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1011-12-7

Basic Information
CAS No.: 1011-12-7
Name: 2-cyclohexylidenecyclohexanone
Article Data: 63
Molecular Structure:
Molecular Structure of 1011-12-7 (2-cyclohexylidenecyclohexanone)
Formula: C12H18 O
Molecular Weight: 178.274
Synonyms: 1-Cyclohexylidene-2-cyclohexanone;2-Cyclohexylidenecyclohexanone; Bicyclohexyliden-2-one; Dianon; NSC 61652
Density: 1.034g/cm3
Melting Point: 57 °C
Boiling Point: 295°C at 760 mmHg
Flash Point: 122.4°C
PSA: 17.07000
LogP: 3.39020
Synthetic route
108-94-1

cyclohexanone

1011-12-7

2-cyclohexylidenecyclohexanone

Conditions
ConditionsYield
With 2-(trimethylsilyl)prop-2-enylzinc chloride; bis(acetylacetonate)nickel(II) In diethyl ether 1.) -15 deg C, 0.5 h, 2.) r.t., 18 h;100%
With titanium(IV) tetraethanolate94%
With [Mg0833Al0.167(OH)2](C(00)O3)84*0.64H2O In acetonitrile at 239.84℃; Reagent/catalyst; Aldol Condensation; Inert atmosphere;13.4%
6032-29-7

(+/-)-2-pentanol

108-94-1

cyclohexanone

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

C11H18O

C

108-93-0

cyclohexanol

Conditions
ConditionsYield
With magnesium oxide for 6h; Reactivity; Temperature; Reagent/catalyst; Time; Meerwein-Ponndorf-Verley reduction; Inert atmosphere; Heating;A n/a
B n/a
C 79%
108-94-1

cyclohexanone

50555-86-7

4-aza-9-diazo-9H-fluorene

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

130716-67-5

2'-oxospiro<4-azafluorene-9',1-cyclopropane>

Conditions
ConditionsYield
With boron trifluoride diethyl etherate at 0℃; for 3h; Product distribution; or cyclopentanone;A 0.4 g
B 73%
With boron trifluoride diethyl etherate at 0℃; for 3h;A 0.4 g
B 73%
108-94-1

cyclohexanone

111317-20-5

(dichloroalumino)(trichlorotitanio)methane

1011-12-7

2-cyclohexylidenecyclohexanone

Conditions
ConditionsYield
In toluene at 25℃; for 3h;60%
108-94-1

cyclohexanone

108-91-8

cyclohexylamine

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

4594-78-9

cyclohexanone-2-propionitrile

Conditions
ConditionsYield
With acetic acid; acrylonitrile; hydroquinone for 16h; Heating;A 15%
B 42%
108-94-1

cyclohexanone

107-13-1

acrylonitrile

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

4594-78-9

cyclohexanone-2-propionitrile

Conditions
ConditionsYield
With cyclohexylamine; acetic acid; hydroquinone for 16h; Heating;A 15%
B 42%
108-94-1

cyclohexanone

A

1502-22-3

2-(1-cyclohexenyl)cyclohexanone

B

1011-12-7

2-cyclohexylidenecyclohexanone

C

41481-20-3

2-cyclohexylidene-6-(1-cyclohexen-1-yl)cyclohexan-1-one

D

20780-25-0

2(R*),6(S*)-di(1-cyclohexen-1-yl)cyclohexanone

Conditions
ConditionsYield
With potassium hydroxide In toluene at 190℃; for 6.5h; Further byproducts given;A n/a
B n/a
C n/a
D 33%
108-94-1

cyclohexanone

999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

6651-36-1

1-(Trimethylsilyloxy)cyclohexene

C

130800-11-2

N-Cyclohexenylcyclohexanimine

Conditions
ConditionsYield
dicobalt octacarbonyl at 110℃; for 6h;A n/a
B n/a
C 32%
108-94-1

cyclohexanone

75-05-8

acetonitrile

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

4435-18-1, 76293-17-9

2-cyclohexylideneacetonitrile

Conditions
ConditionsYield
With [Mg0751Al0.249(OH)2](C(01)O3)25*0.71H2O at 239.84℃; Inert atmosphere;A 11.2%
B 8.4%
108-94-1

cyclohexanone

18162-48-6

tert-butyldimethylsilyl chloride

A

1011-12-7

2-cyclohexylidenecyclohexanone

B

62791-22-4

tert-butyl(cyclohex-1-en-1-yloxy)dimethylsilane

Conditions
ConditionsYield
Stage #1: cyclohexanone; tert-butyldimethylsilyl chloride With triethylamine for 1h; Inert atmosphere;
Stage #2: With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 3h; Inert atmosphere;
A n/a
B 11%
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