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112-73-2

Basic Information
CAS No.: 112-73-2
Name: Bis(2-butoxyethyl)ether
Article Data: 7
Molecular Structure:
Molecular Structure of 112-73-2 (Bis(2-butoxyethyl)ether)
Formula: C12H26O3
Molecular Weight: 218.337
Synonyms: Ether,bis(2-butoxyethyl) (7CI,8CI);2,2'-Dibutoxyethyl ether;2-(2-Butoxyethoxy)-1-butoxyethane;2-Butoxyethyl ether;5,8,11-Trioxapentadecane;Bis(2-butoxyethyl) ether;DBDG;DibutylCarbitol;Hisolve BDB;Butane,1,1'-[oxybis(2,1-ethanediyloxy)]bis-;
EINECS: 204-001-9
Density: 0.888 g/cm3
Melting Point: -60 °C(lit.)
Boiling Point: 254.6 °C at 760 mmHg
Flash Point: 117.2 °C
Solubility: Water Solubility :0.3 g/100 mL (20 °C)
Appearance: clear colorless to yellowish liquid
Safety: 23-24/25
PSA: 27.69000
LogP: 2.63640
Synthetic route
109-69-3

n-Butyl chloride

111-46-6

diethylene glycol

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydroxide; water; tetra(n-butyl)ammonium hydrogensulfate at 60℃; for 4h;97%
With perhydrodibenzo-18-crown-6; potassium hydroxide In water at 70℃; for 5h; Yield given;
52418-81-2

1-chloro-hexan-3-ol

A

111-34-2

-butyl vinyl ether

B

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydroxide
6550-99-8

1-(2-bromoethoxy)butane

A

111-34-2

-butyl vinyl ether

B

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydroxide
111-44-4

3-oxa-1,5-dichloropentane

2372-45-4

sodium butanolate

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With butan-1-ol
111-44-4

3-oxa-1,5-dichloropentane

71-36-3

butan-1-ol

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With perhydrodibenzo-18-crown-6; potassium hydroxide In water Yield given;
109-65-9

1-bromo-butane

111-46-6

diethylene glycol

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With perhydrodibenzo-18-crown-6; potassium hydroxide In water at 70℃; for 5h; Yield given;
6550-99-8

1-(2-bromoethoxy)butane

sodium hydroxide

sodium hydroxide

A

111-34-2

-butyl vinyl ether

B

112-73-2

diethylene glycol dibutyl ether

111-76-2

2-Butoxyethanol

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: dimethylaniline; diethyl ether; PBr3
2: NaOH
View Scheme
109-65-9

1-bromo-butane

112-34-5

Diethylene glycol monobutyl ether

112-73-2

diethylene glycol dibutyl ether

Conditions
ConditionsYield
With sodium hydride In toluene at 50℃;
112-73-2

diethylene glycol dibutyl ether

14309-25-2

trityl azide

574-45-8

N-(diphenylmethylidene)phenylamine

Conditions
ConditionsYield
at 170 - 190℃; Rate constant;
Downstream Products
109-65-9
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    Product Name: Bis(2-butoxyethyl)ether CAS: 112-73-2 MF: C12H26O3 MW: 218.33 EINECS: 204-001-9 Mol File: 112-73-2.mol Bis(2-butoxyethyl)ether Structure Bis(2-butoxyethyl)ether Chemical Properties Melting point -60 °C (lit.)

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Chemistry

MF: C12H26O3
MW: 218.33
EINECS: 204-001-9
mp:  -60 °C(lit.)
bp:  256 °C(lit.)
density:  0.885 g/mL at 25 °C(lit.)
vapor density:  >1 (vs air)
vapor pressure:  <0.01 mm Hg ( 20 °C)
refractive index:  n20/D 1.423(lit.)
Fp: 243 °F
Water Solubility:  0.3 g/100 mL (20 oC
Appearance: clear colorless to yellowish liquid
Product Categories: Functional Materials;Plasticizer;Polyalcohol Ethers, Esters (Plasticizer)
Synonyms: 1,1’-(oxybis(2,1-ethanediyloxy))bis-butan ; 1,1’-[oxybis(2,1-ethanediyloxy)]bis-butan ; 1,1’-[oxybis(2,1-ethanediyloxy)]bis-Butane ; 1-[2-(2-Butoxyethoxy)ethoxy]butane ; 2-(2-Butoxyethoxy)-1-butoxyethane ; 5,8,11-Trioxapentadecane ; Butane,1,1’-[oxybis(2,1-ethanediyloxy)]bis- ; Dibutylether diethylenglykolu 
The structure of  Diethylene glycol dibutyl (CAS NO.112-73-2) ether is:
 

 

Uses

 Diethylene glycol dibutyl (CAS NO.112-73-2) can be used as solvent in electrochemistry, boracium chemistry and polymer, gas adsorption, extractant ,high boiling reaction medium, or used in fuel, lubricant,textile, medicine and pesticide.

Toxicity Data With Reference

1.    

skn-rbt 500 mg open MLD

    UCDS**    Union Carbide Data Sheet. (Industrial Medicine and Toxicology Dept., Union Carbide Corp., 270 Park Ave., New York, NY 10017) 4/21 ,1967.
2.    

eye-rbt 500 mg open

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
3.    

orl-mus TDLo:16 g/kg (7-14D preg):REP

    EVHPAZ    EHP, Environmental Health Perspectives. Subseries of DHEW Publications. 57 (1984),141.
4.    

orl-rat LD50:3900 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.
5.    

skn-rbt LD50:4040 mg/kg

    AMIHBC    AMA Archives of Industrial Hygiene and Occupational Medicine. 10 (1954),61.

Consensus Reports

 Diethylene glycol dibutyl (CAS NO.112-73-2) is reported in EPA TSCA Inventory. Glycol ether compounds are on the Community Right-To-Know List.

Safety Profile

Safety Statements: 23-24/25 
S23: Do not breathe vapour
S24/25: Avoid contact with skin and eyes
WGK Germany: 1
RTECS: KN0350000
HS Code: 29091900
Moderately toxic by ingestion. Mildly toxic by skin contact. Experimental reproductive effects. A skin and eye irritant.Combustible when exposed to heat or flame. To fight fire, use foam or alcohol foam. When heated to decomposition it emits acrid smoke and irritating fumes.

Specification

1、Fire Fighting Measures 
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. 
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
2、Handling and Storage 
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. 
Storage: Store in a cool, dry place. Store in a tightly closed container.