EtOH);97%

diruthenium(II,III) tetraacetatechloride

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With carbon monoxide In methanol; dichloromethane; water High Pressure; dissolving Ru2(CH3COO)4Cl in CH3OH-CH2Cl2-H2O (10:10:1), charging into pressure vessel, pressurizing to 1000 psi with CO, stirring at this pressure for 4 h; venting CO atmosphere, partially removing solvent by vac. distn., pptn.filtration;96%

H(μ-H)Ru3(CO)11

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With carbon monoxide In methanol CO atmosphere (room temp., 10 min, stirring), pptn.; redn. of vol. (vac.), filtration off, washing (MeOH): 87.7%; evapn. of filtrate to dryness, chromy. (silica, hexane): 7.9%;95.7%
52621-15-5

[Ru(CO)4(η2-ethylene)]

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
In n-heptane N2-atmosphere; refluxing for 2 h; solvent removal (vac.), TLC (CH2Cl2/hexane=1:1);95%

tricarbonyldichlororuthenium (II) dimer

201230-82-2

carbon monoxide

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With sodium carbonate In ethylene glycol molar ratio Ru:Na2CO3=1:1; bubbling CO for 5 h at 95°C; extn. of ppt. and sublimate with CH2Cl2 (room temp.), evapn., washing (water);93%
74-85-1

ethene

Ru3(H)(OCC6H5)(CO)10

A

15243-33-1

dodecacarbonyl-triangulo-triruthenium

B

Ru2(OCC2H5)(OCC6H5)(CO)6

Conditions
ConditionsYield
With CO In hexane under N2; Ru compd. is dissolved in hexane, transferred to a Hoke cylinder, charged with CO (1 atm) and ethylene (3 atm), allowed to sit at room temp. for 20 h; gases are vented, IR, mixt. is reduced in volume, cooled to -20°C: crystn. of Ru3(CO)12, soln. is filtered after 12 h, reduced in volume to half, IR, soln. is cooled to -20°C, supernatant liq. is similar worked up; elem. anal.;A n/a
B 93%

ruthenium trichloride

201230-82-2

carbon monoxide

15243-33-1

dodecacarbonyl-triangulo-triruthenium

Conditions
ConditionsYield
With triethylamine In propan-1-ol; water at 85℃; under 2625.26 Torr; Concentration; Reagent/catalyst; Solvent; Temperature; Pressure; Autoclave;92.5%
In methanol at 125℃; under 48754.9 Torr; for 8h; Autoclave;
With triethylamine In propan-1-ol at 85℃; under 2625.26 Torr; for 17h; Autoclave; Gas phase;

Triruthenium dodecacarbonyl Specification

The Ruthenium,dodecacarbonyltri-, triangulo is an organic compound with the formula C12O12Ru3. The systematic name of this chemical is Carbon monooxide - ruthenium. With the CAS registry number 15243-33-1, it is also named as Triruthenium Dodecacarbonyl. The product's categories are  Classes of Metal Compounds; Ru (Ruthenium) Compounds; Transition Metal Compounds. Besides, it is orange plates, which should be stored in a sealed, dry, well-ventilated, lightproof place.

Physical property about Ruthenium,dodecacarbonyltri-, triangulo is: (1)#H bond acceptors: 1.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and harmful by inhalation. When you are using it, avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)InChI: InChI=1/12CO.3Ru/c12*1-2;;;
(2)InChIKey: NQZFAUXPNWSLBI-UHFFFAOYAJ
(3)Std. InChI: InChI=1S/12CO.3Ru/c12*1-2;;;
(4)Std. InChIKey: NQZFAUXPNWSLBI-UHFFFAOYSA-N

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