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10137-69-6

Basic Information
CAS No.: 10137-69-6
Name: 3-CYCLOHEXENYLTRICHLOROSILANE
Article Data: 6
Molecular Structure:
Molecular Structure of 10137-69-6 (3-CYCLOHEXENYLTRICHLOROSILANE)
Formula: C6H9 Cl3 Si
Molecular Weight: 215.582
Synonyms: 3-CYCLOHEXENYLTRICHLOROSILANE;Cyclohexenyl trichlorosilane;(3-cyclohexenyl)trichloro-silan;4-(trichlorosilyl)-cyclohexen;cyclohexenyl;trichloro-3-cyclohexen-1-yl-silan;trichloro-3-cyclohexenylsilane;trichloro-3-cyclohexen-1-ylsilane
EINECS: 233-377-7
Density: 1,25 g/cm3
Melting Point: <0°C
Boiling Point: 87-88°C 16mm
Flash Point: 90°C
Solubility:

Stability

    Stable. Probably incompatible with water, alcohols, strong bases, strong oxidizing agents.Probably water sensitive.

Toxicology

    Corrosive - causes burns. Skin or eye contact may lead to serious b
Appearance: colourless fuming liquid
Risk Codes: 34
Safety: Moderately toxic by ingestion and skin contact. An eye and severe skin irritant. A corrosive material. It fumes in moist air, releasing HCl. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl. See also CHLOROSILANES.
PSA: 0.00000
LogP: 3.75200
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Chemistry

Product Name: Cyclohexenyl trichlorosilane (CAS NO.10137-69-6)


Molecular Formula: C6H9Cl3Si
Molecular Weight: 215.58g/mol
Mol File: 10137-69-6.mol
Einecs: 233-377-7
Appearance: Colourless fuming liquid
Melting Point: <0°C
Boiling point: 202.4 °C at 760 mmHg
Flash Point: 88.4 °C
Density: 1,25 g/cm3
Refractive index: 1.4905
Stability: Stable. Probably incompatible with water, alcohols, strong bases, strong oxidizing agents. Probably water sensitive.
Surface Tension: 29 dyne/cm
Enthalpy of Vaporization: 42.07 kJ/mol
Vapour Pressure: 0.418 mmHg at 25°C
H-Bond Donor: 0
H-Bond Acceptor: 0
Structure Descriptors of Cyclohexenyl trichlorosilane (CAS NO.10137-69-6):
  IUPAC Name: trichloro(cyclohex-3-en-1-yl)silane
  Canonical SMILES: C1CC(CC=C1)[Si](Cl)(Cl)Cl
  InChI: InChI=1S/C6H9Cl3Si/c7-10(8,9)6-4-2-1-3-5-6/h1-2,6H,3-5H2
  InChIKey: TTYRJPILQGWBOQ-UHFFFAOYSA-N

Toxicity Data With Reference

1.    

skn-rbt 5 mg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1227.
2.    

eye-rbt 250 µg/24H SEV

    85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,1227.
3.    

orl-rat LD50:2830 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.
4.    

skn-rbt LD50:630 mg/kg

    AIHAAP    American Industrial Hygiene Association Journal. 23 (1962),95.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion and skin contact. An eye and severe skin irritant. A corrosive material. It fumes in moist air, releasing HCl. Combustible when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Cl. See also CHLOROSILANES.
Safety Information of Cyclohexenyl trichlorosilane (CAS NO.10137-69-6):
Risk Statements: 34  
34:  Causes burns 
Safety Statements: 26-36/37/39
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing  
37:  Wear suitable gloves 
39:  Wear eye/face protection 

Standards and Recommendations

DOT Classification:  8; Label: Corrosive

Specification

 Cyclohexenyl trichlorosilane ,its CAS NO. is 10137-69-6,the synonyms is 3-Cyclohexenyltrichlorosilane ; 4-16-00-01554 (Beilstein Handbook Reference) ; BRN 2935909 ; Cyclohexene, 4-(trichlorosilyl)- ; EINECS 233-377-7 ; Trichloro-3-cyclohexenylsilane ; Silane, (3-cyclohexenyl)trichloro- ; Silane, trichloro-3-cyclohexen-1-yl- .