CAS No.106-45-6,p-Toluenethiol Suppliers,MSDS download

Detail of "106-45-6"

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CAS Number:

106-45-6

Name:

p-Toluenethiol

Molecular Structure:

Formula:

C₇H₈S

Molecular Weight:

124.21

Synonyms:

p-Toluenethiol(7CI,8CI);1-Mercapto-4-methylbenzene;4-Mercaptotoluene;4-Methyl-1-thiophenol;4-Methylbenzenethiol;4-Methylphenyl mercaptan;4-Methylphenylthiol;4-Methylthiophenol;4-Thiocresol;4-Toluenethiol;NSC2227;NSC 229565;p-Mercaptotoluene;p-Methylbenzenethiol;p-Methylbenzenthiol;p-Methylphenyl mercaptan;p-Methylphenylthiol;p-Methylthiophenol;p-Thiocresol;p-Tolyl mercaptan;p-Tolylthiol;Benzenethiol, 4-methyl-;

EINECS:

203-399-1

Density:

1.049 g/cm³

Melting Point:

84-86 °C

Boiling Point:

195 °C at 760 mmHg

Flash Point:

69.5 °C

Solubility:

slightly soluble

Appearance:

White or colorless solid melt

Hazard Symbols:

Risk Codes:

R20/21/22;R36/37/38

Safety:

Poison by intraperitoneal route. A flammable liquid. When heated to decomposition it emits toxic fumes of SO_x. Details

Reference

p-Tolyl ester of p-toluenethiosulfonic acid: p-Tolyl ester of p-toluenethiosulfonic acid. Fleszar, Boleslaw; Sanecki, Przemyslaw (Politechnika Rzeszowska, Pol.). Pol. PL 117533 B1 30 Sep 1983, 2 pp. (Polish). (Poland). CODEN: POXXA7. CLASS: IC: C25B003-04; C07C149-44. APPLICATION: PL 78-210794 7 Nov 1978. DOCUMENT TYPE: Patent CA Section: 45 (Industrial Organic Chemicals, Leather, Fats, and Waxes) Section cross-reference(s): 25 Pure p-tolyl p-toluenethiosulfonate (I) [2943-42-2] is prepd. in high yield by electroredn. of p-toluenesulfonyl chloride [98-59-9] or Na p-toluenesulfonate (II) [657-84-1] in an org. solvent in the presence of 0.5-5 mol/dm3 inorg. acid and, optionally, 31 mol% I or p-thiocresol [106-45-6] as autocatalyst. The electrolysis proceeds until the elec. charge transfer 3 Faraday/mol is reached. Thus, when 0.2 mol II soln. in 1 dm3 99.8% EtOH and 129 cm3 36% HCl contg. 0.01 mol I were electrolyzed at -0.5 V with respect to SCE, the I yield was 0.095 mol after 19,300 C were passed through the soln.

Photocurable compositions containing S-aryl arylcarbothioic acid esters as photoinitiators: Photocurable compositions containing S-aryl arylcarbothioic acid esters as photoinitiators. Wang, Richard H. S.; Pacifici, James G.; Newland, Gordon C. (Eastman Kodak Co., USA). U.S. US 4012302 15 Mar 1977, 4 pp. (English). (United States of America). CODEN: USXXAM. CLASS: IC: C08L001-00. NCL: 204159120. APPLICATION: US 76-658328 17 Feb 1976. DOCUMENT TYPE: Patent CA Section: 36 (Plastics Manufacture and Processing) Section cross-reference(s): 25 Four title esters were prepd. and used as photochem. crosslinking catalysts for ethylenically-unsatd. compds. Thus, 0.02 mol isophthaloyl chloride [99-63-8] and 0.044 mol p-toluenethiol [106-45-6] were refluxed 3 h in 75 mL pyridine to give a quant. yield of bis(S-4-methylphenyl) thioisophthalate (I) [41117-93-5]. An mixt. of maleic anhydride-propylene glycol copolymer [25749-49-9] and styrene contg. 2% I was coated (0.004 in.) onto a glass plate and subjected to an 80 W/in. Hg lamp for 2 min to form a film.In this experiment, several chemicals are used like 41117-93-5 and 62610-78-0 The ratio of extractable-nonextractable material in the film in CH2Cl2 was 0.24, compared to 1.0 for a control not contg. I. .

Detail of "106-45-6"

p-Toluenethiol

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