Detail of "103-67-3"

CAS Number:
103-67-3
Name:
Benzenemethanamine,N-methyl-
Superlist Name:
N-Methylbenzylamine
Molecular Structure:
Formula:
C₈H₁₁N
Molecular Weight:
121.18
Deleted CAS:
854881-74-6
Synonyms:
Benzylamine,N-methyl- (8CI);Benzylmethylamine;N-(Phenylmethyl)methylamine;N-Benzyl-N-methylamine;N-Benzylmethylamine;N-Methyl-1-phenylmethanamine;N-Methyl-N-(phenylmethyl)amine;N-Methyl-N-benzylamine;N-Methylbenzenemethanamine;NSC 8059;
EINECS:
203-133-4
Density:
0.939 g/mL at 25 °C(lit.)
Melting Point:
-24 °C
Boiling Point:
180.5 °C at 760 mmHg
Flash Point:
77.8 °C
Solubility:
Water: 65 g/L (20°C )
Appearance:
Colorless to light yellow liquid
Hazard Symbols:
C
Risk Codes:
34-42/43-22
Safety:
23-26-36/37/39-45 Details
Transport Information:
UN 2735 8/PG 2

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Plant growth regulators: Plant growth regulators. Mabelis, Richard Peter (Imperial Chemical Industries PLC, UK). Eur. Pat. Appl. EP 112629 A1 4 Jul 1984, 20 pp. DESIGNATED STATES: R: AT, BE, CH, DE, FR, GB, IT, LI, NL, SE. (English). (European Patent Organization). CODEN: EPXXDW. CLASS: IC: C07D307-93; C07D213-38; C07C087-28. ICA: A01N045-00. APPLICATION: EP 83-306682 2 Nov 1983. PRIORITY: GB 82-34274 1 Dec 1982. DOCUMENT TYPE: Patent CA Section: 16 (Fermentation and Bioindustrial Chemistry) N-Hydrocarbyl-N-arylmethylamines selectively ppt. gibberellin A4 (GA4) [468-44-0] and GA7 [510-75-8] from fermn. broths, leaving GA3 [77-06-5] in soln. Thus, a 360 L of a concd. EtOAc ext. from Gibberella fujikuroi fermn. broth was treated with 720 L PrOH and 77 kg N-benzyl-N-methylamine [103-67-3] to give a ppt. contg. the amine salt PrOH solvates of GA4 (12.1%) and GA7 (79.7%), and only 7.3% that of GA3. The free gibberellins were obtained from the salt by treatment with citric acid.

Carcinoma of the esophagus of rabbits induced with N-methyl-benzylamine and sodium nitrite: Carcinoma of the esophagus of rabbits induced with N-methyl-benzylamine and sodium nitrite. Iizuka, Toshifumi; Ichimura, Setsuko; Kawachi, Takashi; Hirota, Teruyuki; Itabashi, Masayuki (Serol. Div., Natl. Cancer Cent. Res. Inst., Tokyo, Japan). Gann, 68(6), 829-35 (English) 1977. CODEN: GANNA2. DOCUMENT TYPE: Journal CA Section: 4 (Toxicology) Esophageal carcinomas were induced in 3 of 5 rabbits given 0.25% N-methylbenzylamine [103-67-3] and 0.16% NaNO2 in their drinking water. The 3 rabbits with carcinoma had consumed >94 g NaNO2 and had survived >536 exptl. days. The esophageal carcinomas were a slightly elevated type, and no polypoid lesions were seen. They were classified histol. as squamous cell carcinomas or adenosquamous carcinomas, or both. No metastases were found. The other 2 rabbits died early in the expt. before any esophageal carcinoma had developed.