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| CAS No.: | 110-75-8 |
|---|---|
| Name: | 2-Chloroethoxyethene |
| Article Data: | 21 |
| Molecular Structure: | |
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|
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| Formula: | C4H7 Cl O |
| Molecular Weight: | 106.552 |
| Synonyms: | Ether,2-chloroethyl vinyl (6CI,7CI,8CI); (2-Chloroethoxy)ethene;1-Chloro-2-vinyloxyethane; 2-Chloroethyl vinyl ether; 2-Vinyloxyethyl chloride;NSC 8261; Vinyl 2-chloroethyl ether; Vinyl b-chloroethyl ether; b-Chloroethyl vinyl ether |
| EINECS: | 203-799-6 |
| Density: | 1.048 |
| Melting Point: | -70 ºC |
| Boiling Point: | 109 ºC |
| Flash Point: | 16 ºC |
| Solubility: | slightly soluble |
| Appearance: | CLEAR COLORLESS TO LIGHT YELLOW LIQUID |
| Hazard Symbols: |
 
|
| Risk Codes: | R11;R20/22;R36/37/38;R41 |
| Safety: | Poison by ingestion. Moderately toxic by inhalation and skin contact. A severe eye and skin irritant. See also ETHERS. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Potentially explosive. May form dangerous peroxides on exposure to air. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORIDES and ETHERS. |
| Transport Information: | UN 1992 |
| PSA: | 9.23000 |
| LogP: | 1.38530 |
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Chemistry
Chemistry informtion about 2-Chloroethyl Vinyl Ether (CAS NO.110-75-8) is:
IUPAC Name: 2-Chloroethoxyethene
Synonyms: (2-Chlorethyl)Vinyl Ether ; (2-Chloroethoxy)-Ethen ; 1-(2-Chloroethoxy)Ethylene ; 2-Chlorethylvinylether ; 2-Chloroethoxy-Ethen ; 2-Vinyloxyethyl Chloride ; 2-Vinyloxyethylchloride ; Beta-Chloroethyl Vinyl Ether
Product Categories: Intermediates of Dyes and Pigments ; CHEPA ; 600 Series Wastewater Methods ; 8000 Series Solidwaste Methods ; Alpha Sort ; C ; CAlphabetic ; Method 601EPA ; Method 624EPA ; Method 8021 ; Volatiles/ Semivolatiles ; OthersPolymer Science ; Monomers ; Protecting and Derivatizing Reagents ; Protection and Derivatization ; Vinyl Ethers ; Neats ; Environmental Standards ; Separate Source Standards
MF: C4H7ClO
MW: 106.55
EINECS: 203-799-6
Density: 0.992 g/cm3
Melting Point: -70 °C
Flash Point: 16.1 °C
Boiling Point: 108.8 °C at 760 mmHg
Vapour Pressure: 29.9 mmHg at 25°C
Enthalpy of Vaporization: 33.32 kJ/mol
Merck: 2139
Storage temp.: Refrigerator
Following is the molecular structure of 2-Chloroethyl Vinyl Ether (CAS NO.110-75-8) is:
Toxicity Data With Reference
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD | intraperitoneal | > 500mg/kg (500mg/kg) | "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. Vol. 4, Pg. 108, 1952. | |
| rabbit | LD50 | skin | 2400mg/kg (2400mg/kg) | Union Carbide Data Sheet. Vol. 11/15/1971, | |
| rat | LCLo | inhalation | 250ppm/4H (250ppm) | Journal of Industrial Hygiene and Toxicology. Vol. 31, Pg. 343, 1949. | |
| rat | LD50 | oral | 210mg/kg (210mg/kg) | Union Carbide Data Sheet. Vol. 11/15/1971, |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Poison by ingestion. Moderately toxic by inhalation and skin contact. A severe eye and skin irritant. See also ETHERS. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Potentially explosive. May form dangerous peroxides on exposure to air. To fight fire, use alcohol foam, dry chemical. When heated to decomposition it emits toxic fumes of Cl−. See also CHLORIDES and ETHERS.
Hazard Codes:
F
Xn
T
Risk Statements:
R11:Highly flammable.
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
R39/23/24/25:Toxic by inhalation, in contact with skin and if swallowed and danger of very serious irreversible effects.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R41:Risk of serious damage to the eyes.
R20/22:Harmful by inhalation and if swallowed.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37:Wear suitable protective clothing and gloves.
S16:Keep away from sources of ignition.
S7:Keep container tightly closed.
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: UN 1992 3/PG 2
WGK Germany: 3
RTECS: KN6300000
HazardClass: 3.2
PackingGroup: III
Specification
2-Chloroethyl Vinyl Ether (CAS NO.110-75-8) is a clear colorless to light yellow liquid. It is slightly soluble in water.Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164]. 2-Chloroethyl vinyl ether forms salts with strong acids and addition complexes with Lewis acids. May react violently with strong oxidizing agents. Typically stabilized against polyermizable by addition of triethanolamine.It is dangerous when exposed to heat, flame, or oxidizers. Moderately toxic by ingestion and inhalation. Do not induce vomiting. Volatile chemicals have a high risk of being aspirated into the victim's lungs during vomiting which increases the medical problems. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and immediately call a hospital or poison control center. Immediately transport the victim to a hospital. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body.