Detail of "1013-88-3"

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CAS Number:
1013-88-3
Name:
Benzophenone imine
Molecular Structure:
Formula:
C₁₃H₁₁N
Molecular Weight:
181.2331
Synonyms:
Diphenylmethane imine;Diphenylmethanimine;Iminodiphenylmethane;a-Phenylbenzenemethanimine;Benzenemethanimine, a-phenyl-;Methylenimine,1,1-diphenyl- (6CI,7CI,8CI);1,1-Diphenylmethaneimine;1,1-Diphenylmethanimine;1,1-Diphenylmethylenimine;Benzhydrylidenimine;Benzhydrylimine;Benzophenoneimine;Benzophenonimine;Diphenylketimine;
Density:
0.99 g/cm³
Melting Point:
-30 °C
Boiling Point:
282 °C at 760 mmHg
Flash Point:
124.3 °C
Solubility:
0.3 g/L (25 °C) in water
Appearance:
colorless or light yellow liquid
Hazard Symbols:
Xi,N,Xn
Risk Codes:
36/37/38-51/53-38-22
Safety:
26-36-61-37 Details

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Reference

Organoboron compounds: Organoboron compounds. Communication 311. Synthesis of diarylketiminoboranes from diarylketimines and thioboric acid esters. Mikhailov, B. M. 1013-88-3 and 61209-21-0 are also occured in this study.; Ter-Sarkisyan, G. S.; Govorov, N. N.; Nikolaeva, N. A. (Inst. Org. Khim. im. Zelinskogo, Moscow, USSR). Izv. Akad. Nauk SSSR, Ser. Khim., (8), 1820-3 (Russian) 1976. CODEN: IASKA6. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) RR1C:NBR22 (R = R1 = Ph, R2 = Ph, Bu; R = Ph, R1 = o-, m-MeC6H4, R2 = Bu) were prepd. in 65.5-79.5% yields by treating R22BBu with RR1C:NH. Refluxing Ph2BSBu with Ph(o-MeC6H4)C:NH in hexane gave 78.5% of the dimer I. Ph(o-MeC6H4)C:NBBu2 dimerized easily on heating at 20.degree.. .

Synthesis, isomerism and supramolecular chemistry of diphenylmethanimine complexes of the coinage metals: Synthesis, isomerism and supramolecular chemistry of diphenylmethanimine complexes of the coinage metals. Schneider, Wolfgang; Bauer, Andreas; Schmidbaur, Hubert ( Anorg.-chem. Inst., Tech. Univ. Muenchen, Garching D-85747, Germany). Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry, (3), 415-420 (English) 1997 Royal Society of Chemistry. CODEN: JCDTBI. ISSN: 0300-9246. DOCUMENT TYPE: Journal CA Section: 78 (Inorganic Chemicals and Reactions) Section cross-reference(s): 75 The reactions of [AuCl(SMe2)] or [AuBr(tetrahydrothiophene)] with 1 equiv of diphenylmethanimine gave [AuCl(Ph2C=NH)] (1a), [Au(Ph2C=NH)2][AuCl2] (1b) and [Au(Ph2C=NH)2][AuBr2] (2), resp. Treatment of 1a, 1b with KI in the two-phase system dichloromethane-H2O induced a redox process to give Au0 and [Au(Ph2C=NH)2][I3] (3). The same result was obtained when AuI and Ph2C=NH were allowed to react under anhyd. and O-free conditions. Cu(I) iodide reacted with an excess of Ph2C=NH with formation of [CuI(Ph2C=NH)] (4). Bis(diphenylmethanimine) complexes of Au, [Au(Ph2C=NH)2]BF4 (5), and Ag, [Ag(Ph2C=NH)2]BF4 (6), were prepd. by the reaction of 2 equiv of the ketimine and [Au(PhCN)2]BF4 or AgBF4 in CH2Cl2 or THF solns., resp. The crystal structures of 1a, 1b, 2, 3, 5×CH2Cl2 and 6 were detd. The (Ph2C=NH)AuCl units of 1a form infinite zigzag chains via weak Au×××Au contacts [3.3633(5) ?]. In 1b two AuCl2- anions and two (Ph2C=NH)2Au+ cations form a tetranuclear Z-type unit with Au×××Au contacts of 3.1944(5) [Au(1)×××Au(2)], 3.604(1) [Au(1)×××Au(2')] and 3.392(1) ? [Au(1)×××Au(1')]. The N-H×××Cl geometry suggests H bonding between the H and Cl atoms of neighboring ions.There are some commonly used reagents with their cas registry numbers 29892-37-3 and 1013-88-3 in this article. The Br compd. 2 is isostructural to the chloride 1b with slightly longer Au×××Au distances. 3 Shows bis(diphenylmethanimine)gold(I) cations and triiodide anions with no anomalies in the packing and in bond distances and angles. The geometry of the Ag(I) and Au(I) complexes 5 and 6 are quite similar except for the observation that the Au-N bond is 0.11 ? shorter than the Ag-N bond, which suggests that two-coordinate Au(I) is indeed smaller than two-coordinate Ag(I) in systems with N-contg. ligands, as previously obsd. for phosphine complexes. .

Detail of "1013-88-3"

Benzophenone imine

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