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10124-48-8

Basic Information
CAS No.: 10124-48-8
Name: Aminomercuric chloride
Article Data: 29
Molecular Structure:
Molecular Structure of 10124-48-8 (Aminomercuric chloride)
Formula: ClH2HgN
Molecular Weight: 252.066
Synonyms: Mercury amide chloride(Hg(NH2)Cl);Ammoniated mercuric chloride;Ammoniated mercury;Mercuricamidochloride;Mercuric ammonium chloride;Mercury amide chloride;Mercuryamine chloride;Mercury ammonium chloride;Mercury, ammonobasic (HgNH2Cl);White mercuric precipitate;White precipitate;
EINECS: 233-335-8
Density: 5.7 g/cm3
Melting Point: 383 °C (dec.)
Boiling Point: sublimes [CRC10]
Solubility: insoluble H2O, EtOH; soluble warm acid [CRC10]
Appearance: white powder
Hazard Symbols: VeryT+, DangerousN
Risk Codes: 26/27/28-33-50/53
Safety: 13-28-45-60-61
Transport Information: UN 1630
PSA: 26.02000
LogP: 0.79670
Synthetic route

ammonium chloride

7664-41-7

ammonia

A

10124-48-8

Hg(NH2)Cl

B

mercury(II) diammonium chloride

C

Hg2N(1+)*Cl(1-)*H2O=Hg2NCl*H2O

Conditions
ConditionsYield
With HgCl2 In water dissolving mixt. of NH4Cl and HgCl2 in H2O, then in 8 % NH3 soln., shaking 6 days at ambient temp.; quality of products depending on ratio of educts and solvents;

diammonium hydrogenphosphate

10124-48-8

Hg(NH2)Cl

Conditions
ConditionsYield
With mercury dichloride In not given
With HgCl2 In not given
7664-41-7

ammonia

10124-48-8

Hg(NH2)Cl

Conditions
ConditionsYield
With mercury dichloride In ammonia byproducts: NH4Cl;
With HgCl2 In ammonia byproducts: NH4Cl; NH3 (liquid);
7664-41-7

ammonia

mercury dichloride

A

10124-48-8

Hg(NH2)Cl

B

ammonium chloride

Conditions
ConditionsYield
In water calcd. amts. of educts; washing with H2O, drying 110°C;
In water calcd. amts. of educts; washing with H2O, drying 110°C;
7664-41-7

ammonia

mercury dichloride

A

10124-48-8

Hg(NH2)Cl

B

mercury(II) diammonium chloride

Conditions
ConditionsYield
With KCL In water in presence of KCl, quality of products depending on ratio of educts and KCl;
7664-41-7

ammonia

mercury dichloride

A

10124-48-8

Hg(NH2)Cl

B

Hg2N(1+)*Cl(1-)*H2O=Hg2NCl*H2O

Conditions
ConditionsYield
In water with calcd. amts. of educts;
In water 0.032n HgCl2 reacted with NH3 soln. (various concentration), ratio of products depending on concentration of NH3 soln. and on ratio of eduts;
In water with calcd. amts. of educts;
7664-41-7

ammonia

mercury dichloride

A

10124-48-8

Hg(NH2)Cl

B

Hg2N(1+)*Cl(1-)=Hg2NCl

Conditions
ConditionsYield
With potassium hydroxide In water in presence of KOH;
With KOH In water in presence of KOH;
7664-41-7

ammonia

mercury dichloride

A

10124-48-8

Hg(NH2)Cl

B

2Hg2N(1+)*2Cl(1-)*HgCl2=(Hg2NCl)2*HgCl2

Conditions
ConditionsYield
In water excess of HgCl2, ambient temp.;

mercury(I) oxide

ammonium chloride

A

10124-48-8

Hg(NH2)Cl

B

7732-18-5

water

C

mercury

Conditions
ConditionsYield
In water in presence of NH3;

Hg(2+)*2NH3*2Cl(1-)=Hg(NH3)2Cl2

10124-48-8

Hg(NH2)Cl

Conditions
ConditionsYield
careful treatment;
Raw Materials
7664-41-7
Downstream Products
7664-41-7
13759-23-4
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Chemistry

Chemical Name: Aminomercuric chloride
IUPAC NAME: Amino(chloro)mercury
CAS No.: 10124-48-8
EINECS: 233-335-8
RTECS: OV7020000
Molecular Formula: ClH2HgN
Molecular Weight: 252.07 g/mol
Melting Point: 383°C (dec.)
Following is the structure of Mercury amide chloride (10124-48-8):


The chemical synonymous of Mercury amide chloride (10124-48-8) are Aminomercurychloride ; Ammoniated ; Ammoniatedmercuricchloride ; Hydrargyrumammoniatum ; Hydrargyrumprecipitatumalbum ; Mercuricamidochloride ; Mercury(Ii)chlorideammonobasic ; Mercury,ammonobasic(Hgnh2cl)

Uses

 Mercury amide chloride (10124-48-8) is mainly used in the pharmaceutical industry.

Toxicity Data With Reference

1.    

orl-rat LD50:86 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
2.    

skn-rat LD50:1325 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
3.    

orl-mus LD50:68 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
4.    

ipr-mus LD50:7500 µg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
5.    

ipr-rat TDLo:8925 µg/kg/17W-I

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 28 (5)(1984),46.

Consensus Reports

Mercury and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Safety Profile

A poison by ingestion. Moderately toxic by skin contact. Explosive reaction with halogens or amine metal salts. When heated to decomposition it emits very toxic fumes of Cl, NOx, and Hg. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC.
Hazard Codes:
N: Dangerous for the environment
T+: Very toxic
Risk Statements about Mercury amide chloride (10124-48-8):
R33 Danger of cumulative effects.
R26/27/28: Very toxic by inhalation, in contact with skin and if swallowed.
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements about Mercury amide chloride (10124-48-8):
S13 Keep away from food, drink and animal foodstuffs.
S28 After contact with skin, wash immediately with plenty of soap-suds.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S60 This material and its container must be disposed of as hazardous waste. 
S61 Avoid release to the environment. Refer to special instructions / safety data sheets.

Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Organo) TWA 0.01 mg/m3; STEL 0.03 mg/m3 (skin)
DOT Classification:  6.1; Label: Poison