Products Categories
CAS No.: | 114311-32-9 |
---|---|
Name: | Imazamox |
Article Data: | 5 |
Molecular Structure: | |
Formula: | C15H19N3O4 |
Molecular Weight: | 305.334 |
Synonyms: | (?à)-Imazamox;5-Methoxymethyl-2-(4-isopropyl-4-methyl-5-oxo-2-imidazolin-2-yl) nicotinicacid;Beyond;CL 299263;Imazamox;Pulsar;Raptor;Raptor(herbicide);Sweeper;Sweeper 70DG;2-(4,5-Dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-(methoxymethyl)-3-pyridinecarboxylic acid; |
Density: | 1.31 g/cm3 |
Melting Point: | 166-167°C |
Hazard Symbols: | N |
Risk Codes: | 50/53 |
Safety: | 60-61 |
Transport Information: | UN3077 9/PG 3 |
PSA: | 100.88000 |
LogP: | 0.98170 |
methanol
2-[(1-carbamoyl-1,2-dimethylpropyl)carbamoyl]-5-chloromethyl nicotinic acid
imazamox
Conditions | Yield |
---|---|
Stage #1: methanol; 2-[(1-carbamoyl-1,2-dimethylpropyl)carbamoyl]-5-chloromethyl nicotinic acid With sodium hydroxide In water at 65℃; for 1.5h; Stage #2: With sulfuric acid In water pH=4; | |
Stage #1: methanol; 2-[(1-carbamoyl-1,2-dimethylpropyl)carbamoyl]-5-chloromethyl nicotinic acid With sodium hydroxide In water at 65℃; for 1.5h; Stage #2: With sulfuric acid In water pH=4; |
imazamox
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: sodium hydroxide / pentan-1-ol; water / 1 h / 90 °C 2: picoline; acetic anhydride / 5,5-dimethyl-1,3-cyclohexadiene / 6 h / 75 °C 3: 30 °C / pH 4 4: dihydrogen peroxide View Scheme |
5-(methoxymethyl)-2,3-pyridinedicarboxylic acid
imazamox
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: picoline; acetic anhydride / 5,5-dimethyl-1,3-cyclohexadiene / 6 h / 75 °C 2: 30 °C / pH 4 3: dihydrogen peroxide View Scheme |
imazamox
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 30 °C / pH 4 2: dihydrogen peroxide View Scheme |
imazamox
Conditions | Yield |
---|---|
With dihydrogen peroxide |
imazamox
methyl iodide
Conditions | Yield |
---|---|
With tetra(n-butyl)ammonium hydroxide In methanol; acetone at 40℃; for 2h; |
Conditions | Yield |
---|---|
In ethanol for 0.166667h; |
The CAS register number of Imazamox is 114311-32-9. It also can be called as 2-(4,5-Dihydro-4-methyl-4-(1-methylethyl)-5-oxo-1H-imidazol-2-yl)-5-(methoxymethyl)-3-pyridinecarboxylic acid and the IUPAC name about this chemical is 5-(methoxymethyl)-2-(4-methyl-5-oxo-4-propan-2-yl-1H-imidazol-2-yl) pyridine-3-carboxylic acid. The molecular formula about this chemical is C15H19N3O4 and the molecular weight is 305.33. Classification code about this chemical is Herbicide.
Physical properties about Imazamox are: (1)ACD/LogP: 0.25; (2)ACD/LogD (pH 5.5): -2.4; (3)ACD/LogD (pH 7.4): -2.89; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 1; (7)ACD/KOC (pH 7.4): 1; (8)#H bond acceptors: 7; (9)#H bond donors: 2; (10)#Freely Rotating Bonds: 5; (11)Polar Surface Area: 81.09Å2; (12)Index of Refraction: 1.602; (13)Molar Refractivity: 79.47 cm3; (14)Molar Volume: 231.4 cm3; (15)Polarizability: 31.5x10-24cm3; (16)Surface Tension: 46.4 dyne/cm.
Use methoxy propionaldehyde, diethyl oxalate, methyl isopropyl ketone as starting materials, through the following reactions can get this chemical.
When you are using this chemical, please be cautious about it as the following:
This chemical is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, please avoid release to the environment. Refer to special instructions / safety data sheets. This material and its container must be disposed of as hazardous waste.
You can still convert the following datas into molecular structure:
(1)SMILES: O=C(O)c1c(ncc(c1)COC)/C2=N/C(C(=O)N2)(C(C)C)C
(2)InChI: InChI=1/C15H19N3O4/c1-8(2)15(3)14(21)17-12(18-15)11-10(13(19)20)5-9(6-16-11)7-22-4/h5-6,8H,7H2,1-4H3,(H,19,20)(H,17,18,21)
(3)InChIKey: NUPJIGQFXCQJBK-UHFFFAOYAY
(4)Std. InChI: InChI=1S/C15H19N3O4/c1-8(2)15(3)14(21)17-12(18-15)11-10(13(19)20)5-9(6-16-11)7-22-4/h5-6,8H,7H2,1-4H3,(H,19,20)(H,17,18,21)
(5)Std. InChIKey: NUPJIGQFXCQJBK-UHFFFAOYSA-N