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104372-31-8

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Basic Information
CAS No.: 104372-31-8
Name: (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Article Data: 4
Molecular Structure:
Molecular Structure of 104372-31-8 ((1R)-(-)-(10-Camphorsulfonyl)oxaziridine)
Formula: C10H15NO3S
Molecular Weight: 229.3
Synonyms: 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, [4aR-(4aa,7a,8aR*)]-;(-)-(Camphorsulfonyl)oxaziridine;(-)-(Camphorylsulfonyl)oxaziridine;
Density: 1.49 g/cm3
Melting Point: 170-174 °C
Boiling Point: 317.6 °C at 760 mmHg
Flash Point: 145.9 °C
Appearance: White crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-24/25
PSA: 58.06000
LogP: 2.11830
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  • (1R)-(-)-(10-Camphorsulfonyl)oxaziridine

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Chemistry

Empirical Formula: C10H15NO3S
Molecular Weight: 229.296g/mol
Structure of 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole,tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)-  (CAS NO.104372-31-8):

Index of Refraction: 1.63
Molar Refractivity: 54.62 cm3
Molar Volume: 153.3 cm3
Polarizability: 21.65×10-24cm3
Surface Tension: 59.3 dyne/cm
Density: 1.49 g/cm3
Flash Point: 145.9 °C
Enthalpy of Vaporization: 55.9 kJ/mol 
Melting Point: 170-174 °C
Boiling Point: 317.6 °C at 760 mmHg
Vapour Pressure: 0.000381 mmHg at 25°C 
Product Categories: chiral;Chiral Reagents;Asymmetric Synthesis;Bicyclic Monoterpenes;Biochemistry;Oxidation;Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry;Terpenes;Intermediates & Fine Chemicals;Pharmaceuticals 
Systematic Name: (4aR,7R,8aS)-9,9-dimethyltetrahydro-4a,7-methanooxazireno[3,2-i][2,1]benzisothiazole 3,3-dioxide
SMILES: CC3(C)[C@H]2C[C@@]14ON1S(=O)(=O)C[C@]34CC2 
InChI: InChI=1/C10H15NO3S/c1-8(2)7-3-4-9(8)6-15(12,13)11-10(9,5-7)14-11/h7H,3-6H2,1-2H3/t7-,9-,10+,11?/m1/s1
InChIKey: GBBJBUGPGFNISJ-ZCZLBPHLBV

Uses

A useful synthetic intermediate. Used for asymmetric hydroxylation

Safety Profile

Hazard Codes: IrritantXi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36:Wear suitable protective clothing. 
S24/25:Avoid contact with skin and eyes.
WGK Germany: 3
F: 10