Detail of "10576-12-2"

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Comparison of synthetic routes to DL-canaline

Comparison of synthetic routes to DL-canaline. Korpela, Timo; Lundell, Juhani; Pasanen, Paavo (Dep.In this experiment, several chemicals are used like 10576-12-2 Chem. Biochem., Univ. Turku, Turku, Finland). Org. Prep. Proced. Int., 9(2), 57-62 (English) 1977. 10576-12-2 is the cas registry number of certain chemical which is used as reagents here. CODEN: OPPIAK. DOCUMENT TYPE: Journal CA Section: 34 (Synthesis of Amino Acids, Peptides, and Proteins) DL-Canaline (I) [DL-H2NOCH2CH2CH(NH2)CO2H] was prepd. in good yields (~50% in MeOH) by treating BrCH2CH2CH(NHBz)CO2Me with BzNHONa and hydrolyzing the resulting BzNHOCH2CH2CH(NHBz)CO2Me. I was prepd. in poorer yields by treating lactone II with Ph2C:NONa and hydrolyzing the resulting BzNHOCH2CH2CH(NHBz)CO2Me. The attempted synthesis of I by the coupling of CH2:CHCHO to MeC(:NOH)OEt to give MeC(OEt):NOCH2CH2CHO was unsuccessful. ..

Comparison of synthetic routes to DL-canaline

Comparison of synthetic routes to DL-canaline. Korpela, Timo; Lundell, Juhani; Pasanen, Paavo (Dep.In this experiment, several chemicals are used like 10576-12-2 Chem. Biochem., Univ. Turku, Turku, Finland). Org. Prep. Proced. Int., 9(2), 57-62 (English) 1977. 10576-12-2 is the cas registry number of certain chemical which is used as reagents here. CODEN: OPPIAK. DOCUMENT TYPE: Journal CA Section: 34 (Synthesis of Amino Acids, Peptides, and Proteins) DL-Canaline (I) [DL-H2NOCH2CH2CH(NH2)CO2H] was prepd. in good yields (~50% in MeOH) by treating BrCH2CH2CH(NHBz)CO2Me with BzNHONa and hydrolyzing the resulting BzNHOCH2CH2CH(NHBz)CO2Me. I was prepd. in poorer yields by treating lactone II with Ph2C:NONa and hydrolyzing the resulting BzNHOCH2CH2CH(NHBz)CO2Me. The attempted synthesis of I by the coupling of CH2:CHCHO to MeC(:NOH)OEt to give MeC(OEt):NOCH2CH2CHO was unsuccessful. ..