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Detail of "103029-74-9"

  • CAS Number:
  • 103029-74-9
  • Name:
  • 2-Propenoic acid,2-cyano-3-(3-pyridinyl)-

  • Molecular Structure:
  • Formula:
  • C9H6N2O2
  • Molecular Weight:
  • 174.16
  • Synonyms:
  • 3-Pyridineacrylicacid, a-cyano- (6CI);2-Cyano-3-(3-pyridyl)acrylic acid;
  • Density:
  • 1.361 g/cm3
  • Boiling Point:
  • 362.2 °C at 760 mmHg
  • Flash Point:
  • 172.9 °C
  • Hazard Symbols:
  • IrritantXi

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Reference

Pyrrolecarbonitrile derivatives
Pyrrolecarbonitrile derivatives. Genda, Giichi; Nakayama, Seiji (Nippon Soda Co., Ltd., Japan). Jpn. Kokai Tokkyo Koho JP 61200984 A2 5 Sep 1986 Showa, 6 pp. (Japan) CODEN: JKXXAF. CLASS: ICM: C07D401-04. ICS: C07D405-04; C07D409-04. ICI: C07D401-04, C07D207-00, C07D213-00; C07D405-04, C07D207-00, C07D307-00; C07D409-04, C07D207-00, C07D333-00. APPLICATION: JP 85-40874 1 Mar 1985.Several substances like 87388-71-4 may be metioned in this study. DOCUMENT TYPE: Patent CA Section: 27 (Heterocyclic Compounds (One Hetero Atom)) Section cross-reference(s): 1, 5 The title compds. [I; R = (substituted) thienyl, furyl, pyridyl), useful as intermediates for pharmaceuticals and agrochems., were prepd. by reaction of RCH:C(CN)CO2R1 (II; R1 = H, lower alkyl) with isocyanides R2C6H4SO2CH2NC (III; R2 = H, halo, lower alkyl). Thus, treating II (R = 2-furyl, R1 = H) with III (R2 = 4-Me) in dimethoxyethane contg. KOH at room temp. gave 92.0% I (R = 2-furyl). .
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