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119692-59-0

Basic Information
CAS No.: 119692-59-0
Name: 4-Hydroxybutyl acrylate glycidyl ether
Article Data: 2
Molecular Structure:
Molecular Structure of 119692-59-0 (4-Hydroxybutyl acrylate glycidyl ether)
Formula: C10H16 O4
Molecular Weight: 200.235
Synonyms: 2-Propenoicacid, 4-(oxiranylmethoxy)butyl ester (9CI); 1,4-Butylene glycol glycidyl etheracrylate; 4-(Glycidyloxy)butyl acrylate; 4-Glycidoxybutyl acrylate;4-Hydroxybutyl acrylate glycidyl ether; 4HBAGE
Density: 1.077g/cm3
Boiling Point: 287.531°C at 760 mmHg
Flash Point: 123.267°C
PSA: 48.06000
LogP: 0.91120
Synthetic route
4711-95-9

1,4-butanediol monoglycidyl ether

140-88-5

ethyl acrylate

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

Conditions
ConditionsYield
Stage #1: 1,4-butanediol monoglycidyl ether; ethyl acrylate With titanium(IV) isopropylate at 95℃; under 300.03 Torr; for 4h; Reflux;
Stage #2: With 4-methoxy-phenol under 300.03 Torr;
97%
With titanium(IV) isopropylate; 4-methoxy-phenol at 95℃; under 300.03 Torr; for 6h; Reflux;
3121-61-7

2-methoxyethyl acrylate

4711-95-9

1,4-butanediol monoglycidyl ether

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

Conditions
ConditionsYield
With tetrabutoxytitanium; 4-methoxy-phenol In o-xylene at 80 - 90℃; under 75.0075 Torr;83.7%
2399-48-6

tetrahydrofurfuryl acrylate

4711-95-9

1,4-butanediol monoglycidyl ether

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

Conditions
ConditionsYield
With tetrabutoxytitanium; 4-methylisopropylbenzene; 4-methoxy-phenol at 89 - 102℃; under 30.003 Torr;70.4%
4711-95-9

1,4-butanediol monoglycidyl ether

292638-85-8

acrylic acid methyl ester

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

Conditions
ConditionsYield
With tetrabutoxytitanium; 4-methoxy-phenol In hexane; toluene at 72 - 92℃;111.1 g
119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

1137-42-4

4-Hydroxybenzophenone

1214748-83-0

acrylic acid 4-[3-(4-benzoyl-phenoxy)-2-hydroxy-propoxy]butyl ester

Conditions
ConditionsYield
With potassium carbonate In acetonitrile for 24h; Reflux;
With sodium hydroxide; potassium carbonate In hexane; dichloromethane; water; acetonitrile
With potassium carbonate In acetonitrile for 24h; Reflux;5.5 g
85-52-9

2-Benzoylbenzoic acid

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

1214748-82-9

2-benzoyl-benzoic acid 3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In ISOPROPYLAMIDE; acetonitrile for 16h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In N,N-dimethyl acetamide; acetonitrile for 16h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In N,N-dimethyl acetamide; acetonitrile for 16h; Reflux;45.2 g
84434-05-9

2-[(9-oxo-9H-thioxanthen-2-yl)oxy]-acetic acid

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

1214748-81-8

acrylic acid 4-{2-hydroxy-3-[2-(9-oxo-9H-thioxanthen-2-yloxy)-acetoxy]-propoxy}-butyl ester

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In ISOPROPYLAMIDE; acetonitrile for 16h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In acetonitrile for 16h; Reflux;1.8 g

2[(9-oxo-9H-thioxanthen-2-yl)oxy]-propionic acid

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

1214748-80-7

acrylic acid 4-{2-hydroxy-3-[2-(9-oxo-9H-thioxanthen-2-yloxy)-propionyloxy]propoxy}-butyl ester

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In ISOPROPYLAMIDE; acetonitrile for 16h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In N,N-dimethyl acetamide; acetonitrile for 16h; Reflux;3.7 g
51762-69-7

9-oxo-9H-thioxanthen-1-carboxylic acid

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

1214748-78-3

9-oxo-9H-thioxanthene-1-carboxylic acid-3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In dimethyl sulfoxide; acetonitrile for 24h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In dimethyl sulfoxide; acetonitrile for 24h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In dimethyl sulfoxide; acetonitrile for 24h; Reflux;2.6 g
25095-94-7

9-oxo-9H-thioxanthene-2-carboxylic acid

119692-59-0

4-Hydroxybutyl acrylate glycidyl ether

1214748-79-4

9-oxo-9H-thioxanthene-2-carboxylic acid-3-(4-acryloyloxy-butoxy)-2-hydroxy-propyl ester

Conditions
ConditionsYield
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In ISOPROPYLAMIDE; acetonitrile for 24h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In N,N-dimethyl acetamide; acetonitrile for 24h; Reflux;
With 2,6-di-tert-butyl-4-methyl-phenol; tetrabutylammomium bromide In N,N-dimethyl acetamide; acetonitrile for 24h; Reflux;2.5 g
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