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CAS No.: | 120666-13-9 |
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Name: | 2,8,9-TRIMETHYL-2,5,8,9-TETRAAZA-1-PHOSPHABICYCLO[3.3.3]UNDECANE |
Article Data: | 6 |
Molecular Structure: | |
Formula: | C9H21 N4 P |
Molecular Weight: | 216.266 |
Synonyms: | 2,8,9-Trimethyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane;Proazaphosphatrane |
Density: | g/cm3 |
Melting Point: | 110-115 °C(lit.) |
Boiling Point: | 263.9°Cat760mmHg |
Flash Point: | 113.4°C |
PSA: | 26.55000 |
LogP: | 0.08950 |
bis(diethylamino)chlorophosphine
tris[2-(methylamino)ethyl]amine
proazaphosphatrane
Conditions | Yield |
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With potassium tert-butylate In acetonitrile 1) 1h, RT, 2) 1 h, RT; | 81% |
B
proazaphosphatrane
Conditions | Yield |
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With potassium tert-butylate In dimethylsulfoxide-d6 at 20℃; | A 31% B 69% |
2,8,9-Trimethyl-2,8,9-triaza-5-azonia-1λ5-phospha-tricyclo[3.3.3.01,5]undecane; chloride
proazaphosphatrane
Conditions | Yield |
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With sodium hydroxide at 200℃; | 53% |
tris[2-(methylamino)ethyl]amine
Hexamethylphosphorous triamide
proazaphosphatrane
Conditions | Yield |
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In xylene Heating; |
tris[2-(methylamino)ethyl]amine
proazaphosphatrane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 82 percent / ClP(NMe2)2, Et3N / CH2Cl2 / 1 h / Ambient temperature 2: 53 percent / NaOH / 200 °C View Scheme |
proazaphosphatrane
Conditions | Yield |
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Multi-step reaction with 2 steps 1: tetrahydrofuran / Inert atmosphere 2: tetrahydrofuran / Inert atmosphere View Scheme |
proazaphosphatrane
Conditions | Yield |
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In tetrahydrofuran Inert atmosphere; |
Conditions | Yield |
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In diethyl ether for 0.0833333h; | 100% |
Conditions | Yield |
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In diethyl ether for 0.0833333h; | 100% |
Conditions | Yield |
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In benzene for 12h; Heating / reflux; | 100% |