CAS No.10025-85-1,Trichlorine nitride Suppliers

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Basic Information

Molecular Structure:
CAS No.:	10025-85-1
Name:	Trichlorine nitride
Article Data:	156

Formula:	Cl3N
Molecular Weight:	120.366
Synonyms:	Agene;Chlorine nitride; Nitrogen trichloride; Trichloramine; Trichlorine nitride;Trichloroamine
EINECS:	233-045-1
Density:	1.72 g/cm³
Melting Point:	-40 °C (233 K)
Boiling Point:	70 °C at 760 mmHg
Flash Point:	°C
Solubility:	Immiscible
Appearance:	Yellow oily liquid
Hazard Symbols:	Explodes when heated to approximately 200F (93C) or when exposed to direct sunlight. Toxic by ingestion and inhalation, strong irritant.
Risk Codes:	R36/37/38; R34; R10
Safety:	Moderately toxic by inhalation. An irritant to the eyes, skin, mucous membranes, and a systemic central nervous system irritant. An explosive sensitive to impact, light, and ultrasound. The solid explodes on melting. The liquid explodes above 60°C. Concentrated solutions are also explosive. Explosive decomposition is initiated by contact with: concentrated ammonia, arsenic, dinitrogen tetraoxide, hydrogen sulfide, hydrogen trisulfide, nitrogen oxide, organic matter, ozone, phosphine, phosphorus, potassium cyanide, potassium hydroxide solutions, selenium, hydrogen chloride, hydrogen fluoride, hydrogen bromide, hydrogen iodide. Mixtures with chlorine + hydrogen are potentially explosive. Upon decomposition it emits toxic fumes of Cl⁻ and NO_x. See also CHLORIDES.
PSA:	3.24000
LogP:	1.74980

Synthetic route

: 7778-54-3
calcium hypochlorite

: 12125-02-9
ammonium chloride

: 10025-85-1
nitrogen trichloride

Conditions

Conditions	Yield
With hydrogenchloride In dichloromethane; water at 4℃; for 0.75h;

: ammonium chloride

A: 10025-85-1
nitrogen trichloride

B: 14797-73-0
perchlorate(1-)

Conditions

Conditions	Yield
In water Electrolysis;

: 2696-92-6
nitrosylchloride

A: 81390-26-3, 35576-91-1, 81407-93-4
nitrosoamine

B: 10025-85-1
nitrogen trichloride

Conditions

Conditions	Yield
With ammonia In neat (no solvent) reaction of NOCl with melted NH3;;

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 2696-92-6
nitrosylchloride

A: 10025-85-1
nitrogen trichloride

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In not given react. with NOCl;;
In not given educts are passed through a porcelain tube heated at 1000 to 1100.degreeC;; very poor yield;;
In not given heating;;
In not given educts are passed through a porcelain tube heated at 1000 to 1100.degreeC;; very poor yield;;

...Expand

: 7727-37-9
nitrogen

: 10102-43-9
nitrogen(II) oxide

: 10294-34-5
boron trichloride

A: 10025-85-1
nitrogen trichloride

B: 12505-77-0
boron monoxide

Conditions

Conditions	Yield
with "active N" in presence of traces of O2;
with "active N" in presence of traces of O2;

...Expand

: 302-01-2
hydrazine

: 10025-85-1
nitrogen trichloride

Conditions

Conditions	Yield
With chlorine with chlorine excess, in presence of CCl4;
With Cl2 with chlorine excess, in presence of CCl4;

: 7664-41-7
ammonia

: 7782-50-5
chlorine

A: 10025-85-1
nitrogen trichloride

B: ammonium chloride

Conditions

Conditions	Yield
with dried gases at ambient temp., under 25 Torr; at higher pressure no NCl3 formed;
In tetrachloromethane at -90 and -180°C;;
In pentane at -90 and -180°C;;

...Expand

: 7664-41-7
ammonia

A: 10025-85-1
nitrogen trichloride

B: 14380-61-1
hypochlorite

Conditions

Conditions	Yield
In water; sodium chloride Electrolysis; the anode is graphite, cathode is platimun wire;

: ammonium chloride

: 10025-85-1
nitrogen trichloride

Conditions

Conditions	Yield
In not given Electrolysis; a cold satd. soln. is used;;
In water Electrolysis; NCl3 is formed at a platinum anode and explodes at touching of both poles;;
In water Electrolysis; electrolysis of concd. NH4Cl soln. at 35 - 40°C; don't stirring soln.;;

: 7778-54-3
calcium hypochlorite

: ammonium chloride

: 10025-85-1
nitrogen trichloride

Conditions

Conditions	Yield
In water reaction of acidified NH4Cl soln. with calcd. amount of Ca(ClO)2;; chloride free NCl3;;
In water reaction of acidified NH4Cl soln. with calcd. amount of Ca(ClO)2;; chloride free NCl3;;

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Chemistry

Product Name: Trichlorine nitride
Molecular Weight: 120.3657 g/mol
Molecular Formula: C_l3N
Canonical SMILES: N(Cl)(Cl)Cl
InChI: InChI=1S/Cl3N/c1-4(2)3
EINECS: 233-045-1
Index of Refraction: 1.492
Molar Refractivity: 20.31 cm³
Molar Volume: 69.9 cm³
Surface Tension: 37.5 dyne/cm
Density: 1.72 g/cm³
Enthalpy of Vaporization: 31.16 kJ/mol
Boiling Point: 70 °C at 760 mmHg
Vapour Pressure of Nitrogen chloride (CAS NO.10025-85-1): 131 mmHg at 25 °C

Uses

Nitrogen Chloride (CAS NO.10025-85-1) was trademarked as Agene and used to artificially bleach and age flour. It has the same effect as that of tear gas, but has never been used as such.

Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LC50	inhalation	112ppm/1H (112ppm)	sense organs and special senses: lacrimation: eye behavioral: convulsions or effect on seizure threshold gastrointestinal: changes in structure or function of salivary glands	American Industrial Hygiene Association Journal. Vol. 44, Pg. 145, 1983.

Safety Profile

Moderately toxic by inhalation. An irritant to the eyes, skin, mucous membranes, and a systemic central nervous system irritant. An explosive sensitive to impact, light, and ultrasound. The solid explodes on melting. The liquid explodes above 60°C. Concentrated solutions are also explosive. Explosive decomposition is initiated by contact with: concentrated ammonia, arsenic, dinitrogen tetraoxide, hydrogen sulfide, hydrogen trisulfide, nitrogen oxide, organic matter, ozone, phosphine, phosphorus, potassium cyanide, potassium hydroxide solutions, selenium, hydrogen chloride, hydrogen fluoride, hydrogen bromide, hydrogen iodide. Mixtures with chlorine + hydrogen are potentially explosive. Upon decomposition it emits toxic fumes of Cl⁻ and NO_x. See also CHLORIDES.
RIDADR: 3099
HazardClass: 5.1
PackingGroup: II

Standards and Recommendations

DOT Classification: Forbidden

Specification

Nitrogen chloride (CAS NO.10025-85-1), its Synonyms are Agene ; Chlorine nitride ; Nitrogen trichloride ; Trichloramine ; Trichlorine nitride ; Nitrogen chloride (NCl3) .