Detail of "12093-10-6"

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CAS Number:
12093-10-6
Name:
Ferrocenecarboxaldehyde
Molecular Structure:
Formula:
C₁₁H₁₀FeO
Molecular Weight:
214.04
Synonyms:
Ferrocenecarboxaldehyde(8CI);Iron, cyclopentadienyl(formylcyclopentadienyl)- (6CI,7CI);1-Formylferrocene;2-Ferrocenecarboxaldehyde;Cyclopentadienecarboxaldehyde,cyclopentadienyliron deriv.;Ferrocene-1-carboxaldehyde;Ferrocenecarbaldehyde;Ferrocenylcarbaldehyde;Ferrocene, formyl-;Formyldicyclopentadienyliron;Formylferrocene;NSC 407052;
EINECS:
235-158-1
Melting Point:
118-120 °C(lit.)
Boiling Point:
213.6 °C at 760 mmHg
Flash Point:
98.8 °C
Solubility:
insoluble
Appearance:
crystalline solid
Safety:
22-24/25 Details

Studies on ferrocene and its derivatives: Studies on ferrocene and its derivatives. IV. Some reactions with 1-phenyl-3-methyl-2-pyrazolin-5-one. Hassan, K. M. (Fac. Sci., Assiut Univ., Assiut, Egypt). J. Indian Chem. Soc., 53(12), 1185-9 (English) 1976. 3718-29-4 which is the cas registry number of one of substances is just one of reagents here. CODEN: JICSAH. DOCUMENT TYPE: Journal CA Section: 40 (Dyes, Fluorescent Whitening Agents, and Photosensitizers) Section cross-reference(s): 28, 29 Condensation of 1-phenyl-3-methyl-2-pyrazolin-5-ones with ferrocenealdehyde (FcCHO) [12093-10-6] and 2-methyl heterocyclic quaternary salts gave I (R = H or NO2) and II (R = H, NO2; R1 = R2 = H or R1 = H and R2R2 = o-C6H4), resp. New monomethine cyanine dyes (III; R = H, NO2; R1 = CHFc; R2 = H or R2R2 = o-C6H4) were prepd. by condensing FcCHO with II. The reactions of I (R = H, NO2) with hydrazine hydrate, phenylhydrazine [100-63-0], amines, and urea [57-13-6] were also studied. .

Synthesis of N-ferrocenylmethylbutylamine: All Rights Reserved.Some chemicals with cas registry numbers like 12093-10-6 and 385818-42-8 are also used. Synthesis of N-ferrocenylmethylbutylamine. Liu, Yu-ting; Yin, Da-wei; Lu, Bo (College of Chemistry and Chemical Engineering, Shanxi University of Science and Technology, Xianyang 712081, Peop. Rep. China). Hecheng Huaxue, 14(2), 203-205 (Chinese) 2006 Hecheng Huaxue Bianjibu. CODEN: HEHUE2. ISSN: 1005-1511. DOCUMENT TYPE: Journal CA Section: 29 (Organometallic and Organometalloidal Compounds) Section cross-reference(s): 21 N-ferrocenylmethylbutylamine was synthesized by condensation and redn. from formylferrocene and n-butylamine. The optimal reaction conditions that were established by orthogonal exptl. method were as follows: 10 mmol formylferrocene, n (FcCHO) : n (BuNH2) : n (KBH4) = 1.0:1.4:1.4, condensation at (65 ± 2)° for 6 h, redn. at (55 ± 2)° for 8 h. The yield reached 77% under the optimal conditions. The yield was 80% and the purity was 99.5% in a 50 times amplification expt. under the optimal reaction conditions. .