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CAS No.: | 102-50-1 |
---|---|
Name: | 2-Methyl-4-methoxybenzenamine |
Article Data: | 32 |
Molecular Structure: | |
Formula: | C8H11NO |
Molecular Weight: | 137.181 |
Synonyms: | p-Anisidine,2-methyl- (7CI,8CI);2-Amino-5-methoxytoluene;2-Methyl-4-(methyloxy)aniline;2-Methyl-4-anisidine;2-Methyl-4-methoxyaniline;2-Methyl-4-methoxybenzenamine;2-Methyl-p-anisidine;4-Methoxy-2-methylaniline;4-Methoxy-2-methylbenzenamine;4-Methoxy-o-toluidine;NSC 66563;[2-Methyl-4-(methyloxy)phenyl]amine; |
EINECS: | 203-036-7 |
Density: | 1.065 g/cm3 |
Melting Point: | 13-14 °C(lit.) |
Boiling Point: | 249.4 °C at 760 mmHg |
Flash Point: | 113.5 °C |
Solubility: | insoluble, |
Appearance: | brick red crystals or liquid |
Hazard Symbols: | Xi,Xn,T |
Risk Codes: | 36/37/38-40-45 |
Safety: | 26-36/37/39-53-45 |
PSA: | 35.25000 |
LogP: | 2.16700 |
Conditions | Yield |
---|---|
With hydrogen; platinum(IV) oxide In isopropyl alcohol under 2327.2 Torr; | 98.5% |
With sodium formate In ethanol at 85℃; for 1h; | 87% |
With tetrahydroxydiboron; water at 80℃; for 8h; | 80% |
4-methoxy-2-methylphenyl boronic acid
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With sodium hydroxide; hydroxylamine-O-sulfonic acid In acetonitrile at 20℃; for 16h; | 89% |
4-bromo-3-methylanisole
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With ammonium sulfate; (R)-(-)-1-[(SP)-2-(dicyclohexylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; bis(tri-ortho-tolylphosphine)palladium(0); sodium t-butanolate In 1,4-dioxane at 100℃; for 6h; Inert atmosphere; Glovebox; | 80% |
With ammonium hydroxide; copper(l) iodide; potassium carbonate; 4R-4-hydroxyproline In dimethyl sulfoxide at 70℃; for 36h; | 77% |
1-(4-methoxy-2-methylphenyl)-1,2-hydrazinedicarboxylic acid bis(2,2,2-trichloroethyl) ester
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With acetic acid; zinc for 0.75h; Ambient temperature; | 76% |
1-chloro-4-methoxy-2-methylbenzene
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With ammonium hydroxide; potassium phosphate; copper(l) iodide; N1,N2-bis(2,4,6-trimethoxyphenyl)oxalamide In water; dimethyl sulfoxide at 120℃; for 48h; Inert atmosphere; | 64% |
With bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]; N-[2-(di(1-adamantyl)phosphino)phenyl]morpholine; ammonia; sodium t-butanolate In 1,4-dioxane at 65℃; for 24h; Inert atmosphere; chemoselective reaction; | 52% |
N-(4-methoxy-2-methylphenyl)acetamide
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With hydrogenchloride |
Conditions | Yield |
---|---|
With sulfuric acid at 25℃; durch wochenlange Einw.; |
para-methoxynitrobenzene
methylmagnesium chloride
A
N-methyl-N-(4-methoxyphenyl)amine
B
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; palladium on activated charcoal 1) THF, 20 min, -30 deg C, 2) 20 deg C, 2 h; Yield given. Multistep reaction. Yields of byproduct given; |
2-methyl-4-methoxyaniline
Conditions | Yield |
---|---|
With hydrogenchloride |
hydrogenchloride
1-(4-methoxy-2-methyl-phenyl)-ethanone oxime
2-methyl-4-methoxyaniline
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1. | otr-rat:emb 51,500 ng/plate | JJATDK JAT, Journal of Applied Toxicology. 1 (1981),190. |
Suspected carcinogen with experimental carcinogenic and tumorigenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Other safty informations about 2-METHYL-p-ANISIDINE(102-50-1):
Hazard Codes: Xi,Xn,T (Irritant;Harmful;Toxic)
Risk Statements :
R36/37/38:Irritating to eyes, respiratory system and skin
R40:Limited evidence of a carcinogenic effect
R45 :May cause cancer
Safety Statements :
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection
S53:Avoid exposure - obtain special instruction before use
S45 :In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR : 2810
WGK Germany : 3