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Detail of "104322-63-6"

  • CAS Number:
  • 104322-63-6
  • Name:
  • 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aS,7R,8aS)-

  • Superlist Name:
  • (1S)-(+)-(10-Camphorsulfonyl)oxaziridine
  • Molecular Structure:
  • Formula:
  • C10H15NO3S
  • Molecular Weight:
  • 229.30
  • Synonyms:
  • 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, [4aS-(4aa,7a,8aR*)]-;(+)-(Camphorsulfonyl)oxaziridine;(+)-(Camphorylsulfonyl)oxaziridine;Davis' chiral oxaziridine;
  • Density:
  • 1.49 g/cm3
  • Melting Point:
  • 172-174 °C
  • Boiling Point:
  • 317.6 °C at 760 mmHg
  • Flash Point:
  • 145.9 °C
  • Appearance:
  • white crystall powder
  • Safety:
  • 22-24/25 Details

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridineCompetitive Product

Assay:98%min

Supplier:Jiangsu Changzhou Qiangda Baocheng Chemical Technical Institute [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Assay:98%

Supplier:Hangzhou Dayangchem Co., Ltd. [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Assay:99.0% Min.

Supplier:ORCHID CHEMICAL SUPPLIES LTD (OCS) [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

(1S)-(+)-(10-Camphorsulfonyl) oxaziridine Structure: CAS Number: 104322-63-6 Molecular Formula: C10H15NO3S Formula Weight: 229.30 Description: White Solid Melting Point: 172-174 °C(lit.) Assay: 98%

Supplier:Shanghai jiongli Chemical Technology Co., Ltd. [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

TOXICITY: N/A SAFETY: N/A Production: N/A Others: APIChem is a professional supplier of Research Chemicals. We have this item in stock, purity: 98%.

Supplier:Hangzhou APIChem Technology Co., Ltd. [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Name: (1S)-(+)-(10-Camphorsulfonyl)oxaziridine CAS No.: (1S)-(+)-(10-Camphorsulfonyl)oxaziridine Purity: 98% up

Supplier:SHANGHAI RC CHEMICALS CO.,LTD. [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

1g;10g;50g;100g;500g 98%,99%ee(HPLC)

Supplier:Daicel Chiral Technologies (China)CO.,LTD [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

(+)-(camphorylsulfonyl)oxaziridine

Supplier:shanghai eshine chemicals co.ltd [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

White to off white solid

Supplier:Tyger Scientific Inc. [ United States]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

(1S)-(+)-(Camphorylsulfonyl)oxaziridine

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

98% min

Supplier:SHANGHAI INFINE CHEMICALS CO.,LTD [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Supplier:DSL Chemicals (Shanghai) Co., Ltd. [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Supplier:Shanghai Zuozhou Biology Science Co.,Ltd [ China (Mainland)]

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

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CAS No.104322-63-6 (1S)-(+)-(10-Camphorsulfonyl)oxaziridine

Supplier:Beijing Donghualituo Techonlogy Development Co.,Ltd. [ China (Mainland)]

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Reference

Stereochemistry of the asymmetric oxidation of ketone enolates using (camphorylsulfonyl)oxaziridines
Stereochemistry of the asymmetric oxidation of ketone enolates using (camphorylsulfonyl)oxaziridines. Davis, Frankin A.; Haque, M. Serajul (Dep. Chem., Drexel Univ., Philadelphia, PA 19104, USA). J. Org. Chem., 51(21), 4083-5 (English) 1986. CODEN: JOCEAH. ISSN: 0022-3263. DOCUMENT TYPE: Journal CA Section: 25 (Benzene, Its Derivatives, and Condensed Benzenoid Compounds) Ketones (e.g.Several substances like 104322-63-6 may be metioned in this study., PhCOCH2R; R = Me, Ph) were converted to their enolates with a base, e.g., (Me3Si)2NNa, and then oxidized with chiral oxaziridines, e.g., I, to give chiral hydroxy ketones, e.g. (+)(R)- and (-)(S)-PhCOCH(OH)R, in 69-95% enantiomeric excess and yields as high as 88%. Generally, sodium enolates gave the highest enantiomeric excess. A mechanism is proposed to account for the chiral recognition. .
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