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12069-69-1

Basic Information
CAS No.: 12069-69-1
Name: Cupric carbonate basic
Molecular Structure:
Molecular Structure of 12069-69-1 (Cupric carbonate basic)
Formula: CuCO3.Cu.(OH)2
Molecular Weight: 221.11
Synonyms: Copper, (carbonato)dihydroxydi- (8CI);Copper, [m-[carbonato(2-)-O:O']]dihydroxydi-;Carbonic acid, copper complex;Basic copper carbonate;Basic copper carbonate(Cu2(CO3)(OH)2);Basic copper(II)carbonate;Basic cupric carbonate;Carbonatodihydroxodicopper;Carbonic acid,copper(2+) salt (1:1), basic;Cheshunt compound;Copper basic carbonate;Coppercarbonate hydroxide (Cu2CO3(OH)2);Cupriccarbonate, basic;Dicopper dihydroxycarbonate;Dicopper(2+) carbonatedihydroxide;
EINECS: 235-113-6
Density: 4.0 g/cm3
Melting Point: 200 °C
Boiling Point: 333.6 °C at 760 mmHg
Flash Point: 169.8 °C
Solubility: Insoluble in water
Appearance: Fine green powder
Hazard Symbols: HarmfulXn
Risk Codes: 22-36/37/38
Safety: 26-36
PSA: 103.65000
LogP: -2.80560
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    Product Name: Cupric carbonate basic CAS: 12069-69-1 MF: CO3.Cu.CuH2O2 MW: 221.11 EINECS: 235-113-6 Mol File: 12069-69-1.mol Cupric carbonate basic Structure Cupric carbonate basic Chemical Properties Melting point 200 °C

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  • Copper(II) carbonate basic

  • Casno:

    12069-69-1

    Copper(II) carbonate basic

    Min.Order: 1 Gram

    FOB Price:  USD $ 0.0-0.0

    Located in Hangzhou National Hi-Tech Industrial Development Zone, zhongqichem is a technical company mainly focus on the Custom synthesis, manufacturing, sales of chemicals to various industries. Benefiting from the outstanding customer service an

    Located in Hangzhou National Hi-Tech Industrial Development Zone, Hangzhou zhongqi chem co.,Ltd is an ISO 9001:2015 & SGS certified molden chemical company,who is mainly focus on t

  •  Hangzhou Zhongqi chem Co.,Ltd.

     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:0086-571-86976032

    Address:Kangkang Gu 1010, Chun xiao road 61,Binjiang District 310052,Hangzhou city , China

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  • Copper(II) carbonate basic

  • Casno:

    12069-69-1

    Copper(II) carbonate basic

    Min.Order: 0

    FOB Price:  USD $ 0.0-0.0

    Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

    Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns

  •  Hunan chemfish Pharmaceutical co.,Ltd

     China (Mainland)  |  Contact Details

    Business Type:Manufacturers

    Tel:0731-85567275

    Address:No.10048, xiangjiang centry bulding ,kaifu district ,changsha city ,Hunan

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  • Cupric carbonate basic CAS NO.12069-69-1  CAS NO.12069-69-1

  • Casno:

    12069-69-1

    Cupric carbonate basic CAS NO.12069-69-1 CAS NO.12069-69-1

    Min.Order: 1 Metric Ton

    FOB Price:  USD $ 7.0-8.0

    1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

    KAISA GROUP INC.is the enterprise which is specialize in manfacturing and exporting avariety of Chemical in China. We have the strong economic base and comprehensive technology.We

  •  KAISA GROUP INC

    United States  |  Contact Details

    Business Type:Trading Company

    Tel:15131197030

    Address:1312 17th Street Suite 1402 Denver CO 80202

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Consensus Reports

Copper and its compounds are on the Community Right-To-Know List. Copper(II) carbonate basic (CAS NO.12069-69-1) is reported in EPA TSCA Inventory.

Standards and Recommendations

ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3

Specification

The IUPAC name of Copper(II) carbonate basic is dicopper carbonate dihydroxide. With the CAS registry number 12069-69-1, it is also named as (Carbonato(2-))dihydroxydicopper. The classification codes are Agricultural Chemical; Fungicide, bactericide, wood preservative; Molluscicide. It is fine green powder which is insoluble in cold water and alcohol, soluble in acid forming the corresponding copper, soluble in cyanide, ammonia, ammonium salt and alkali metal carbonate solution. Additionally, this chemical should be stored in the ventilate, low-temperature and dry place. 

The other characteristics of this product can be summarized as: (1)#H bond acceptors: 5; (2)#H bond donors: 4; (3)#Freely Rotating Bonds: 2; (4)Polar Surface Area: 103.65 ?2; (5)Rotatable Bond Count: 0; (6)Exact Mass: 219.849425; (7)MonoIsotopic Mass: 219.849425; (8)Topological Polar Surface Area: 65.2; (9)Heavy Atom Count: 8; (10)Complexity: 18.8; (11)Covalently-Bonded Unit Count: 5.

Preparation of Copper(II) carbonate basic: It can be obtained by the following reaction equations.
Cu+4HNO3→Cu(NO3)2+2NO2↑+2H2O
2Cu(NO3)2+2Na2CO3+H2O→CuCO3·Cu(OH)2+4NaNO3+CO2
2Cu(NO3)2+4NaHCO3→CuCO3·Cu(OH)2+4NaNO3+3CO2↑+H2O

Uses of Copper(II) carbonate basic: It is used in the fireworks, pesticides, paint, animal feed, fungicides, anti-corrosion and other industries. And it is also used in the manufacturing of copper compounds. In addition, this chemical can be used as analysis reagents and pesticides.

When you are using this chemical, please be cautious about it as the following:
It is not only harmful if swallowed, but also irritating to eyes, respiratory system and skin. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If you want to contact this product, you must wear suitable protective clothing.

People can use the following data to convert to the molecule structure.
1. Smiles: C(=O)([O-])[O-].[OH-].[OH-].[Cu+2].[Cu+2]
2. InChI: InChI=1/CH2O3.2Cu.2H2O/c2-1(3)4;;;;/h(H2,2,3,4);;;2*1H2/q;2*+2;;/p-4

The following are the toxicity data which has been tested.

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
bird - domestic LD50 oral 900mg/kg (900mg/kg)   Pesticide Chemicals Official Compendium, Association of the American Pesticide Control Officials, Inc., 1966. Vol. -, Pg. 258, 1966.
duck LDLo oral 900mg/kg (900mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: COMA
Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
pigeon LDLo oral 1gm/kg (1000mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: COMA
Australian Veterinary Journal. Vol. 16, Pg. 147, 1940.
rabbit LD50 oral 159mg/kg (159mg/kg)   Guide to the Chemicals Used in Crop Protection. Vol. 6, Pg. 128, 1973.
rat LD50 oral 1350mg/kg (1350mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"

BLOOD: NORMOCYTIC ANEMIA
Shokuhin Eiseigaku Zasshi. Food Hygiene Journal. Vol. 26, Pg. 605, 1985.