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Basic Information
| CAS No.: | 112-72-1 |
|---|---|
| Name: | 1-Tetradecanol |
| Article Data: | 102 |
| Molecular Structure: | |
|
|
|
| Formula: | C14H30O |
| Molecular Weight: | 214.392 |
| Synonyms: | Tetradecyl alcohol;n-Tetradecan-1-ol;n-Tetradecanol;n-Tetradecyl alcohol;Tetradecanol;Tetradecanol(7CI);1-Hydroxytetradecane;1-Tetradecyl alcohol;Adol 18;Alfol 14;Conol1495;Hinol 14SS;Kalcohl 40;Kalcohl 4098;Kalcol 4098;Lanette 14;Lanette K;Lanette Wax KS;Lorol C 14;Loxanol V;Myristic alcohol;Myristyl alcohol;NSC8549;Nacol 14-95; |
| EINECS: | 204-000-3 |
| Density: | 0.833 g/cm3 |
| Melting Point: | 35-39 °C(lit.) |
| Boiling Point: | 263.2 °C at 760 mmHg |
| Flash Point: | 125.9 °C |
| Solubility: | insoluble in water |
| Appearance: | white low melting solid or flakes |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 38 |
| Safety: | 24/25 |
| PSA: | 20.23000 |
| LogP: | 4.67980 |
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Synthetic route
Conditions
| Conditions | Yield |
|---|---|
| With C32H36ClNO2P2Ru; potassium tert-butylate; hydrogen In neat (no solvent) at 120℃; under 38002.6 Torr; for 20h; Autoclave; Green chemistry; | 99% |
| With [RuCl2(2-(diphenylphosphino)-N-((6-((diphenylphosphino)methyl)pyridin-2-yl)methyl)ethan-1-amine)]; potassium tert-butylate; hydrogen In tetrahydrofuran at 80℃; under 38002.6 Torr; for 5h; Catalytic behavior; Autoclave; | 97% |
| Stage #1: methyl myristoate With phenylsilane; fac-[Mn-(xantphos)(CO)3Br] at 120℃; for 12h; Inert atmosphere; Stage #2: With water; sodium hydroxide In methanol at 20℃; Inert atmosphere; | 96% |
- 112-72-1
1-Tetradecanol
Conditions
| Conditions | Yield |
|---|---|
| With 18-crown-6 ether; tert-butylamine; tert-butyl alcohol; potassium In tetrahydrofuran at 20℃; for 2h; | 98% |
- 144708-82-7
1-Methoxymethoxy-tetradecane
- 112-72-1
1-Tetradecanol
Conditions
| Conditions | Yield |
|---|---|
| With methanol; DOWEX-50W-X2 for 30h; Heating; | 96% |
- 108-88-3
toluene
A
- 112-72-1
1-Tetradecanol
B
- 620-47-3
1-methyl-3-(phenylmethyl)-benzene
C
- 620-83-7
1-methyl-4-(phenylmethyl)benzene
D
- 713-36-0
2-benzyltoluene
Conditions
| Conditions | Yield |
|---|---|
| With boron trifluoride diethyl etherate at 120℃; for 2h; | A 96% B n/a C n/a D n/a |
...Expand
- 77774-34-6
tetradecyl tert-butyldimethylsilyl ether
- 112-72-1
1-Tetradecanol
Conditions
| Conditions | Yield |
|---|---|
| With toluene-4-sulfonic acid In methanol; dichloromethane at 20 - 25℃; for 0.333333h; Flow reactor; | 96% |
Conditions
| Conditions | Yield |
|---|---|
| With zirconium(IV) borohydride In tetrahydrofuran at 25℃; for 1h; Reduction; | 95% |
| With sodium tetrahydroborate; benzene-1,2-diol; trifluoroacetic acid In tetrahydrofuran at 25℃; for 4h; | 91% |
| With hydrogen In neat (no solvent) at 160℃; under 37503.8 Torr; for 24h; | 88% |
Conditions
| Conditions | Yield |
|---|---|
