CAS No.10025-82-8,Indium chloride Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	10025-82-8
Name:	Indium chloride
Article Data:	81

Formula:	InCl₃
Molecular Weight:	221.179
Synonyms:	Indium trichloride;Indium(III) chloride;Trichloroindium;Indium(Ⅲ)chloride;
EINECS:	233-043-0
Density:	3.46 g/mL at 25 °C(lit.)
Melting Point:	262 °C (dec.)(lit.)
Boiling Point:	300 °C
Flash Point:	300°C subl.
Solubility:	reacts with water
Appearance:	white crystalline powder
Hazard Symbols:	C
Risk Codes:	36/37/38-34-29-22
Safety:	26-36/37/39-45
Transport Information:	UN 3260 8/PG 2
PSA:	0.00000
LogP:	2.06850

Synthetic route

: indium(III) oxide

: 7446-09-5
sulfur dioxide

: 7782-50-5
chlorine

A: indium sulfate

B: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; heating from 550 to 750°C;
In neat (no solvent) on In2O3 surface; not isolated, detd. by thermal desorption (20-650°C) and mass spectroscopy;

...Expand

: indium(III) oxide

: 7719-09-7
thionyl chloride

: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) 300°C;;
In neat (no solvent) 300°C;;

: indium(III) oxide

: 7719-09-7
thionyl chloride

: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
In neat (no solvent) 300°C;;
In neat (no solvent) 300°C;;

: indium(III) oxide

: 10026-04-7, 53609-55-5
tetrachlorosilane

A: 112926-00-8, 7631-86-9
silica gel

B: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
780-800°C in vac.; Two-fold vacuum sublimation with prior distilling off SiCl4.;

...Expand

: 56-23-5
tetrachloromethane

: indium(III) oxide

: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
450°C;;
In neat (no solvent) chlorination of In2O3 with CCl4 at ca 450°C;
In not given react. of In2O3 with CCl4;

: indium(III) oxide

: 7782-50-5
chlorine

: 7646-78-8
tin(IV) chloride

A: (indium trichloride)2

B: 10025-82-8
indium(III) chloride

C: tin(IV) oxide

Conditions

Conditions	Yield
In gas Kinetics; flow method (600 - 800°C, 5 - 50 vol.% SnCl4, 20 - 120 min);

...Expand

: indium(III) oxide

: 7782-50-5
chlorine

A: 27693-84-1, 21563-01-9
In2Cl6

B: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
With tin(IV) chloride In neat (no solvent) byproducts: O2; chlorination of equimolar mixt. of In2O3 by Cl2/SnCl4 mixt. (4 vol % SnCl4, const. temp. in range 550-700°C, 60 min); chem. anal.;

...Expand

: indium(III) oxide

: 7782-50-5
chlorine

: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
With pyrographite heating in dry flow of Cl2;
In neat (no solvent) Kinetics; byproducts: O2; heating to 700°C;

: indium(III) oxide

: 7782-50-5
chlorine

A: (indium trichloride)2

B: 80937-33-3
oxygen

C: 10025-82-8
indium(III) chloride

Conditions

Conditions	Yield
Cl2/Ar mixt. flowing over In2O3 (const. temp. in range 500-700°C,gas flow rate 2ml/min, complete satn. of carrier gas by vapours of gase ous products, duration 3 h); monitoring by gravimetric and chem. anal.;

...Expand

: indium(III) oxide

: 7782-50-5
chlorine

: tin(IV) oxide

A: 27693-84-1, 21563-01-9
In2Cl6

B: 10025-82-8
indium(III) chloride

C: 7646-78-8
tin(IV) chloride

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal.;
With sulfur dioxide In neat (no solvent) Kinetics; byproducts: O2, SO3, In2(SO4)3; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2/SO2 flow 100 ml/min); chem. anal.;

...Expand

Raw Materials

Downstream Products

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Chemistry

Molecular Formula: InCl₃
Molecular Weight: 221.18g/mol
Mol File: 10025-82-8.mol
Einecs: 233-043-0
Appearance: White flakes
Melting Point: 586 °C
Boiling point: 800 °C
Flash Point: 300 °C subl
Density: 3.46 g/mL at 25 °C(lit.)
Water Solubility: Reacts
Sensitive: Hygroscopic
Structure of Indium trichloride (CAS NO.10025-82-8):

IUPAC Name: Trichloroindigane
Canonical SMILES: Cl[In](Cl)Cl
InChI: InChI=1S/3ClH.In/h3*1H;/q;;;+3/p-3
InChIKey: PSCMQHVBLHHWTO-UHFFFAOYSA-K
Product Categories of Indium trichloride(CAS NO.10025-82-8): Inorganics ; Catalysis and Inorganic Chemistry ; Chemical Synthesis ; Crystal Grade Inorganics ; Indium Salts ; IndiumMetal and Ceramic Science ;Salts;Indium .

Uses

Indium trichloride (CAS NO.10025-82-8) is a lewis acid catalyst in organic reactions such as Friedel-Crafts acylations and Diels-Alder reactions,and it's also the imporant materials to manufacture other indium salt.

Production

Indium trichloride (CAS NO.10025-82-8) will be placed in dry metal quartz tube, which leads to a fully dry chlorine gas, heated to 150 to 300 ° C for the reactions to produce a shiny sheet metal indium trichloride, 600 ° C sublimation, the sublimation process which leads to a small amount of chlorine-containing nitrogen or carbon dioxide flow, which leads to non-final chlorine carbon dioxide, obtained by cooling. Two by three indium chloride and hydrogen chloride at 100 ° C reaction progressive derived. Four hydration from hydrochloric acid-soluble metal indium obtained after crystallization.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	4950ug/kg (4.95mg/kg)		Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse	LD50	intravenous	11900ug/kg (11.9mg/kg)		Drugs in Japan Vol. -, Pg. 136, 1990.
mouse	LDLo	subcutaneous	60mg/kg (60mg/kg)		Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit	LDLo	intravenous	640ug/kg (0.64mg/kg)		Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit	LDLo	subcutaneous	2mg/kg (2mg/kg)		Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(10), Pg. 28, 1965.
rat	LD50	intraperitoneal	2370ug/kg (2.37mg/kg)		Drugs in Japan Vol. -, Pg. 136, 1990.
rat	LD50	intravenous	4460ug/kg (4.46mg/kg)		Drugs in Japan Vol. -, Pg. 136, 1990.
rat	LDLo	subcutaneous	10mg/kg (10mg/kg)	SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Journal of Industrial Hygiene and Toxicology. Vol. 24, Pg. 243, 1942.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison by subcutaneous, intraperitoneal, and intravenous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl⁻. See also INDIUM.
Hazard Codes of Indium trichloride (CAS NO.10025-82-8): C
Risk Statements: 36/37/38-34-29-22
36: Irritating to the eyes
37: Irritating to the respiratory system
38: Irritating to the skin
34: Causes burns
29: Contact with water liberates toxic gas
22: Harmful if swallowed
Safety Statements: 26-36/37/39-45
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves
39: Wear eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Specification

Indium trichloride , its cas register number is 10025-82-8. It also can be called Indium trichloride ; Indium (III) chloride ; and Indium In 111 Chloride .