Detail of "110-81-6"

Reference

Thermochemical study of the coordination capacity of alkyl compounds of zinc and cadmium in solutions

Thermochemical study of the coordination capacity of alkyl compounds of zinc and cadmium in solutions. Aleksandrov, Yu. A.; Fedostseva, G. A.; Tsvetkov, V. G.; Lebedev, S. A.; Kozyrkin, B. I. (Gor'k. Gos. Univ., Gorkiy, USSR). Zh. Obshch. Khim., 53(7), 1561-4 (Russian) 1983. CODEN: ZOKHA4.Several substances with their cas registry numbers 110-81-6 and 91-63-4 may be metioned in this study. ISSN: 0044-460X. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 22 A calorimetric method was used to study the assocn. of Me2Cd in soln. The coordination ability of dialkylzinc compds. is greater than that of dialkylcadmium compds. Increasing the length of the alkyl radical in dialkylzinc compds. decreases their electron accepting capacity. The stability of coordination compds. of dialkylzinc and -cadmium with Group VIA element compds. (e.g. Et2S) was studied from their thermochem. data; it is a max. for S compds. .

Conversions of tris(ethylthio)methane initiated by tert-butyl peroxide

Conversions of tris(ethylthio)methane initiated by tert-butyl peroxide. Taganliev, A.; Pastushenko, E. V.; Zorin, V. V.; Rol'nik, L. Z.; Zlotskii, S. S.; Rakhmankulov, D. L. (Ufim. Neft. Inst., Ufa, USSR). Zh. Obshch. Khim., 54(11), 2570-2 (Russian) 1984. CODEN: ZOKHA4. ISSN: 0044-460X. DOCUMENT TYPE: Journal CA Section: 22 (Physical Organic Chemistry) The reaction of (EtS)3CH with (Me3C)2O2 gave (EtS)2C:S, (EtS)2C:C(SEt)2, Et2S, Et2S2, and CH2(SEt)2. The reaction proceeded by a radical chain mechanism with 2nd-order chain termination.Except for chemicals metioned above, 110-81-6 is also used. .