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| Name |
Vanadium tribromide |
EINECS | N/A |
| CAS No. | 13470-26-3 | Density | g/cm3 |
| PSA | 0.00000 | LogP | 2.53680 |
| Solubility | Soluble in water and tetrahydrofuran. | Melting Point |
N/A |
| Formula | Br3V | Boiling Point | °Cat760mmHg |
| Molecular Weight | 290.654 | Flash Point | °C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Poison by subcutaneous route. When heated to decomposition it emits toxic fumes of VOx and Br−. See also VANADIUM COMPOUNDS and BROMIDES. | Risk Codes | 34 |
| Molecular Structure |
|
Hazard Symbols |
|
| Synonyms |
NSC 151961;Vanadium bromide; Vanadium tribromide |
Article Data | 38 |
Vanadium tribromide Chemical Properties
IUPAC Name: Tribromovanadium
Synonyms of Vanadium tribromide (CAS NO.13470-26-3) : Vanadium bromide ; Vanadium bromide (VBr3)
InChI: InChI=1/3BrH.V/h3*1H;/q;;;+2/p-3
Product Categories: Alternative Energy;Catalysts;Materials for Hydrogen Storage
CAS NO:13470-26-3
Molecular Formula:Br3V
Molecular Weight :290.654
Molecular Structure :.png)
EINECS: 236-736-6
Density: 4 g/cm3
Sensitive : Moisture Sensitive
Appearance: Vanadium tribromide (CAS NO.13470-26-3) is red-brown .
Solubility:soluble complexes with dimethoxyethane and THF, such as mer-VBr3(THF)3
Vanadium tribromide Production
Vanadium tribromide (CAS NO.13470-26-3) has been prepared by treatment of VCl4 with HBr:
2 VCl4 + 8 HBr → 2 VBr3 + 8 HCl + Br2
The reaction proceeds via the unstable vanadium(IV) bromide, VBr4, which releases Br2 at room temperature.
Vanadium tribromide Toxicity Data With Reference
| 1. | scu-rbt LDLo:20 mg/kg ,- | 27ZWAY Heffters Handbuch der Experimentelle Pharmakologie. 3 (1541),3. |
Vanadium tribromide Consensus Reports
Reported in EPA TSCA Inventory.
Vanadium tribromide Safety Profile
Poison by subcutaneous route. When heated to decomposition it emits toxic fumes of VOx and Br−. See also VANADIUM COMPOUNDS and BROMIDES.
Hazard Codes 
C
Risk Statements 34
R34:Causes burns.
Safety Statements 26-36/37/39-45-27-22
S22:Do not breathe dust.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S27:Take off immediately all contaminated clothing.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR 3260
RTECS YW2750000
HazardClass 8
PackingGroup II
Vanadium tribromide Standards and Recommendations
ACGIH TLV: TWA 0.05 mg(V2O5)/m3
NIOSH REL: CL 0.05 mg(V)/m3/15M
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