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| CAS No.: | 110-69-0 |
|---|---|
| Name: | Butyraldehyde oxime |
| Article Data: | 34 |
| Molecular Structure: | |
|
|
|
| Formula: | C4H9NO |
| Molecular Weight: | 87.1216 |
| Synonyms: | Butylaldoxime;Butyraldoxime;NSC 1487;n-Butylaldoxime;n-Butyraldoxime;Butyraldehyde,oxime (6CI,7CI,8CI);Butanaldoxime; |
| EINECS: | 203-792-8 |
| Density: | 0.894 g/cm3 |
| Melting Point: | -29.5°C |
| Boiling Point: | 148.968 °C at 760 mmHg |
| Flash Point: | 64.514 °C |
| Solubility: | <0.1 g/100 mL at 20 °C in water |
| Appearance: | colourless liquid |
| Hazard Symbols: |
 T
|
| Risk Codes: | 36-24-22 |
| Safety: | 45-36-23 |
| PSA: | 32.59000 |
| LogP: | 1.24650 |
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Chemistry
Chemistry informtion about N-Butyraldehyde Oxime (CAS NO.110-69-0) is:
IUPAC Name: (NE)-N-butylidenehydroxylamine
Synonyms: Tert-Nitrooctane ; Nitrous Acid N-Pentyl Ester ; N-Pentyl Nitrite ; Pentyl Nitrite ; N-Amyl Nitrite ; Nitramyl ; Nitrous Acid, Pentyl Ester ; Nitrousacid,Pentylester
Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes ; Organics
MF: C4H9NO
MW: 87.12
EINECS: 203-792-8
Density: 0.89 g/cm3
Melting Point: -29.5°C
Flash Point: 64.5 °C
Boiling Point: 149 °C at 760 mmHg
Vapour Pressure: 2.26 mmHg at 25°C
Enthalpy of Vaporization: 42.57 kJ/mol
Storage temp.: 1.4367
Water Solubility: <0.1 g/100 mL at 20 ºC
BRN: 1698799
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, powdered metals, acids.
Following is the molecular structure of N-Butyraldehyde Oxime (CAS NO.110-69-0) is:
Uses
N-Butyraldehyde Oxime (CAS NO.110-69-0) can be used to make plastics and rubber.
Toxicity Data With Reference
| 1. | msc-mus:lyms 1700 mg/L | MUREAV Mutation Research. 204 (1988),149. | ||
| 2. | ipr-mus LD50:200 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) AD277-689 . |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
A poison by intraperitoneal route. Mutation data reported. Flammable liquid when exposed to heat or flame. To fight fire, use alcohol foam, dry chemical. Highly explosive. Can explode during vacuum distillation. Incompatible with oxidizing materials, metallic impurities. When heated to decomposition it emits toxic fumes of NOx. See also ALDEHYDES.
Hazard Codes:
T
Risk Statements:
R36:Irritating to eyes.
R24:Toxic in contact with skin.
R22:Harmful if swallowed.
Safety Statements:
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36:Wear suitable protective clothing.
S23:Do not breathe vapour.
RIDADR: 2840
RTECS: ES3500000
HazardClass: 3
PackingGroup: III
Standards and Recommendations
DOT Classification: 3; Label: Flammable Liquid
Specification
N-Butyraldehyde Oxime (CAS NO.110-69-0) is a colourless liquid. It is slightly less dense than water and vapors heavier than air. It is highly explosive during vacuum distillation.And it is incompatible with oxidizing materials. It is also incompatible with metallic impurities. It may react with strong acids.
It may cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution. It will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.