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116-06-3

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Basic Information
CAS No.: 116-06-3
Name: ALDICARB
Article Data: 6
Molecular Structure:
Molecular Structure of 116-06-3 (ALDICARB)
Formula: C7H14 N2 O2 S
Molecular Weight: 190.266
Synonyms: Propionaldehyde,2-methyl-2-(methylthio)-, O-(methylcarbamoyl)oxime (8CI); 2-Methyl-2-(methylthio)propionaldehydeO-(methylcarbamoyl)oxime; Aldicarb; NSC 379586; OMS 771; Temik; Temik 10G;Temik G 10; UC 21149
EINECS: 204-123-2
Density: 1.08 g/cm3
Melting Point: 100ºC
Boiling Point: °Cat760mmHg
Flash Point: >100 ºC
Solubility: Solubility in water, g/100 ml at 25ºC: 0.6
Appearance: COLOURLESS CRYSTALS.
Hazard Symbols:
Risk Codes: R24;R26/28;R50/53   
Safety: 22-36/37-45-60-61-26
Transport Information: UN 2811
PSA: 75.99000
LogP: 1.86070
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Chemistry

 Carbanolate(116-06-3) exists as colourless crystals. The solubility of carbanolate(116-06-3) is 0.6 g/100 mL in water at 25 ℃. Carbanolate(116-06-3) is soluble in most organic solvents, almost insoluble in N-hexane.
Molecular Structure:
Molecular Formula: C7H14N2O2S.
Molecular Weight: 190.29.
Density: 1.08 g/cm3.
Melting Point: 100 ℃.

Uses

Carbanolate(116-06-3) is mainly used as insecticide for agricultural pesticides.

Toxicity Data With Reference

1.   

sce-hmn:lym 10 mg/L

   MUREAV    Mutation Research. 138 (1984),175.
2.   

otr-rat:emb 117 µg/plate

   JJATDK    JAT, Journal of Applied Toxicology. 1 (1981),190.
3.   

orl-rat LD50:650 µg/kg

   TXAPA9    Toxicology and Applied Pharmacology. 14 (1969),515.
4.   

ihl-rat LC50:200 mg/m3/5H

   85JCAE    Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,999.
5.   

skn-rat LD50:2500 µg/kg

   TXAPA9    Toxicology and Applied Pharmacology. 14 (1969),515.
6.   

scu-rat LDLo:666 µg/kg

   TXAPA9    Toxicology and Applied Pharmacology. 25 (1973),569.
7.   

orl-mus LD50:300 µg/kg

   JAFCAU    Journal of Agricultural and Food Chemistry. 18 (1970),793.
8.   

skn-rbt LD50:1400 mg/kg

   GUCHAZ    Guide to the Chemicals Used in Crop Protection 6 (1973),4.
9.   

skn-gpg LD50:2400 mg/kg

   85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
10.   

orl-pgn LD50:3160 µg/kg

   ASTT

Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 53 , 1991,p. 93.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 53 , 1991,p. 93.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human No Available Data IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 53 , 1991,p. 93.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR*    National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-136 ,1979. . Reported in EPA TSCA Inventory. EPA Extremely Hazardous Substances List.

Safety Profile

Deadly poison by ingestion, skin contact, subcutaneous, and possibly other routes. Human mutation data reported. Questionable carcinogen. A powerful systemic poison. In 1985 over 150 people in California exhibited toxic effects from eating watermelons contaminated with aldicarb. When heated to decomposition it emits very toxic fumes of NOx and SOx.
Hazard Codes: T+,N,Xn,F
Risk Statements: 24-26/28-50/53-36-20/21/22-11
24:  Toxic in contact with skin 
26/28:  Very Toxic by inhalation and if swallowed 
50/53:  Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment 
36:  Irritating to the eyes 
20/21/22:  Harmful by inhalation, in contact with skin and if swallowed 
11:  Highly Flammable 
Safety Statements: 22-36/37-45-60-61-26
22:  Do not breathe dust 
36/37:  Wear suitable protective clothing and gloves 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
60:  This material and/or its container must be disposed of as hazardous waste 
61:  Avoid release to the environment. Refer to special instructions safety data sheet 
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
RIDADR: 2757
RTECS: UE2275000
HazardClass: 6.1(a)
PackingGroup: I