CAS No.105-38-4,Vinyl propionate Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	105-38-4
Name:	Vinyl propionate
Article Data:	19

Formula:	C5H8 O2
Molecular Weight:	100.117
Synonyms:	Propionicacid, vinyl ester (6CI,8CI); NSC 5275; Vinyl propanoate; Vinyl propionate
Density:	0.919g/mLat 25°C(lit.)
Melting Point:	-80oC(lit.)
Boiling Point:	94-95°C(lit.)
Flash Point:	43°F
Hazard Symbols:	F,Xn
Risk Codes:	R11
Safety:	Mildly toxic by ingestion and inhalation. A skin and eye irritant. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, mist, fog. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
PSA:	26.30000
LogP:	1.08310

Synthetic route

: 4387-13-7
bis(formylmethyl)mercury

: 79-03-8
propionyl chloride

: 105-38-4
vinyl propionate

Conditions

Conditions	Yield
In tetrahydrofuran Heating;	90%

: 108-05-4
vinyl acetate

: 802294-64-0
propionic acid

: 105-38-4
vinyl propionate

Conditions

Conditions	Yield
With sulfuric acid; mercury(II) diacetate; copper (I) acetate at 20℃; for 2h; 30 deg C, 72 h;	30%
With [fac-Ru(CO)3(η2-CH3CH2COO)(η1-CH3CH2COO)] at 100℃; Kinetics; Reagent/catalyst;
With sulfuric acid; mercury(II) diacetate

: 802294-64-0
propionic acid

: 74-86-2
acetylene

: 105-38-4
vinyl propionate

Conditions

Conditions	Yield
With copper(I) monacetylide at 200℃; under 8826.09 Torr;
With zinc(II) propionate; pyrographite at 250℃;
With mercury(II) sulfate at 95 - 105℃;
With mercury salt-boron fluoride at 27 - 30℃;
With mercury salt-boron fluoride at 27 - 30℃;

: 2-acetoxyethyl propionate

A: 108-05-4
vinyl acetate

B: 105-38-4
vinyl propionate

Conditions

Conditions	Yield
With methanolate In gas
With methanolate In gas Product distribution; also with base F(1-);

ethylene glycol dipropionate: ethylene glycol dipropionate

: 105-38-4
vinyl propionate

Conditions

Conditions	Yield
at 550 - 560℃; Pyrolysis;

: 108-05-4
vinyl acetate

: 105-38-4
vinyl propionate

Conditions

Conditions	Yield
With propionic acid; tin(IV) chloride

: 74-85-1
ethene

: 802294-64-0
propionic acid

: 71-43-2
benzene

A: 292638-84-7
styrene

B: 103-30-0
(E)-1,2-diphenyl-ethene

C: 105-38-4
vinyl propionate

D: 108-95-2
phenol

Conditions

Conditions	Yield
With air; 1,3-diphenylpropanedione; palladium diacetate at 90℃; under 1900.13 Torr; for 8h; Product distribution; Further Variations:; Pressures; Reagents; Solvents; Temperatures; ethylene/air ratio;	A 0.213 mmol B 0.043 mmol C 0.038 mmol D 0.030 mmol

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Chemistry

Chemistry informtion about Vinyl Propionate (105-38-4) is:
IUPAC Name: Ethenyl propanoate
Synonyms: Ethenylpropanoate ; Propanoicacid,Ethenylester ; Vinyl ; Vinylester Kyseliny Propionove ; Vinylesterkyselinypropionove ; Vinylpropanoate ; Vinyl Propionate ; Propionic Acid Vinyl Ester
MF: C5H11NO2
MW: 117.15
EINECS: 207-332-7
Melting Point: −80 °C(lit.)
Density: 0.913 g/cm³
Flash Point: 13.1 °C
Boiling Point: 93 °C at 760 mmHg
Vapour Pressure: 50.4 mmHg at 25°C
Enthalpy of Vaporization: 33.28 kJ/mol
Refractive Index: n20/D 1.403(lit.)
Storage temp.: 2-8°C
BRN: 1741731
Following is the molecular structure of Vinyl Propionate (105-38-4) is:

Toxicity Data With Reference

1.	skn-rat 500 mg MLD	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 2 (1950),582.
2.	skn-rbt 10 mg/24H open MLD	AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95.
3.	eye-rbt 10 mg MLD	AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. 2 (1950),582.
4.	sce-hmn:lym 400 µmol/L	MUREAV Mutation Research. 279 (1992),75.
5.	orl-rat LD50:4760 mg/kg	AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95.
6.	ihl-rat LCLo:4000 ppm/4H	AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Mildly toxic by ingestion and inhalation. A skin and eye irritant. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. To fight fire, use alcohol foam, mist, fog. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
Hazard Codes:
F: Flammable
Xn: Harmful
Risk Statements:
R11: Highly flammable.
R21: Harmful in contact with skin.
R36/38: Irritating to eyes and skin.
Safety Statements:
S9: Keep container in a well-ventilated place.
S16: Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S29: Do not empty into drains.
S33: Take precautionary measures against static discharges.
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 3272 3/PG 2
WGK Germany: 1
RTECS: UF8575000
F:
F 8: Photosensitive.
F 10: Keep under argon.
F 23: Sensitive to air.
HazardClass: 3
PackingGroup: II