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Zinc sulphate

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Name

Zinc sulphate

EINECS 231-793-3
CAS No. 7733-02-0 Density 1.31 g/mL at 20 °C
PSA 82.98000 LogP 0.42550
Solubility soluble in water Melting Point 100 °C
Formula ZnSO4 Boiling Point 330 °C at 760 mmHg
Molecular Weight 161.454 Flash Point N/A
Transport Information UN 3082 9/PG 3 Appearance colorless solid
Safety 61-39-26-60 Risk Codes 52-50-41-22-51/53
Molecular Structure Molecular Structure of 7733-02-0 (Zinc sulphate) Hazard Symbols HarmfulXn,DangerousN,IrritantXi
Synonyms

Zinc sulfate (1:1);Zinc sulfate (ZnSO4);Zinc vitriol;Zinc(II) sulfate;Zincaps;Zincate;Zinco;Zincomed;Zin Sulphate Mono/Hepta;BiolectraZink;Bonazen;Bufopto Zinc Sulfate;Complexonat;Honny Fresh 10P;Kreatol;Op-Thal-Zin;Optraex;Solvazinc;Solvezink;Sulfuric acid zinc salt;Verazinc;White vitriol;Z-Span;Zinc sulfate;

Article Data 240

Zinc sulphate Synthetic route

A

B

zinc sulfide

zinc sulfide

A

7733-02-0

zinc(II) sulfate

B

zinc(II) oxide

copper(ll) sulfate pentahydrate

zinc ferrite

A

7733-02-0

zinc(II) sulfate

B

copper(II) oxide

Conditions
ConditionsYield
In solid byproducts: H2O; mixt. heating in derivatograph in Pt crucible at 10 K/min in air up to 850°C; TG, DTG, DTA;A 15.6%
B n/a
In solid byproducts: H2O; mixt. heating in derivatograph in Pt crucible at 10 K/min in air up to 1000°C; TG, DTG, DTA;A 0%
B n/a
743369-26-8

zinc(II) carbonate

77-78-1

dimethyl sulfate

7733-02-0

zinc(II) sulfate

Conditions
ConditionsYield
byproducts: (CH3)2O; on react. of ZnCO3 with dimethyl sulfate in vacuum, evaporating of formed dimethyl ether (method of Recoura);; compd. free of H2O is obtained;;

zinc sulfide

7733-02-0

zinc(II) sulfate

Conditions
ConditionsYield
In water

zinc sulfide

7733-02-0

zinc(II) sulfate

Conditions
ConditionsYield
In water suspension of ZnS in H2O; reaction is fast in acidic H2O or an ozon dissolving liquid (eg. rosin oil);;
In neat (no solvent) reaction with luminescence;;
In neat (no solvent) reaction with luminescence;;

dipotassium peroxodisulfate

zinc sulfide

7733-02-0

zinc(II) sulfate

Conditions
ConditionsYield
In water slow oxidation with aq. K2S2O8;;
In water slow oxidation with aq. K2S2O8;;
7782-50-5

chlorine

zinc(II) oxide

A

7733-02-0

zinc(II) sulfate

B

7646-85-7

zinc(II) chloride

Conditions
ConditionsYield
With iron(II) sulfate In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;;
With FeSO4 In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;;
With iron(II) sulfate In not given byproducts: Fe(OH)3; Zn production from industrial wastes; detailed description given;; ZnCl2 not isolated;;

zinc(II) oxide

7733-02-0

zinc(II) sulfate

Conditions
ConditionsYield
With sulfur dioxide In neat (no solvent) in presence of O2, starting of react. at 350 °C;;
With sulfuric acid In sulfuric acid leaching the oxide roast with sulfuric acid; amt. of formed ZnSo4 is depending on temp. of H2SO4;;
With sulfuric acid In sulfuric acid leaching the oxide roast with sulfuric acid;;
7446-09-5

sulfur dioxide

zinc(II) oxide

7733-02-0

zinc(II) sulfate

Conditions
ConditionsYield
With oxygen Kinetics; 920 - 1200 K, in a fixed bed reactor;

Zinc sulphate Chemical Properties

IUPAC Name:zinc sulfate
Molecular Formula: O4SZn
Molecular Weight: 161.471600 g/mol
Appearance: Colorless to slightly green, odorless solid
Melting Point: 100°C
Boiling Point: 330 °C at 760 mmHg
EINECS: 231-793-3
Density: 1.31 g/mL at 20 °C
Water Solubility: Soluble
Merck: 14,10159
Synonyms of Zinc sulfate (CAS NO.7733-02-0): AI3-03967 ; Bonazen ; Bufopto zinc sulfate ; CCRIS 3664 ; Caswell No. 927 ; Complexonat ; EINECS 231-793-3 ; EPA Pesticide Chemical Code 089001 ; HSDB 1063 ; Medizinc ; NSC 135806 ; NSC 32677 ; NU-Z ; Neozin ; OP-Thal-zin ; Optised ; Optraex ; Orazinc ; Prefrin-Z ; Solvezinc ; Solvezink ; Sulfate de zinc ; Sulfate de zinc [French] ; Sulfuric acid zinc salt (VAN) ; Sulfuric acid, zinc salt ; Sulfuric acid, zinc salt (1:1) ; UNII-0J6Z13X3WO ; Verazinc ; Visine-ac ; White copperas ; White vitriol ; White vitriol (VAN) ; Zinc sulfate (1:1) ; Zinc sulfate (ZnSO4) ; Zinc sulfate anhydrous ; Zinc sulphate ; Zinc vitriol ; Zinc vitriol (VAN) ; Zinc-200 ; Zincate ; Zinci Sulfas ; Zincomed ; Zincum Sulfuricum ; Zink-Gro ; Zinklet ; Zinkosite ; component of Phenylzin 
Categories: Inorganics;Volumetric Solutions ; BioUltraProtein Structural Analysis ; Molecular Biology ; Molecular Biology Reagents ; Optimization Reagents ; X-Ray Crystallography ; Complexometric Solutions (IDRANAL)Volumetric Solutions ; Complexometric Titration (IDRANAL) ; S - Z;Salt Solutions ; Titration ; Complexometric Concentrates (IDRANAL)Titration ; Concentrates (e.g. FIXANAL) ; Salt Concentrates

