Detail of "10498-35-8"
- CAS Number:
- 10498-35-8
- Name:
Cyclohexane,1,2-dichloro-, (1R,2S)-rel-
- Molecular Structure:
- Formula:
- C6H10Cl2
- Molecular Weight:
- 153.05
- Synonyms:
- Cyclohexane,1,2-dichloro-, cis- (8CI);cis-1,2-Dichlorocyclohexane;(1R,2S)-1,2-Dichlorocyclohexane;Cyclohexane, 1,2-dichloro-, (1R,2S)-;AC1L2559;CID66334;Cyclohexane, 1,2-dichloro-, cis-;
- Density:
- 1.14 g/cm3
- Boiling Point:
- 206.9 °C at 760 mmHg
- Flash Point:
- 66.1 °C
Cyclohexane,1,2-dichloro-, (1R,2S)-rel-
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Reference
- Isomerization of 1,4- and 1,2-dichlorocyclohexanes by antimony(V) chloride
- Isomerization of 1,4- and 1,2-dichlorocyclohexanes by antimony(V) chloride. Akiyama, Fuminori; Terashima, Kiyotaka; Matsuda, Minoru (Chem. Res. Inst. Non-Aqueous Solutions, Tohoku Univ., Sendai, Japan).Several reagents with their cas registry numbers 7647-18-9 and 10498-35-8 are used here. Nippon Kagaku Kaishi, (1), 61-5 (Japanese) 1977. CODEN: NKAKB8. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) A study of the reaction of cis-1,2-(I), trans-1,2-(II), cis-1,4-, and trans-1,4-dichlorocyclohexane with SbCl5 showed that I decompd. without isomerization, whereas the other 3 compds. isomerized, with II giving the lowest yields of products. The distribution of products (cis-1,3-, trans-1,3-, cis-1,4-, and trans-1,4-dichlorocyclohexane) was the same for all reactants and reaction times. The difference in behavior of reactants was discussed in terms of their conformations, and a mechanism involving a carbonium ion with an SbCl6- counterion as intermediate was suggested. .