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VINYL CROTONATE

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Name

VINYL CROTONATE

EINECS 238-930-6
CAS No. 14861-06-4 Density 0.94
PSA 26.30000 LogP 1.24920
Solubility Slightly soluble in water Melting Point -60 °C
Formula C6H8 O2 Boiling Point 133-134 ºC
Molecular Weight 112.128 Flash Point 27 ºC
Transport Information UN 3272 Appearance Clear, colorless liquid.
Safety Mildly toxic by ingestion and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to heat, flame or oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a cross-linking agent for acrylic and polyolefin plastics. See also ESTERS. Risk Codes R10;R36/37/38   
Molecular Structure Molecular Structure of 14861-06-4 (Vinyl crotonate) Hazard Symbols
Synonyms

Crotonicacid, vinyl ester (6CI,7CI,8CI); NSC 5215; Vinyl 2-butenoate; Vinyl crotonate

Article Data 15

VINYL CROTONATE Chemical Properties

IUPAC Name: Ethenyl (E)-but-2-enoate
The MF of Ethenyl (E)-but-2-enoate (14861-06-4) is C6H8O2.

                                
The MW of Ethenyl (E)-but-2-enoate (14861-06-4) is 112.13.
Synonyms of Ethenyl (E)-but-2-enoate (14861-06-4): Crotonic acid vinyl ester ; But-2-enoic acid vinyl ester ; Vinyl crotonate ; Vinyl 2-butenoate ; 2-Butenoic acid, ethenyl ester ; 2-Butenoicacid,ethenylester ; Vinyl (2e)-2-butenoate
Apperance: clear colourless to yellow liquid
Index of Refraction: 1.437 
EINECS: 238-930-6
Density: 0.936 g/ml 
Flash Point: 27.2 °C 
Boiling Point: 133 °C
Storage temp: 0-6°C
Merck: 2597

VINYL CROTONATE Uses

  Ethenyl (E)-but-2-enoate (14861-06-4) is used as acrylic and polyolefin plastics cross-linking agent.

VINYL CROTONATE Toxicity Data With Reference

1.    

skn-rbt 500 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 11/15 ,1971.
2.    

eye-rbt 500 mg open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.    

orl-rat LD50:6500 mg/kg

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 11/15 ,1971.
4.    

ihl-rat LCLo:4000 ppm/4H

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

VINYL CROTONATE Safety Profile

Mildly toxic by ingestion and inhalation. A skin and eye irritant. A very dangerous fire hazard when exposed to heat, flame or oxidizers. To fight fire, use alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a cross-linking agent for acrylic and polyolefin plastics. See also ESTERS.
Safety information of Ethenyl (E)-but-2-enoate (14861-06-4):
Hazard Codes  Xi
Risk Statements 
10  Flammable
36/37/38  Irritating to eyes, respiratory system and skin
Safety Statements 
16  Keep away from sources of ignition - No smoking
26  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27  Take off immediately all contaminated clothing
36/37/39  Wear suitable protective clothing, gloves and eye/face protection
RIDADR  UN 3272 3/PG 3
WGK Germany  2
RTECS  GQ5850000
HazardClass  3.2
PackingGroup  III

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