Reference

Three-Component, Stereoselective Palladium-Catalyzed Synthesis of Functionalized Bicyclopentanoids

Three-Component, Stereoselective Palladium-Catalyzed Synthesis of Functionalized Bicyclopentanoids. There are some commonly used reagents like 14220-64-5 in this article. Hulin, Bernard; Newton, Linda S.; Cabral, Shawn; Walker, Aaron J.; Bordner, Jon (Pfizer Global Research and Development, Groton, CT 06340, USA). Organic Letters, 6(23), 4343-4345 (English) 2004 American Chemical Society. CODEN: ORLEF7. ISSN: 1523-7060. DOCUMENT TYPE: Journal CA Section: 24 (Alicyclic Compounds) 1,5-Cyclooctadiene can be stereoselectively transformed into a substituted bicyclo[3.3.0]octane ring system under palladium catalysis with concomitant formation of three carbon-carbon bonds. Reaction with an aryl iodide or triflate and malonate gives an exo-endo product, while the reaction with a malonate in the presence of oxygen affords a bis-endo adduct. .

p-Cyclooctenyl-p-1,5-cyclooctadienecobalt

p-Cyclooctenyl-p-1,5-cyclooctadienecobalt. [(1,2,5,6-h)-1,5-Cyclooctadiene][(1,2,3-h)-2-cycloocten-1-yl]cobalt. Gosser, L. W.; Cushing, Martin A., Jr. (Cent. Res. Dev. Dep., E. I. du Pont de Nemours and Co., Wilmington, Del., USA). Inorg. Synth., 17, 112-15 (English) 1977. CODEN: INSYA3. ISSN: 0073-8077. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) The title compd. was prepd. in 40% yield from CoCl2, 1,5-cyclooctadiene and Na.