Zinc sulphate Uses

  Zinc sulfate (CAS NO.7733-02-0) is used to supply zinc in fertilizers, animal feeds , and agricultural sprays. it is used in making lithopone, in electrolytes for zinc plating, as a mordant in dyeing, as a preservative for skins and leather and in medicine as an emetic.

Zinc sulphate Production

 Zinc sulfate (CAS NO.7733-02-0) can  be prepared by adding solid zinc to a copper(II) sulfate solution. Zn + CuSO4 → ZnSO4 + Cu

Zinc sulphate Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 66mg/kg (66mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
dog LDLo subcutaneous 78mg/kg (78mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
human TDLo oral 45mg/kg/7D-C (45mg/kg) CARDIAC: PULSE RATE INCREASE WITHOUT FALL IN BP

GASTROINTESTINAL: OTHER CHANGES

BLOOD: NORMOCYTIC ANEMIA
British Medical Journal. Vol. 1, Pg. 754, 1978.
human TDLo oral 106mg/kg (106mg/kg) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
British Medical Journal. Vol. 1, Pg. 1390, 1977.
man TDLo oral 180mg/kg/6W-I (180mg/kg) BLOOD: OTHER CHANGES JAMA, Journal of the American Medical Association. Vol. 252, Pg. 1443, 1984.
mouse LD50 intraperitoneal 29060ug/kg (29.06mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse LD50 intravenous 23300ug/kg (23.3mg/kg)   Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
mouse LD50 oral 245mg/kg (245mg/kg)   Yaoxue Tongbao. Bulletin of Pharmacology. Vol. 22, Pg. 230, 1987.
mouse LD50 subcutaneous 781mg/kg (781mg/kg) GASTROINTESTINAL: CHANGES IN PANCREATIC WEIGHT

BLOOD: "CHANGES IN SERUM COMPOSITION (E.G., TP, BILIRUBIN, CHOLESTEROL)"
Japanese Journal of Toxicology and Environmental Health. Vol. 44, Pg. 305, 1998.
rabbit LD50 oral 2gm/kg (2000mg/kg)   International Polymer Science and Technology. Vol. 3, Pg. 93, 1976.
rabbit LDLo intravenous 23mg/kg (23mg/kg)   Toxicology and Applied Pharmacology. Vol. 9, Pg. 269, 1966.
rabbit LDLo subcutaneous 300mg/kg (300mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rat LD50 intraperitoneal 196mg/kg (196mg/kg)   Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 intravenous 69900ug/kg (69.9mg/kg)   Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LD50 oral 1710mg/kg (1710mg/kg)   Indian Journal of Pharmacology. Vol. 23, Pg. 153, 1991.
rat LDLo subcutaneous 330mg/kg (330mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
women TDLo oral 3120mg/kg/43W (3120mg/kg) BLOOD: MICROCYTOSIS WITH OR WITHOUT ANEMIA

BLOOD: AGRANULOCYTOSIS
Gastroenterology. Vol. 94, Pg. 508, 1988.

Zinc sulphate Safety Profile

Safety Information of Zinc sulfate (CAS NO.7733-02-0):
Hazard Codes:Xn,Xi  ,N
Risk Statements:52/53-50/53-41-22-51/53
52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
41:Risk of serious damage to eyes
22:Harmful if swallowed
51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment      
Safety Statements:61-39-26-60
61:Avoid release to the environment. Refer to special instructions safety data sheet
39:Wear eye/face protection
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
60:This material and/or its container must be disposed of as hazardous waste       
RIDADR:UN 3082 9/PG 3
WGK Germany:3
RTECS:ZH5260000

Zinc sulphate Specification

First Aid Measures of Zinc sulfate (CAS NO.7733-02-0):
Ingestion:Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.
Inhalation:If fumes or combustion products are inhaled, remove to fresh air. Lay victim down and keep warm and rested. If breathing is shallow, or has stopped, ensure clear airway and apply resuscitation. Transport to a hospital or doctor immediately.
Skin:If this product comes into contact with skin, wash skin with soap and water. Remove contaminated clothing and footwear. Ensure contaminated clothing is thoroughly washed before using again. Transport to hospital or doctor if symptoms develop.
Eyes:If this product comes into contact with eyes, hold eyes open and wash continuously for 15 minutes with running water. Ensure irrigation under eyelids by occasionally lifting eyelids. Do not attempt to remove contact lenses unless trained. Transport to a hospital or doctor immediately.
Storage of Zinc sulfate (CAS NO.7733-02-0): Keep well closed.

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