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1002-84-2

Basic Information
CAS No.: 1002-84-2
Name: Pentadecanoic acid
Article Data: 76
Molecular Structure:
Molecular Structure of 1002-84-2 (Pentadecanoic acid)
Formula: C15H30 O2
Molecular Weight: 242.402
Synonyms: 14FA; NSC28486; Pentadecylic acid; n-Pentadecanoic acid
EINECS: 213-693-1
Density: 0.895 g/cm3
Melting Point: 51-53 °C(lit.)
Boiling Point: 257 °C100 mm Hg(lit.),330.4 °C at 760 mmHg
Flash Point: 149.6 °C
Solubility: insoluble in water
Appearance: White Powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes.
PSA: 37.30000
LogP: 5.16220
Synthetic route

4′-methoxybenzyl hexadecanoate

1002-84-2

palmitic acid

Conditions
ConditionsYield
With silver hexafluoroantimonate; 1,2,3-trimethoxybenzene In dichloromethane at 40℃; for 8h;99%
629-73-2

1-Hexadecene

1002-84-2

palmitic acid

Conditions
ConditionsYield
With potassium permanganate; sulfuric acid; acetic acid In dichloromethane; water at 20℃; for 21h; Cooling with ice;84%
With diethyl ether bei der Einw. nitroser Gase;
With acetic acid bei der Einw. nitroser Gase;
89036-88-4

(1-Methoxy-pentadecylsulfanyl)-benzene

1002-84-2

palmitic acid

Conditions
ConditionsYield
With chromium(VI) oxide; sulfuric acid In acetone at 0℃; for 1h;78%
89861-47-2

4-methyl-3-[(1-oxohexadecyl)oxy]-2(3H)-thiazolethione

A

1002-84-2

palmitic acid

B

39220-65-0

1-nitropentadecane

Conditions
ConditionsYield
With bismuth trisphenylsulphide; dinitrogen tetraoxide In chlorobenzene at 110℃; for 12h;A 72%
B 5%
106-02-5

pentadecanolide

1002-84-2

palmitic acid

Conditions
ConditionsYield
With palladium 10% on activated carbon; W(OTf)6; hydrogen at 135℃; under 760.051 Torr; for 12h;71%
With palladium on activated carbon; W(OTf)6; hydrogen In neat (no solvent) at 135℃; under 760.051 Torr; for 12h;71%
103227-50-5

4-carbonyloxybutyryl dodecanoyl peroxide

A

1120-21-4

n-Undecane

B

1002-84-2

palmitic acid

Conditions
ConditionsYield
at -78℃; for 50h; Irradiation;A 1 % Chromat.
B 59%

3-n-pentadecyl-2-nitrophenol

A

O-pentadecanoyl-3-n-pentadecyl-4-nitrophenol

B

1002-84-2

palmitic acid

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII); acetic acid at 80℃; for 4h;A 55%
B 6%
22991-47-5

3-n-pentadecyl-4-nitrophenol

A

O-pentadecanoyl-3-n-pentadecyl-2-nitrophenol

B

1002-84-2

palmitic acid

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII); acetic acid at 80℃; for 4h;A 51%
B 6%
2437-56-1

1-tridecene

124-38-9

carbon dioxide

1002-84-2

palmitic acid

Conditions
ConditionsYield
Stage #1: 1-tridecene With bis(cyclopentadienyl)titanium dichloride; isopropylmagnesium chloride In diethyl ether at 30℃; for 8h; Schlenk technique; Inert atmosphere;
Stage #2: carbon dioxide In tetrahydrofuran at 20℃; for 0.5h; Schlenk technique; Inert atmosphere; regioselective reaction;
51%
200421-95-0

5-n-pentadecyl-2-nitrophenol

A

1-(3-hydroxy-4-nitro-phenyl)-pentadecan-1-one

B

O-pentadecanoyl-5-n-pentadecyl-2-nitrophenol

C

1002-84-2

palmitic acid

D

3163-07-3

4-nitroresorcinol

Conditions
ConditionsYield
With dihydrogen peroxide; methyltrioxorhenium(VII); acetic acid at 80℃; for 4h;A n/a
B 45%
C 8%
D n/a
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Chemistry

Chemistry informtion about Pentadecanoic Acid (CAS NO.1002-84-2) is:
IUPAC Name: Pentadecanoic Acid
Synonyms: Carboxylic Acid C15 ; C15:0 Fatty Acid ; C15 Acid ; 1-Pentadecanoic Acid ; Rarechem Al Bo 0368 ; Tetradecane-1-Carboxylic Acid ; Pentadecyclic Acid ; Pentadecylic Acid
Product Categories: Alkylcarboxylic Acids ; Biochemistry ; Higher Fatty Acids & Higher Alcohols ; Monofunctional & alpha,omega-Bifunctional Alkanes ; Monofunctional Alkanes ; Saturated Higher Fatty Acids ; PA - PENFatty Acids ; Fatty AcidsFA/FAME/Lipids/Steroids ; Free Fatty Acids ; Lipid Analytical Standards ; NeatsAlphabetic ; Other Lipid Related Products ; P ; C13 to C42+Fatty Acids ; Carbonyl Compounds ; Carboxylic Acids ; Fatty Acids ; Saturated fatty acids and derivatives ; Straight chain fatty acids 
MF: C15H30O2
MW: 242.4
EINECS: 213-693-1
Density: 0.895 g/cm3 
Melting Point: 51-53 °C(lit.)
Flash Point: 149.6 °C
Boiling Point: 330.4 °C at 760 mmHg
Vapour Pressure: 6.67E-05 mmHg at 25°C 
Enthalpy of Vaporization: 60.48 kJ/mol
Storage temp.: −20°C
BRN: 1773831
Stability: Stable. Combustible. Incompatible with bases, reducing agents, oxidizing agents.
Following is the molecular structure of Pentadecanoic Acid (CAS NO.1002-84-2) is:

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intravenous 54mg/kg (54mg/kg)
Behavioral: convulsions or effect on seizure threshold
Acta Pharmacologica et Toxicologica. Vol. 18, Pg. 141, 1961.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by intravenous route. When heated to decomposition it emits acrid smoke and irritating fumes. 
Hazard Codes:
IrritantXi
Risk Statements:
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing.
WGK Germany: 3
RTECS: RZ1925000

Specification

Pentadecanoic Acid (CAS NO.1002-84-2) is a white powder.
First Aid Measures
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively. 
Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation.
Storage: Store in a cool, dry place. Store in a tightly closed container.