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CAS No.: | 1085-98-9 |
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Name: | DICHLOFLUANID |
Article Data: | 10 |
Molecular Structure: | |
Formula: | C9H11 Cl2 F N2 O2 S2 |
Molecular Weight: | 333.235 |
Synonyms: | Sulfamide,N-[(dichlorofluoromethyl)thio]-N',N'-dimethyl-N-phenyl- (7CI,8CI);BAY 47531;Bayer 47531;Chlormethionate;Coatcide TW;Dichlofluanid;Dichlofluanide;Diclofluanide;Elvaron;Eparen;Euparen;Euparen WG;Lichenicide 246;N,N-Dimethyl-N'-(dichlorofluoromethylthio)-N'-phenylsulfamide;N,N-Dimethyl-N'-phenyl-N'-(dichlorofluoromethylthio)sulfamide;N,N-Dimethyl-N'-phenyl-N'-(fluorodichloromethylthio)sulfamide;N-Phenyl-N-(fluorodichloromethylsulfenyl)-N',N'-dimethylsulfamide;N-[(Dichlorofluoromethyl)thio]-N',N'-dimethyl-N-phenylsulfamide;NSC 218451;N'-(Dichlorofluoromethylthio)-N,N-dimethyl-N'-phenylsulfamide;Oiparen;Pecudin;Preventol A 4;Preventol A 4S; |
EINECS: | 214-118-7 |
Density: | 1.553 g/cm3 |
Melting Point: | 105.6℃ |
Boiling Point: | 336.8 ºC at 760 mmHg |
Flash Point: | 157.5ºC |
Solubility: | 1.3mgl-1 |
Hazard Symbols: | XnNF |
Risk Codes: | 20-36-43-50/53-20/21/22-11 |
Safety: | 24-37-60-61-36-26-16 |
PSA: | 74.30000 |
LogP: | 4.08680 |
N,N-dimethyl-N'-phenylsulfonamide
dichlorofluoromethanesulphenyl chloride
N-dichlorofluoromethylthio-N',N'-dimethyl-N-phenylsulfamide
Conditions | Yield |
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Stage #1: N,N-dimethyl-N'-phenylsulfonamide With sodium hydride In toluene at 0 - 20℃; for 1h; Stage #2: dichlorofluoromethanesulphenyl chloride In toluene at 20℃; | 84.2% |
N,N-dimethyl-N'-phenylsulfonamide
triethylamine
dichlorofluoromethanesulphenyl chloride
N-dichlorofluoromethylthio-N',N'-dimethyl-N-phenylsulfamide
N-dichlorofluoromethylthio-N',N'-dimethyl-N-phenylsulfamide
bis(dichlorofluoromethyl)disulfane
Conditions | Yield |
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In acetone Irradiation (UV/VIS); together with other products; | |
In acetone Irradiation (UV/VIS); together with other products; |
1. | mmo-esc 10 µg/plate | MUREAV Mutation Research. 116 (1983),185. | ||
2. | mma-esc 100 µg/plate | MUREAV Mutation Research. 116 (1983),185. | ||
3. | orl-rat LD50:500 mg/kg | WRPCA2 World Review of Pest Control. 9 (1970),119. | ||
4. | ihl-rat LC50:300 mg/m3/4H | 85JFAN “Agrochemicals Handbook“, with updates, Hartley, D., and H. Kidd, eds., Nottingham, UK, Royal Soc. of Chemistry, 1983-86 A136 ,1986. | ||
5. | skn-rat LD50:1 g/kg | GUCHAZ Guide to the Chemicals Used in Crop Protection 6 (1973),179. | ||
6. | orl-mus LD50:1250 mg/kg | MEIEDD Merck Index. 10 (1983),442. | ||
7. | orl-cat LD50:1 g/kg | 85GYAZ Pflanzenschutz-und Schaedlingsbekaempfungsmittel: Abriss einer Toxikologie und Therapie von Vergiftungen 2nd ed.,Klimmer, O.R.,Hattingen, Germany.: Hundt-Verlag,1971,97. |
Moderately toxic by ingestion and skin contact. Mutation data reported. A pesticide. When heated to decomposition it emits very toxic fumes of Cl−, F−, NOx, and SOx.
Hazard Codes Xn,N,F
Risk Statements
11:Highly Flammable
20:Harmful by inhalation
21:Harmful in contact with skin
22:Harmful if swallowed
36:Irritating to the eyes
43:May cause sensitization by skin contact
50:Very Toxic to aquatic organisms
53:May cause long-term adverse effects in the aquatic environment
Safety Statements
16:Keep away from sources of ignition - No smoking
24:Avoid contact with skin
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:Wear suitable protective clothing
37:Wear suitable gloves
60:This material and/or its container must be disposed of as hazardous waste
61:Avoid release to the environment. Refer to special instructions safety data sheet