- Vinylmagnesium bromide
- Vinylmagnesium chloride
- 182678-46-2Ethanone,1-[4-(fluoromethoxy)phenyl]-
- 18268-45-6Dodecanoic acid,silver(1+) salt (1:1)
- 18268-54-71-Naphthalenesulfonicacid, 4-[2-(2-hydroxy-1-naphthalenyl)diazenyl]-
- 18268-70-7Hexanoic acid,2-ethyl-, 1,1'-[oxybis(2,1-ethanediyloxy-2,1-ethanediyl)] ester
- 18268-74-1Silanediol,1,1-dimethyl-, potassium salt (1:2)
- 18269-97-12-Propenoic acid,2-methyl-, (trimethylsilyl)methyl ester
- 182699-77-02(3H)-Benzofuranone,3a,4,5,7a-tetrahydro-3,6-dimethyl-, (3S,3aS,7aR)-
- 18269-99-32-Propenoic acid,2-[(trimethylsilyl)oxy]ethyl ester
- 18270-17-2Silane,trimethyl-1-pentyn-1-yl-
- 1827-27-63-Pyridinamine,6-fluoro-
Hot Products
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
- 7631-86-9Silicon dioxide
- 302-79-4Tretinoin
- 77-92-9Citric acid
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
Vinylmagnesium bromide |
EINECS | 217-375-3 |
| CAS No. | 1826-67-1 | Density | 0.981 g/mL at 25 °C |
| PSA | 0.00000 | LogP | 1.52480 |
| Solubility | vigorous reaction with water | Melting Point |
N/A |
| Formula | C2H3BrMg | Boiling Point | N/A |
| Molecular Weight | 131.255 | Flash Point | -17 °C |
| Transport Information | UN 3399 4.3/PG 2 | Appearance | Clear light brown to brown solution |
| Safety | 16-26-29-33-36/37/39-45-6A-43B | Risk Codes | 11-14-19-34-14/15 |
| Molecular Structure |
|
Hazard Symbols |
 F,  C
|
| Synonyms |
Magnesium,bromovinyl- (7CI,8CI);Vinylmagnesium bromide (6CI);Bromovinylmagnesium;Ethenylmagnesium bromide;Norman reagent; |
Article Data | 16 |
Vinylmagnesium bromide Synthetic route
| Conditions | Yield |
|---|---|
| With magnesium In tetrahydrofuran; diethyl ether at 0℃; | |
| With iodine; magnesium In tetrahydrofuran for 0.5h; Ambient temperature; | |
| With magnesium In tetrahydrofuran |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran |
- 141-79-7
4-methyl-pent-3-en-2-one
- 1826-67-1
vinyl magnesium bromide
- 38552-68-0
3,5-dimethyl-hexa-1,4-dien-3-ol
| Conditions | Yield |
|---|---|
| In tetrahydrofuran | 100% |
- 1826-67-1
vinyl magnesium bromide
- 123-11-5
4-methoxy-benzaldehyde
- 51410-44-7
1-(4-methoxylphenyl)-2-propen-1-ol
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; hexane at 0℃; for 2h; Inert atmosphere; | 100% |
| In tetrahydrofuran at 0℃; for 4h; | 96% |
| In tetrahydrofuran; diethyl ether at 0 - 20℃; | 95% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; | 100% |
| In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 98% |
| In tetrahydrofuran at 0 - 20℃; Inert atmosphere; | 92% |
- 2930-05-4
Benzyloxymethyl-oxiran
- 1826-67-1
vinyl magnesium bromide
- 58931-16-1
1-(benzyloxy)-4-penten-2-ol
| Conditions | Yield |
|---|---|
| With copper(l) iodide In tetrahydrofuran at -20℃; for 0.333333h; | 100% |
| With copper(l) iodide In tetrahydrofuran at -78 - -40℃; | 95% |
| With copper(l) iodide In tetrahydrofuran | 93% |
- 75-77-4
chloro-trimethyl-silane
- 1826-67-1
vinyl magnesium bromide
- 121220-80-2
(E)-3-Methoxy-2-(4-oxo-cyclopent-2-enyl)-acrylic acid methyl ester
- 121220-81-3
(E)-3-Methoxy-2-((1R,2S)-4-trimethylsilanyloxy-2-vinyl-cyclopent-3-enyl)-acrylic acid methyl ester
| Conditions | Yield |
|---|---|
| With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; chloro-trimethyl-silane; copper(l) iodide In tetrahydrofuran 1.) -75 deg C, 10 h; 2.) -75 deg C to -40 deg C; | 100% |
| With N,N,N,N,N,N-hexamethylphosphoric triamide; dmap; copper(l) iodide In tetrahydrofuran at -78℃; | 0.62 g |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; diethyl ether at 0 - 20℃; Inert atmosphere; | 100% |