| With C30H34Cl2N2P2Ru; potassium methanolate; hydrogen In tetrahydrofuran at 100℃; under 38002.6 - 76005.1 Torr; for 15h; Glovebox; Autoclave; | 94% |
| With kieselguhr; copper at 350℃; under 73550.8 - 147102 Torr; Hydrogenation; | |
| With lithium aluminium tetrahydride |
- 146404-39-9
C21H38N2O2S
- 112-72-1
1-Tetradecanol
Conditions
| Conditions | Yield |
|---|---|
| With potassium hydroxide; ethanol; oxygen Heating; | 91% |
- 14980-92-8
ethyl 2-bromomyristate
- 112-72-1
1-Tetradecanol
Conditions
| Conditions | Yield |
|---|---|
| With sodium tetrahydroborate at 65℃; for 24h; | 90% |
- 112-72-1
1-Tetradecanol
Conditions
| Conditions | Yield |
|---|---|
| With water; silica gel In methanol at 60℃; Inert atmosphere; | 89% |
Raw Materials
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1-Tetradecanol
Chemistry
Product Name: 1-Tetradecanol
Synonyms: Dytol R-52;dytolr-52;Dehydag wax 14;Emery 3334;Epal 14 ;Alfol 14;alfol14;Cachalot M-43 NF;
The Molecular formula of 1-TETRADECANOL(112-72-1): C14H30O
The Molecular Weight of 1-TETRADECANOL(112-72-1): 214.39
Molecular Structure :
EINECS: 204-000-3
Melting point: 35-39 °C(lit.)
Boiling point: 289 °C(lit.)
Flash point: >230 °F
density: 0.823 g/mL at 25 °C(lit.)
vapor density: 7.4 (vs air)
storage temp.:-20°C
Water Solubility: insoluble
Synonyms: Dytol R-52;dytolr-52;Dehydag wax 14;Emery 3334;Epal 14 ;Alfol 14;alfol14;Cachalot M-43 NF;
The Molecular formula of 1-TETRADECANOL(112-72-1): C14H30O
The Molecular Weight of 1-TETRADECANOL(112-72-1): 214.39
Molecular Structure :
EINECS: 204-000-3
Melting point: 35-39 °C(lit.)
Boiling point: 289 °C(lit.)
Flash point: >230 °F
density: 0.823 g/mL at 25 °C(lit.)
vapor density: 7.4 (vs air)
storage temp.:-20°C
Water Solubility: insoluble
Uses
1-TETRADECANOL(112-72-1) is used in organic synthesis and surfactant materials.
Toxicity Data With Reference
| 1. | skn-hmn 75 mg/3D-I MOD | 85DKA8 Cutaneous Toxicity Drill, V.A. andP. Lazar, eds.,New York, NY.: Academic Press,1977,127. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Questionable carcinogen with experimental tumorigenic data. A human skin irritant. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ALCOHOL, DENATURED; ALCOHOLS, C6-12; ALCOHOLS, C9-11; ALCOHOLS, C12-13, ETHOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED; ALCOHOLS, C12-16, ETHOXYLATED; ALCOHOLS, C14-15, ETHOXYLATED; ALCOHOLS, C16-18, ETHOXYLATED; ALCOHOLS, C8-10, ETHOXYLATED PROPOXYLATED; ALCOHOLS, C12-15, ETHOXYLATED PROPOXYLATED; ALCOHOLS, N.O.S. and TETRADECANOL, mixed isomers.
The Hazard Codes of 1-TETRADECANOL(112-72-1):
Xi
The Risk Statements information of 1-TETRADECANOL(112-72-1):
38: Irritating to the skin
The Safety Statements information of 1-TETRADECANOL(112-72-1):
24/25: Avoid contact with skin and eyes
The Hazard Codes of 1-TETRADECANOL(112-72-1):
Xi The Risk Statements information of 1-TETRADECANOL(112-72-1):
38: Irritating to the skin
The Safety Statements information of 1-TETRADECANOL(112-72-1):
24/25: Avoid contact with skin and eyes