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12014-28-7

Basic Information
CAS No.: 12014-28-7
Name: CADMIUM PHOSPHIDE
Molecular Structure:
Molecular Structure of 12014-28-7 (CADMIUM PHOSPHIDE)
Formula: P
Molecular Weight: 399.18
Synonyms: Tricadmiumdiphosphide
Density: g/cm3
Melting Point: 700 °C(lit.)
Boiling Point: °Cat760mmHg
Flash Point: °C
Hazard Symbols:
Risk Codes: 20/21/22-50/53
Safety: Confirmed human carcinogen. Explosive reaction with concentrated nitric acid. When heated to decomposition it emits toxic fumes of POx and Cd. See also CADMIUM COMPOUNDS and PHOSPHIDES.
PSA: 46.94000
LogP: 1.17950
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Chemistry

IUPAC Name: Cadmium(2+); phosphorus(3-) 
Molecular Formula: Cd3P2
Molecular Weight: 399.18g/mol
EINECS: 234-595-5 
Density: 5.6g/cm3
Appearance: green quartet needle crystal
Transport information: UN 3134 4.3/PG 1
Melting Point: 700 °C(lit.)
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å2 
Solubility: not soluble in ethanol, ether, dissolved in hydrochloric acid and escape Phosphine (PH3)
The Cas Register Number  of Cadmium phosphide is 12014-28-7.The chemical synonyms of Cadmium phosphide (CAS NO.12014-28-7) are Cadmium phosphide ; Cadmiumphosphide(cd3p2) ; Tricadmium diphosphide ; Cadmium phosphide -100 mesh ; Cadmium phosphide, 99.5% (metals basis) .The molecular structure of Cadmium phosphide (CAS NO.12014-28-7) is.

Uses

 Cadmium phosphide (CAS NO.12014-28-7) can be used as pesticide.

Production

 Cadmium phosphide (CAS NO.12014-28-7) can be obtained when Cadmium and red phosphorus  heated (400 ~ 600°C ) in a vacuum quartz tube.

Consensus Reports

Cadmium compounds are on the Community Right-To-Know List.

Safety Profile

Confirmed human carcinogen. Explosive reaction with concentrated nitric acid. When heated to decomposition it emits toxic fumes of POx and Cd. See also CADMIUM COMPOUNDS and PHOSPHIDES.
Hazard Codes: HarmfulXn,DangerousN
Risk Statements: 20/21/22-50/53 
R20/21/22: Harmful by inhalation, in contact with skin and if swallowed. 
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 60-61 
S60: This material and its container must be disposed of as hazardous waste. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3134 4.3/PG 1
WGK: Germany 3

Standards and Recommendations

OSHA PEL: TWA 5 µg(Cd)/m3
ACGIH TLV: TWA 0.002 mg(Cd)/m3 (respirable dust), Suspected Human Carcinogen); BEI: 5 µg/g creatinine in urine; 5 µg/L in blood
DFG MAK: DFG BAT: Blood 1.5 µg/dL; Urine 15 µg/dL. MAK: Suspected Carcinogen
NIOSH REL: (Cadmium) Reduce to lowest feasible level