| 85% | |
| In tetrahydrofuran for 1h; | 82% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 20℃; Grignard reaction; | 100% |
| Stage #1: hept-6-enal; vinyl magnesium bromide In tetrahydrofuran; diethyl ether at -78 - 20℃; Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether at 20℃; | 90% |
| In tetrahydrofuran; diethyl ether for 3h; Ambient temperature; Yield given; | |
| In tetrahydrofuran |
| Conditions | Yield |
|---|---|
| (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 0.0833333h; | 100% |
| (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride In tetrahydrofuran for 5h; further catalysts; | 73% |
| With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc(II) chloride 1.) THF, RT, 20 min, 2.) RT, 1 h; Yield given. Multistep reaction; |
Vinylmagnesium bromide Chemical Properties
IUPAC Name: Magnesium ethene bromide
Synonyms of Magnesium,bromoethenyl- (CAS NO.1826-67-1): Vinylmagnesium bromide ; Bromovinylmagnesium
Molecular Structure: 
Molecular Formula: C2H3BrMg
Molecular Weight: 131.25
CAS NO: 1826-67-1
EINECS: 217-375-3
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 1
Polar Surface Area: 0 Å2
Density: 0.981 g/mL at 25 °C
Flash Point: 1 °F
Storage temp: Refrigerator
Solubility: vigorous reaction
Water Solubility: vigorous reaction
Appearance: Clear light brown to brown solution
SMILES: Br[Mg]\C=C
InChI: InChI=1/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1/rC2H3BrMg/c1-2-4-3/h2H,1H2
InChIKey: XHHHAXOHMKAOSL-ZAPIYNQUAR
Std. InChI: InChI=1S/C2H3.BrH.Mg/c1-2;;/h1H,2H2;1H;/q;;+1/p-1
Std. InChIKey: XHHHAXOHMKAOSL-UHFFFAOYSA-M
Product Categories of Magnesium,bromoethenyl- (CAS NO.1826-67-1): GRIGNARD REAGENTS;Classes of Metal Compounds;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;Alkenyl;Grignard Reagents;Organometallic Reagents
Vinylmagnesium bromide Safety Profile
Safety Information of Magnesium,bromoethenyl- (CAS NO.1826-67-1):
Hazard Codes: 
F,
C
Risk Statements: 11-19-34-14/15
R11: Highly flammable.
R14/15: Reacts violently with water, liberating extremely flammable gases
R19: May form explosive peroxides.
R34: Causes burns.
Safety Statements: 16-26-29-33-36/37/39-45-6-43
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29: Do not empty into drains.
S33: Take precautionary measures against static discharges.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S6: Keep under ... (inert gas to be specified by the manufacturer)
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
RIDADR: UN3399 4.3/PG 2
WGK Germany: 1
F:1-3-10
Vinylmagnesium bromide Specification
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Water Reactive. Material will react with water and may release a flammable and/or toxic gas. Flammable liquid and vapor. May form explosive peroxides.
Extinguishing Media: Use approved class D extinguishing agents or smother with dry sand, clay, or sodium bicarbonate. DO Handling: Do not allow water to get into the container because of violent reaction. Use spark-proof tools and explosion proof equipment. Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Do not allow contact with water. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Do not store in direct sunlight. Store in a tightly closed container. Store in a dry area. Flammables-area. Corrosives area. Water free area. Store under nitrogen. Store at room temperature.
What can I do for you?
Get Best Price
