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103-70-8

Basic Information
CAS No.: 103-70-8
Name: FORMANILIDE
Article Data: 478
Molecular Structure:
Molecular Structure of 103-70-8 (FORMANILIDE)
Formula: C7H7 N O
Molecular Weight: 121.139
Synonyms: Formanilide(6CI,7CI,8CI); Carbanilaldehyde; Formamidobenzene; Formylaniline;N-Formylaniline; N-Phenylformamide; NSC 203239; NSC 8862
EINECS: 203-136-0
Density: 1.14g/cm3
Melting Point: 46-48 °C(lit.)
Boiling Point: 166 °C14 mm Hg(lit.)
Flash Point: 150.2°C
Solubility: Toxicity data
"> moderate

Stability

    Stable. Combustible. Incompatible with strong oxidizing agents.

Toxicology

    Irritant. May be harmful - toxicology not fullyinvestigated.

    Toxicity data

Appearance: white or light yellow crystals or powder
Risk Codes: 22
Safety: Poison by ingestion and intravenous routes. When heated to decomposition it emits toxic fumes of NOx.
PSA: 29.10000
LogP: 1.96380
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Chemistry

Chemistry informtion about Formylaniline (CAS NO.103-70-8) is:
IUPAC Name: N-phenylformamide
Synonyms: Aniline, N-Formyl- ; Carbanilaldehyde ; Formamide, N-Phenyl- ; Formamidobenzene ; Formamilide ; Formylaniline ; N-Formanilide ; N-Formyl-Anilin
MF: C7H7NO
MW: 121.14
EINECS: 203-136-0 
Density: 1.14 g/cm3
Melting Point: 46-48 °C(lit.)
Flash Point: 150.2 °C
Boiling Point: 271 °C at 760 mmHg
Vapour Pressure: 0.00662 mmHg at 25°C
Enthalpy of Vaporization: 50.92 kJ/mol
Merck: 14,4238
BRN: 906934
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
Following is the molecular structure of Formylaniline (CAS NO.103-70-8) is:

Production

Preparation Products are 4-Aminobenzotrifluoride-->4-Aminodiphenylamine-->N-Methylformanilide-->phthalogen auxiliary BSK-->phthalogen auxiliary agent BSM .

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
dog LDLo intravenous 400mg/kg (400mg/kg)
behavioral: somnolence (general depressed activity) behavioral: muscle weakness lungs, thorax, or respiration: respiratory stimulation
U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 19, 1941.
dog LDLo oral 400mg/kg (400mg/kg)   U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 19, 1941.
frog LDLo oral 800ug/kg (0.8mg/kg)   U.S. Public Health Service, Public Health Bulletin. Vol. 271, Pg. 19, 1941.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Poison by ingestion and intravenous routes. When heated to decomposition it emits toxic fumes of NOx
Risk Statements:
R22:Harmful if swallowed. 
Safety Statements:
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes.
WGK Germany: 2
RTECS: BY1780000
F:
F 8: Photosensitive.

Specification

Formylaniline (CAS NO.103-70-8) is a white or light yellow crystals or powder.It may be sensitive to prolonged exposure to air and soluble in water. 
It is an amide. Amides/imides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides/imides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Exposure to Formylaniline may cause cyanosis, headache, dizziness, confusion, decreased blood pressure, convulsions and coma.Formylaniline is probably combustible.