Detail of "10026-00-3"

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CAS Number:
10026-00-3
Name:
Platinate(2-),tetrachloro-, sodium (1:2), (SP-4-1)-
Superlist Name:
Disodium tetrachloroplatinate
Molecular Structure:
Formula:
Cl4Pt . 2 Na
Molecular Weight:
382.87
Synonyms:
Platinate(2-),tetrachloro-, disodium (8CI); Platinate(2-), tetrachloro-, disodium, (SP-4-1)-(9CI); Sodium tetrachloroplatinate(II) (7CI); Disodium tetrachloroplatinate;Disodium tetrachloroplatinate(2-); NSC 271964
EINECS:
233-051-4
Density:
g/cm³
Melting Point:
100°C
Boiling Point:
°Cat760mmHg
Flash Point:
°C
Hazard Symbols:
Risk Codes:
36/37/38-42/43-41-38-25

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Thermal transformations and electronic structure of platinum(II) complexes with trifluoromethylphosphines: Thermal transformations and electronic structure of platinum(II) complexes with trifluoromethylphosphines. Khokhryakov, K. A.; Grigorov, E. I.In this study， 594-09-2 and 10026-00-3 are also used.; Pamina, N. S.; Yakovlev, V. N.; Kukushkin, Yu. N. (Leningr. Tekhnol. Inst., Leningrad, USSR). Koord. Khim., 13(2), 237-41 (Russian) 1987. CODEN: KOKHDC. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 65 Na2[PtCl4] reacted with PPh(CF3)2 (L) in EtOH to give trans-PtL2Cl2 which reacted with AgNO3 in Me2CO to give trans-PtL2(NO3)2. trans-PtL12Cl2 (L1 = PPh2CF3, PPh3) reacted with AgNO3 to give Pt12(NO3)2. The electronic structures were calcd. for [PtL2Cl3]- (L2 = PMe3, PMe2(CF3), PMe(CF3)2, P(CF3)3, PEt3, PEt(CF3)2, PPhMe2 and PPh(CF3)2) and L by the CNDO method. During complexation significant transfer of electron d. occurs from the ligand to the metal, decreasing with an increase in the no. of CF3 groups on the phosphine. The ionization potential of the phosphines increased with increase no. of CF3 groups. These results are used to explain the tendency of PPh3-x(CF3)x in Pt complexes toward thermal oxidn. .

Reaction of [Pt(CO)2]n with triarylphosphines: Reaction of [Pt(CO)2]n with triarylphosphines. Eremenko, N. K.; Kurasov, S. S.; Mednikov, E. G.; Gubin, S. P.Several reagents with their cas registry numbers 10026-00-3 and 603-35-0 are used here. (Inst. Uglya, Kemerovo, USSR). Izv. Akad. Nauk SSSR, Ser. Khim., (3), 659-62 (Russian) 1986. CODEN: IASKA6. ISSN: 0002-3353. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 78 Triarylphosphines reacted with [Pt(CO)2]n in aq. acetone to give Pt3(CO)3L4 and Pt5(CO)6L4, where L = triphenyl-, trianisyl-, tritolyl-, or ethyldiphenylphosphine. A mechanism involving [Pt3(CO)6]52- formation was discussed. .