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1003-67-4

Basic Information
CAS No.: 1003-67-4
Name: 4-Picoline-N-oxide
Article Data: 91
Molecular Structure:
Molecular Structure of 1003-67-4 (4-Picoline-N-oxide)
Formula: C6H7NO
Molecular Weight: 109.128
Synonyms: 4-Picoline,1-oxide (6CI,8CI);4-Methylpyridine 1-oxide;4-Methylpyridine N-oxide;4-Methylpyridine oxide;4-Picoline N-oxide;4-Picoline oxide;NSC 5086;g-Picoline 1-oxide;g-Picoline N-oxide;g-Picoline oxide;N-oxide of 4-methyl pyridine;
EINECS: 213-712-3
Density: 1.01 g/cm3
Melting Point: 182-185 °C(lit.)
Boiling Point: 279.2 °C at 760 mmHg
Flash Point: 122.6 °C
Solubility: soluble in water
Appearance: Almost white to brown fine crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-24/25
PSA: 25.46000
LogP: 1.42350
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Chemistry

IUPAC Name:  4-Methyl-1-oxidopyridin-1-ium
Synonyms:   4-Methylpyridine N-oxide ; 4-Methylpyridine N-oxide ; 4-Picoline N-oxide ; 4-Picoline, 1-oxide ; 4-Picoline 1-oxide ; gamma-Picoline 1-oxide ; gamma-Picoline N-oxide ; 4-Methylpyridine 1-oxide ; 4-Picoline, 1-oxide
The Molecular Formula of  4-Methylpyridine 1-oxide (1003-67-4):C6H7NO
The Molecular Weight of  4-Methylpyridine 1-oxide (1003-67-4):109.1259g/mol
The Molecular Structure of   4-Methylpyridine 1-oxide (1003-67-4):
Index of Refraction: 1.512
Molar Refractivity: 32.26 cm3
Molar Volume: 107.4cm3
Surface Tension: 36.1 dyne/cm
Density: 1.01 g/cm3
Flash Point: 122.6 °C
Enthalpy of Vaporization: 49.7 kJ/mol
Boiling Point: 279.2 °C at 760 mmHg
Vapour Pressure: 0.00692 mmHg at 25°C 

Uses

  4-Methylpyridine 1-oxide (1003-67-4) can be used in organic synthesis.

Toxicity Data With Reference

1.    

ipr-mus LD50:1242 mg/kg

    TOXIA6    Toxicon. 23 (1985),815.
2.    

orl-qal LD50:750 mg/kg

    AECTCV    Archives of Environmental Contamination and Toxicology. 12 (1983),355.
3.    

orl-brd LD50:1 g/kg

    AECTCV    Archives of Environmental Contamination and Toxicology. 12 (1983),355.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion and intraperitoneal routes. When heated to decomposition it emits toxic vapors of NOx.
Hazard Codes: Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements: 26-36-24/25
S26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36:  Wear suitable protective clothing 
S24/25:  Avoid contact with skin and eyes
WGK Germany: 1