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Zirconium fluoride

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Name

Zirconium fluoride

EINECS 232-018-1
CAS No. 7783-64-4 Density 4,43 g/cm3
PSA 0.00000 LogP 1.68080
Solubility water: 1.388 g/100 mL Melting Point 640 °C
Formula ZrF4 Boiling Point 905 °C
Molecular Weight 167.218 Flash Point N/A
Transport Information UN 3260 8/PG 2 Appearance white fine crystalline powder
Safety 26-27-28-36/37/39-45 Risk Codes 34-36/37/38
Molecular Structure Molecular Structure of 7783-64-4 (Zirconium fluoride) Hazard Symbols CorrosiveC,IrritantXi
Synonyms

Zirconiumfluoride (ZrF4) (8CI);Zirconium tetrafluoride;Zirconium(IV) fluoride;

Article Data 90

Zirconium fluoride Chemical Properties

IUPAC Name: Tetrafluorozirconium
The MF of Zirconium fluoride (CAS NO.7783-64-4) is F4Zr.

                            
The MW of Zirconium fluoride (CAS NO.7783-64-4) is 167.22.
Synonyms of Zirconium fluoride (CAS NO.7783-64-4): Zirconium fluoride (ZrF4), (beta-4)- ; Zirconium tetrafluoride ; Zirconium(IV) fluoride ; Zirconium fluoride (ZrF4), (T-4)-
Product Categories: Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Crystal Grade Inorganics;Salts;ZirconiumMetal and Ceramic Science
Apperance: white fine crystalline powder
Boiling Point: 956 °C
Melting Point: 640 °C
EINECS: 232-018-1
Density: 4,43 g/ml
Refractive index: 1.59 
Water Solubility: 1.388 g/100 mL
Sensitive: Moisture Sensitive
Merck: 14,10175

Zirconium fluoride Uses

  Zirconium fluoride (CAS NO.7783-64-4) is as used a zirconium source in oxygen-sensitive applications, e.g. metal production. Zirconium fluoride can be purified by distillation or sublimation.Together with uranium salt, zirconium fluoride can be a component of fuel-coolant in molten salt reactors.

Zirconium fluoride Toxicity Data With Reference

1.    

ivn-mus LD50:98 mg/kg

    19UQAS    Khimicheskie Paktory Vneshnei Sredy I Ikh Gigienicheskoe Znachenie, Materialy Nauchnoi Konferentsii 2nd,Pervyi Moskovskii Meditsinskii Institut,Moscow, USSR.: 1965,30.

Zirconium fluoride Consensus Reports

Reported in EPA TSCA Inventory.

Zirconium fluoride Safety Profile

Poison by intravenous route. When heated to decomposition it emits toxic fumes of F. See also ZIRCONIUM COMPOUNDS and FLUORIDES.Safety information of Zirconium fluoride (CAS NO.7783-64-4):
Hazard Codes  CorrosiveC,IrritantXi
Risk Statements 
34 Causes burns
36/37/38 Irritating to eyes, respiratory system and skin
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
27 Take off immediately all contaminated clothing
28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer)
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR  UN 3260 8/PG 2
WGK Germany  3
RTECS  ZH7875000
Hazard Note  Corrosive
HazardClass  8
PackingGroup  II

Zirconium fluoride Standards and Recommendations

OSHA PEL: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3
ACGIH TLV: TWA 5 mg(Zr)/m3; STEL 10 mg(Zr)/m3; Not Classifiable as a Human Carcinogen; TWA 2.5 mg(F)/m3; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
DFG MAK: 1 mg(Zr)/m3
NIOSH REL: (Fluorides, Inorganic) 10H TWA 2.5 mg(F)/m3

Zirconium fluoride Specification

 Zirconium(IV) fluoride (ZrF4) is an inorganic chemical compound. It is a component of ZBLAN fluoride glass. It is insoluble in water. It is the main component of fluorozirconate glasses.Three crystalline phases of ZrF4 have been reported, α (monoclinic, β (tetragonal, Pearson symbol tP40, space group P42/m, No 84) and γ (unknown structure). β and γ phases are unstable and irreversibly transform into the α phase at 400 °C.

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